ACS Journals Logo
Journal of the American Chemical Society logo

Volume 107
Main Index

Issue 1


Approach to a general classification of solvents using a multivariate statistical treatment of quantitative solvent parameters
M. Chastrette, M. Rajzmann, and M. Chanon
pp 1 - 11; DOI:
10.1021/ja00287a001
PDF
Multinuclear NMR study of the complexation of lanthanide(III) cations with sodium triphosphate: induced shifts and relaxation rate enhancements
Maarten S. Nieuwenhuizen, Joop A. Peters, Anton Sinnema, Antonius P. G. Kieboom, and Herman Van Bekkum
pp 12 - 16; DOI:
10.1021/ja00287a002
PDF
Circular dichroism of rifamycin antibiotics. 2. Circular dichroism and stereochemistry in solution of 8-O-methylrifamycin SV
Carlo Rosini, Carlo Bertucci, Piero Salvadori, and Maurizio Zandomeneghi
pp 17 - 19; DOI:
10.1021/ja00287a003
PDF
ENDOR studies of novel di- and triphenylmethyl radicals generated from galvinols
B. Kirste, W. Harrer, and H. Kurreck
pp 20 - 28; DOI:
10.1021/ja00287a004
PDF
Two-dimensional NMR spectroscopy of tetra-o-tolylcyclopentadienone. Complete rotamer assignment
Rudolph Willem, Arnold Jans, Cornelis Hoogzand, Marcel Gielen, Georges Van Binst, and Henri Pepermans
pp 28 - 32; DOI:
10.1021/ja00287a005
PDF
Carbon-13 and proton EPR analysis of the benzo[a]pyrene cation
Paul D. Sullivan, Fouad Bannoura, and Guido H. Daub
pp 32 - 35; DOI:
10.1021/ja00287a006
PDF
An advanced visible-light-induced water reduction with dye-sensitized semiconductor powder catalyst
Takeo Shimidzu, Tomokazu Iyoda, and Yoshihiro Koide
pp 35 - 41; DOI:
10.1021/ja00287a007
PDF
Polymerized-depolymerized vesicles. Reversible thiol-disulfide-based phosphatidylcholine membranes
N. K. P. Samuel, Maninder Singh, Kazuo Yamaguchi, and Steven L. Regen
pp 42 - 47; DOI:
10.1021/ja00287a008
PDF
Electron-relay chain mechanism in the sensitized photoisomerization of stilbazole salts in aqueous anionic micelles
Katsuhiko Takagi, Keitaro Aoshima, Yasuhiko Sawaki, and Hiizu Iwamura
pp 47 - 52; DOI:
10.1021/ja00287a009
PDF
Temperature-dependent photoselection-intramolecular exciton motion in tris(2,2'-bipyridine)ruthenium [Ru(bpy)3]2+
Clifford M. Carlin and M. Keith DeArmond
pp 53 - 57; DOI:
10.1021/ja00287a010
PDF
Formation of gas-phase methyl radicals over magnesium oxide
Daniel J. Driscoll, Wilson Martir, Ji Xiang Wang, and Jack H. Lunsford
pp 58 - 63; DOI:
10.1021/ja00287a011
PDF
Cation transport from multiple alkali cation mixtures using a liquid membrane system containing a series of calixarene carriers
Steven R. Izatt, Richard T. Hawkins, James J. Christensen, and Reed M. Izatt
pp 63 - 66; DOI:
10.1021/ja00287a012
PDF
Reactions of iron carbene (FeCH2+) and cobalt carbene (CoCH2+) with cyclic alkanes in the gas phase
D. B. Jacobson and B. S. Freiser
pp 67 - 72; DOI:
10.1021/ja00287a013
PDF
Dynamics of monoolefin-metal ion complexes in the gas phase. Determination of the number of labile .beta.-hydrogens by reaction with ethene-d4
D. B. Jacobson and B. S. Freiser
pp 72 - 80; DOI:
10.1021/ja00287a014
PDF
Methyl substituent effects in the gas-phase acidities of halosubstituted oxygen acids. A realignment with substituent effects in solution
G. Caldwell, T. B. McMahon, P. Kebarle, J. E. Bartmess, and J. P. Kiplinger
pp 80 - 82; DOI:
10.1021/ja00287a015
PDF
Photophysics and photochemistry of arylmethyl radicals in liquids
A. Bromberg, K. H. Schmidt, and D. Meisel
pp 83 - 91; DOI:
10.1021/ja00287a016
PDF
Problems of CD spectrometers. 3. Critical comments on liquid crystal induced circular dichroism
Yohji Shindo and Yasuhiro Ohmi
pp 91 - 97; DOI:
10.1021/ja00287a017
PDF
Adsorption and decomposition of dimethyl methylphosphonate on an aluminum oxide surface
M. K. Templeton and W. H. Weinberg
pp 97 - 108; DOI:
10.1021/ja00287a018
PDF
Alkylation of enolate ions
Mark E. Jones, Steven R. Kass, Jonathan Filley, Robert M. Barkley, and G. Barney Ellison
pp 109 - 115; DOI:
10.1021/ja00287a019
PDF
Correlation of acyl ion intensities with product enthalpies from collisionally activated decomposition of molecular ions of small aliphatic ketones
Maurice M. Bursey and J. Ronald Hass
pp 115 - 117; DOI:
10.1021/ja00287a020
PDF
Role of the Madelung energy in the neutral-ionic phase transition of tetrathiafulvalene chloranil
Robert M. Metzger and Jerry B. Torrance
pp 117 - 121; DOI:
10.1021/ja00287a021
PDF
Some effects of amine substituents in strained hydrocarbons
Peter Politzer, Keerthi Jayasuriya, and Barbara A. Zilles
pp 121 - 124; DOI:
10.1021/ja00287a022
PDF
Structure-energy relations, reaction mechanism, and disparity of progress of concerted reaction events
Ernest Grunwald
pp 125 - 133; DOI:
10.1021/ja00287a023
PDF
Corresponding orbital analysis of the bonding of some monosubstituted benzenes
Hans Aagren and Paul S. Bagus
pp 134 - 137; DOI:
10.1021/ja00287a024
PDF
Toward the laboratory identification of cyclopropenylidene
Timothy J. Lee, Annik Bunge, and Henry F. Schaefer
pp 137 - 142; DOI:
10.1021/ja00287a025
PDF
Syn and anti bent hydrazine radical cations. Effect of .sigma.,.pi. mixing on spectral properties
Stephen F. Nelsen, Silas C. Blackstock, Nathan P. Yumibe, Timothy B. Frigo, John E. Carpenter, and Frank Weinhold
pp 143 - 149; DOI:
10.1021/ja00287a026
PDF
Theoretical studies of [1,n]-sigmatropic rearrangements involving hydrogen transfer in simple methyl-substituted conjugated polyenes
B. Andes Hess, L. J. Schaad, and J. Pancir
pp 149 - 154; DOI:
10.1021/ja00287a027
PDF
Theoretical examination of the SN2 reaction involving chloride ion and methyl chloride in the gas phase and aqueous solution
Jayaraman Chandrasekhar, Scott F. Smith, and William L. Jorgensen
pp 154 - 163; DOI:
10.1021/ja00287a028
PDF
Calculations of isotope effects in elimination reactions. New experimental criteria for tunneling in slow proton transfers
William H. Saunders
pp 164 - 169; DOI:
10.1021/ja00287a029
PDF
An unusual carbon-carbon bond cleavage in bulky metal alkoxides: syntheses and x-ray crystal structures of three-coordinate manganese(II) and chromium(II) complexes containing the di-tert-butylmethoxide ligand
Brendan D. Murray, Haakon Hope, and Philip P. Power
pp 169 - 173; DOI:
10.1021/ja00287a030
PDF
Novel organosulfur metal complexes derived from dithioesters
Howard Alper, Frederick W. B. Einstein, Frederick W. Hartstock, and Anthony C. Willis
pp 173 - 179; DOI:
10.1021/ja00287a031
PDF
Electronic coupling in delocalized mixed-valence dimers
Lucjan Dubicki, James Ferguson, and Elmars R. Krausz
pp 179 - 182; DOI:
10.1021/ja00287a032
PDF
Resonance Raman spectroscopy of metallochlorins: models for green heme protein prosthetic groups
Laura A. Andersson, Thomas M. Loehr, Chi K. Chang, and A. Grant Mauk
pp 182 - 191; DOI:
10.1021/ja00287a033
PDF
Electronic and redox properties of stacked-ring silicon phthalocyanines from molecular orbital theory
Alfred B. Anderson, Teresa L. Gordon, and Malcolm E. Kenney
pp 192 - 195; DOI:
10.1021/ja00287a034
PDF
Enantioselective ring construction: synthesis of (+)-.alpha.-cuparenone
Douglass F. Taber, Eric H. Petty, and Krishna Raman
pp 196 - 199; DOI:
10.1021/ja00287a035
PDF
Total synthesis of (+)-demethyldysidenin and (-)-demethylisodysidenin, hexachlorinated amino acids from the marine sponge Dysidea herbacea. Assignment of absolute stereochemistry
Stephen E. De Laszlo and Paul G. Williard
pp 199 - 203; DOI:
10.1021/ja00287a036
PDF
One-way photoisomerization of cis-stilbene via a cation radical chain mechanism
Frederick D. Lewis, James R. Petisce, Joe D. Oxman, and Marshall J. Nepras
pp 203 - 207; DOI:
10.1021/ja00287a037
PDF
Anchimeric assistance in carbon-hydrogen bond homolysis. Reaction of tert-butoxyl radicals with tetraethyl Group IV compounds
Richard A. Jackson, Keith U. Ingold, David Griller, and Avtar S. Nazran
pp 208 - 211; DOI:
10.1021/ja00287a038
PDF
Nitrosation of organic hydroperoxides by nitrogen dioxide/dinitrogen tetraoxide
William A. Pryor, Laurence Castle, and Daniel F. Church
pp 211 - 217; DOI:
10.1021/ja00287a039
PDF
Stereochemistry of the Wittig reaction. Effect of nucleophilic groups in the phosphonium ylide
Bruce E. Maryanoff, Allen B. Reitz, and Barbara A. Duhl-Emswiler
pp 217 - 226; DOI:
10.1021/ja00287a040
PDF
Energetics and pattern analysis of crystals of proflavine deoxydinucleoside phosphate complex
Kwang S. Kim and E. Clementi
pp 227 - 234; DOI:
10.1021/ja00287a041
PDF
Inactivation of cytochrome P-450 by a catalytically generated cyclobutadiene species
Ralph A. Stearns and Paul R. Ortiz de Montellano
pp 234 - 240; DOI:
10.1021/ja00287a042
PDF
Carrier-mediated transport through bulk liquid membranes: dependence of transport rates and selectivity on carrier properties in a diffusion-limited process
Jean Paul Behr, Michele Kirch, and Jean Marie Lehn
pp 241 - 246; DOI:
10.1021/ja00287a043
PDF
Micellar systems as devices for enhancing the lifetimes and concentrations of free radicals
T. J. Burkey and D. Griller
pp 246 - 249; DOI:
10.1021/ja00287a044
PDF
Single charge accumulation dynamics on photocatalytic titanium dioxide particles in ethanol slurries by time domain reflectometry
Seiichiro Nakabayashi, Akira Fujishima, and Kenichi Honda
pp 250 - 251; DOI:
10.1021/ja00287a045
PDF
Homogeneous models for propylene ammoxidation. 1. Tungsten(VI) imido complexes as models for the active sites
Dominic M. T. Chan, William C. Fultz, William A. Nugent, D. Christopher Roe, and Thomas H. Tulip
pp 251 - 253; DOI:
10.1021/ja00287a046
PDF
Photon-assisted carbon-hydrogen bond activation in a coordinated methoxy. A molecular orbital explanation
Alfred B. Anderson and N. K. Ray
pp 253 - 254; DOI:
10.1021/ja00287a047
PDF
Halide-promoted insertion of carbon monoxide into bridging-methylene ligands in triosmium clusters
Eric D. Morrison, Gregory L. Geoffroy, and Arnold L. Rheingold
pp 254 - 255; DOI:
10.1021/ja00287a048
PDF
Total synthesis of (.+-.)-ovalicin
Elias J. Corey and James P. Dittami
pp 256 - 257; DOI:
10.1021/ja00287a049
PDF
Electronic structure of the molybdenum-iron-sulfur cluster MoFe3S4(SH)63-ion
Michael Cook and Martin Karplus
pp 257 - 259; DOI:
10.1021/ja00287a050
PDF
Tris(dimethylphenylphosphine)tetrahydridoiridium(1+) ion: its characteristic reactivity and use as a catalyst for isomerization of tris(dimethylphenylphosphine)trihydridoiridium
Larry F. Rhodes and Kenneth G. Caulton
pp 259 - 260; DOI:
10.1021/ja00287a051
PDF
Oxygen transfer by bleomycin analogs dysfunctional in DNA cleavage
Robert E. Kilkuskie, Hosbett Suguna, Benjamin Yellin, Natesan Murugesan, and Sidney M. Hecht
pp 260 - 261; DOI:
10.1021/ja00287a052
PDF
(Ethylene)ethylnickel cyanide complex intermediate in catalytic hydrocyanation of ethylene. Reductive elimination by an associative process
Ronald J. McKinney and D. Christopher Roe
pp 261 - 262; DOI:
10.1021/ja00287a053
PDF
Useful approach for determination of the structure of organosulfur compounds: sulfur-33 high-resolution FT-NMR
T. C. Farrar, Barry M. Trost, S. L. Tang, and S. E. Springer-Wilson
pp 262 - 264; DOI:
10.1021/ja00287a054
PDF
Raman spectroscopic study of acetylene on supported rhodium catalysts
W. L. Parker, A. R. Siedle, and R. M. Hexter
pp 264 - 266; DOI:
10.1021/ja00287a055
PDF
Phosphinoalkylsilyl complexes. 6. Isolation of a silyl complex of iridium(I). Crystal and molecular structure of dicarbonyl(triphenylphosphine)[[(diphenylphosphino)ethyl]dimethylsilyl]iridium
Mary J. Auburn, Stephen L. Grundy, Stephen R. Stobart, and Michael J. Zaworotko
pp 266 - 267; DOI:
10.1021/ja00287a056
PDF
Ammonolysis of cephamycins: carbon-13 NMR characterization of the intermediates from .beta.-lactam ring cleavage prior to loss of the 3'-group
E. J. J. Grabowski, A. W. Douglas, and G. B. Smith
pp 267 - 268; DOI:
10.1021/ja00287a057
PDF
On the antarafacial stereochemistry of the thermal [1,7]-sigmatropic hydrogen shift
Carl A. Hoeger and William H. Okamura
pp 268 - 270; DOI:
10.1021/ja00287a058
PDF
Concerning the role of nidurufin in aflatoxin biosynthesis
Craig A. Townsend and Siegfried B. Christensen
pp 270 - 271; DOI:
10.1021/ja00287a059
PDF
Solid-state conformations of linear oligopeptides and aliphatic amides. A model of chiral perturbation of a conjugated system
Andrzej Stanislaw Cieplak
pp 271 - 273; DOI:
10.1021/ja00287a060
PDF
Enantioselective synthesis of quaternary carbon centers through Michael-type alkylation of chiral imines
Michel Pfau, Gilbert Revial, Andre Guingant, and Jean d'Angelo
pp 273 - 274; DOI:
10.1021/ja00287a061
PDF
Synthesis, structure and antitumor properties of platinum complexes of vitamin C
L. Steven Hollis, Alan R. Amundsen, and Eric W. Stern
pp 274 - 276; DOI:
10.1021/ja00287a062
PDF
Picosecond absorption studies on m-naphthoquinomethane. Singlet-triplet intersystem crossing
Joshua L. Goodman, Kevin S. Peters, Paul M. Lahti, and Jerome A. Berson
pp 276 - 277; DOI:
10.1021/ja00287a063
PDF
A molecular beam of tryptophan
Thomas R. Rizzo, Young D. Park, and Donald H. Levy
pp 277 - 278; DOI:
10.1021/ja00287a064
PDF
1-Methyl-2-(2-hydroxyphenyl)imidazole: a catalytic phosphate protecting group in deoxyoligonucleotide synthesis
Brian C. Froehler and Mark D. Matteucci
pp 278 - 279; DOI:
10.1021/ja00287a065
PDF
A novel metal-metal bonded iridium(II) dimer
P. G. Rasmussen, J. E. Anderson, O. H. Bailey, Milton Tamres, and J. C. Bayon
pp 279 - 281; DOI:
10.1021/ja00287a066
PDF
Interconversion of tetrahedral and .pi.-carbonyl containing butterfly clusters: [Fe4(MPR3)(CO)12(.eta.2-CO)]-.dblharw.[Fe4(MPR3)(CO)13]- (M = gold, R = ethyl; M = copper, R = phenyl) and Fe4(AuPEt3)(CO)12(.eta.2-COMe)
Colin P. Horwitz, Elizabeth M. Holt, and Duward F. Shriver
pp 281 - 282; DOI:
10.1021/ja00287a067
PDF
Book Reviews

pp 282 - 288; DOI:
10.1021/ja00287a600
PDF

Issue 2


Comparative molecular orbital study of [6]-, [10]-, and [18]annulenes and the bridged [10]annulenes
Robert C. Haddon and Krishnan Raghavachari
pp 289 - 298; DOI:
10.1021/ja00288a001
PDF
Magnetotropism of biphenylene and related hydrocarbons. A circuit current analysis
Junichi Aihara
pp 298 - 302; DOI:
10.1021/ja00288a002
PDF
NMR studies of phenylsilyl anions. Evaluation of ion pairing and charge distribution
Erwin Buncel, T. K. Venkatachalam, Bertil Eliasson, and Ulf Edlund
pp 303 - 306; DOI:
10.1021/ja00288a003
PDF
Kinetic study of the proton-transfer reactions involving kryptopyrrole and its cation in aqueous solution. Transition-state structure determinations
F. G. Terrier, F. L. Debleds, J. F. Verchere, and A. P. Chatrousse
pp 307 - 312; DOI:
10.1021/ja00288a004
PDF
Direct measurement of a prominent outer-sphere electron self-exchange: kinetic parameters for the hexaaquaruthenium(II)/(III) couple determined by oxygen-17 and ruthenium-99 NMR
Paul Bernhard, Lothar Helm, Andreas Ludi, and Andre E. Merbach
pp 312 - 317; DOI:
10.1021/ja00288a005
PDF
The mechanism of the reaction between silyl radicals and chloroethylenes: a case study of the triethylsilyl-tetrachloroethylene reaction
Abraham Horowitz
pp 318 - 321; DOI:
10.1021/ja00288a006
PDF
Pyramidalization of carbonyl carbons in asymmetric environments: carboxylates, amides, and amino acids
G. A. Jeffrey, K. N. Houk, Michael N. Paddon-Row, Nelson G. Rondan, and J. Mitra
pp 321 - 326; DOI:
10.1021/ja00288a007
PDF
Gas-phase reactions of nucleophiles with methyl formate
Carolyn L. Johlman and Charles L. Wilkins
pp 327 - 332; DOI:
10.1021/ja00288a008
PDF
Nonplanar structures of the singlet and triplet cyclopropenyl anions. An ab initio study
Georg Winkelhofer, Rudolf Janoschek, F. Fratev, Guenther W. Spitznagel, Jayaraman Chandrasekhar, and Paul v. R. Schleyer
pp 332 - 337; DOI:
10.1021/ja00288a009
PDF
Structure of dichromium tetraacetate by gas-phase electron diffraction
S. N. Ketkar and M. Fink
pp 338 - 340; DOI:
10.1021/ja00288a010
PDF
Conformation analysis. 9. 2,3-Dichloro-1,3-butadiene. An electron-diffraction investigation of the molecular structure, composition, and anti-gauche energy and entropy differences
Kolbjoern Hagen, Kenneth Hedberg, John Neisess, and Grete Gundersen
pp 341 - 345; DOI:
10.1021/ja00288a011
PDF
Hydrazinium radical cation (NH3NH3+.cntdot.) and dication (NH3NH32+): prototypes for the ionized forms of medium-ring bicyclic compounds
Willem J. Bouma and Leo Radom
pp 345 - 348; DOI:
10.1021/ja00288a012
PDF
The modification of benzene and carbon monoxide adsorption on platinum(111) by the coadsorption of potassium or sulfur
E. L. Garfunkel, M. H. Farias, and G. A. Somorjai
pp 349 - 353; DOI:
10.1021/ja00288a013
PDF
Preparation and Characterization of a Dialkoxyiron(IV) Porphyrin
John T. Groves, Robert Quinn, Thomas J. McMurry, Mikio Nakamura, George Lang, and Brian Boso
pp 354 - 360; DOI:
10.1021/ja00288a014
PDF
Transalkylation reaction. Homogeneous catalytic formation of carbon-nitrogen bonds
Robert B. Wilson and Richard M. Laine
pp 361 - 369; DOI:
10.1021/ja00288a015
PDF
Aqueous solution chemistry of .mu.-pyrazine-pentaammineruthenium(II,III) pentacyanoferrate(II,III): formation, redox reactions, and intervalence properties
Andrew Yeh and Albert Haim
pp 369 - 376; DOI:
10.1021/ja00288a016
PDF
Hydride donating properties of [HRu3(CO)11]- in the presence of carbon monoxide; chemistry of ruthenium carbonyl anions relevant to the catalysis of the water gas shift reaction
Jeffery C. Bricker, Colleen C. Nagel, Alak A. Bhattacharyya, and Sheldon G. Shore
pp 377 - 384; DOI:
10.1021/ja00288a017
PDF
Examination of rhodium carboxylate antitumor agents complexed with nucleosides by extended x-ray absorption fine structure spectroscopy
Neil Alberding, N. Farrell, and E. D. Crozier
pp 384 - 388; DOI:
10.1021/ja00288a018
PDF
Experimental probes of the electronic matrix element contributions to bimolecular reactions. Retardation factors associated with the mismatching of electronic excited states in outer-sphere redox couples
T. Ramasami and John F. Endicott
pp 389 - 396; DOI:
10.1021/ja00288a019
PDF
Stereochemistry of allyl sulfones. On the structure of metalated allyl sulfones and their stereochemistry of alkylation
Barry M. Trost and Norman R. Schmuff
pp 396 - 405; DOI:
10.1021/ja00288a020
PDF
Synthesis and x-ray crystallographic characterization of an oxo-bridged bimetallic organosamarium complex, [(C5Me5)2Sm]2(.mu.-O)
William J. Evans, Jay W. Grate, Ira Bloom, William E. Hunter, and Jerry L. Atwood
pp 405 - 409; DOI:
10.1021/ja00288a021
PDF
Effects of methylation on the thermal stability and chemiluminescence properties of 1,2-dioxetanes
Waldemar Adam and Wilhelm J. Baader
pp 410 - 416; DOI:
10.1021/ja00288a022
PDF
Solvent and counterion effects on the stereochemistry and the competition between electron-transfer and SN2 mechanisms in the reactions of (trimethylstannyl)alkalis with bromides
Mikhail S. Alnajjar and Henry G. Kuivila
pp 416 - 423; DOI:
10.1021/ja00288a023
PDF
Absolute stereochemistry of (+)-1,8a-dihydro-3,8-dimethylazulene, a labile biosynthetic intermediate for 1,4-dimethylazulene. Determination by theoretical calculation of CD spectra and verification by synthesis of model compounds
Nobuyuki Harada, Jun Kohori, Hisashi Uda, Koji Nakanishi, and Reiji Takeda
pp 423 - 428; DOI:
10.1021/ja00288a024
PDF
Conjugative interaction in the orthogonal enamine, 1-azabicyclo[3.2.2]non-2-ene
W. von E. Doering, Ludmila Birladeanu, D. W. Andrews, and M. Pagnotta
pp 428 - 432; DOI:
10.1021/ja00288a025
PDF
Magnesiate ions in solutions and solids prepared from dialkylmagnesium compounds and cryptands
Edward P. Squiller, Robert R. Whittle, and Herman G. Richey
pp 432 - 435; DOI:
10.1021/ja00288a026
PDF
Photoinduced cyclizations of mono- and dianions of N-acyl-o-chloroanilines and N-acyl-o-chlorobenzylamines as general methods for the synthesis of oxindoles and 1,4-dihydro-3(2H)-isoquinolinones
R. Richard Goehring, Yesh P. Sachdeva, Jyothi S. Pisipati, Mark C. Sleevi, and James F. Wolfe
pp 435 - 443; DOI:
10.1021/ja00288a027
PDF
Asymmetric induction in the Claisen rearrangement of N-allylketene N,O-acetals
Mark J. Kurth, Owen H. W. Decker, Hakon Hope, and Michael D. Yanuck
pp 443 - 448; DOI:
10.1021/ja00288a028
PDF
Host-guest complexation. 34. Bridged hemispherands
George M. Lein and Donald J. Cram
pp 448 - 455; DOI:
10.1021/ja00288a029
PDF
Observation of transient cyclohexadienones during the aqueous bromination of phenols. Mechanisms of enolization
Oswald S. Tee and N. Rani Iyengar
pp 455 - 459; DOI:
10.1021/ja00288a030
PDF
Chiral synthesis via organoboranes. 2. Rapid reaction of boronic esters of very high optical purity with lithium aluminum hydride. Facile reaction of essentially optically pure borinic esters with lithium monoethoxyaluminohydride. A novel and quantitative synthesis of lithium monoalkyl- and dialkylborohydrides of essentially 100% optical purity
Herbert C. Brown, Bakthan Singaram, and Thomas E. Cole
pp 460 - 464; DOI:
10.1021/ja00288a031
PDF
Enantiospecific and stereospecific synthesis of lipoxin A. Stereochemical assignment of the natural lipoxin A and its possible biosynthesis
Julian Adams, Brian J. Fitzsimmons, Yves Girard, Yves Leblanc, Jillian F. Evans, and Joshua Rokach
pp 464 - 469; DOI:
10.1021/ja00288a032
PDF
Unconventional ionic hydrogen bonds. 1. CH.delta.+.cntdot..cntdot..cntdot.X. Complexes of quaternary ions with n- and .pi.-donors
Michael Meot-Ner and Carol A. Deakyne
pp 469 - 474; DOI:
10.1021/ja00288a033
PDF
Unconventional ionic hydrogen bonds. 2. NH+.cntdot..cntdot..cntdot..pi.. Complexes of onium ions with olefins and benzene derivatives
Michael Meot-Ner and Carol A. Deakyne
pp 474 - 479; DOI:
10.1021/ja00288a034
PDF
Mechanism of the oxidation of NADH by quinones. Energetics of one-electron and hydride routes
Brian W. Carlson and Larry L. Miller
pp 479 - 485; DOI:
10.1021/ja00288a035
PDF
Stereoselectivity in the enzymic oxidation and nonenzymic hydrogen-exchange reactions of dihydroorotate
Loren D. Keys and Michael Johnston
pp 486 - 492; DOI:
10.1021/ja00288a036
PDF
Bleomycin as an oxene transferase. Catalytic oxygen transfer to olefins
Natesan Murugesan and Sidney M. Hecht
pp 493 - 500; DOI:
10.1021/ja00288a037
PDF
Control of ring junction stereochemistry via radical cyclization
Gilbert Stork and Michael Kahn
pp 500 - 501; DOI:
10.1021/ja00288a038
PDF
An organothorium-nickel phosphido complex with a short thorium-nickel distance. The structure of Th(.eta.5-C5Me5)2(.mu.-PPh2)2Ni(CO)2
J. M. Ritchey, A. J. Zozulin, D. A. Wrobleski, R. R. Ryan, H. J. Wasserman, D. C. Moody, and R. T. Paine
pp 501 - 503; DOI:
10.1021/ja00288a039
PDF
Aldol reactions of transition metal carbene complexes
William D. Wulff and Scott R. Gilbertson
pp 503 - 505; DOI:
10.1021/ja00288a040
PDF
Unusual reactivity of [Os3Sn(.mu.-H)2(CO)10R2] involving the tin atom and the novel bridging hydride: x-ray crystal and molecular structures of [Os3Sn(.mu.-H)2{.mu.-RC(Os)(:O)(Sn)}(CO)9R] and [Os3Sn(CO)9{.mu.2,.eta.1-C(CO2Me)CH2C:O(Os)OMe}R2] [R = CH(SiMe3)2]
Christine J. Cardin, David J. Cardin, John M. Power, and Michael B. Hursthouse
pp 505 - 507; DOI:
10.1021/ja00288a041
PDF
Photochemical reactions in organized assemblies. 43. Micelle and vesicle solubilization sites. Determination of micropolarity and microviscosity using photophysics of a dipolar olefin
Kirk S. Schanze, Dong Myung Shin, and David G. Whitten
pp 507 - 509; DOI:
10.1021/ja00288a042
PDF
Optical microscopic study of helical superstructures of chiral bilayer membranes
N. Nakashima, S. Asakuma, and T. Kunitake
pp 509 - 510; DOI:
10.1021/ja00288a043
PDF
Magnetic and spectroscopic properties of the .delta..delta.* states of tetrachlorotetrakis(trimethylphosphine)dimolybdenum and .beta.-[tetrachlorobis[1,2-bis(dimethylphosphino)ethane]dimolybdenum]: experimental determination of the energy of a triplet .delta..delta.* state
Michael D. Hopkins, Thomas C. Zietlow, Vincent M. Miskowski, and Harry B. Gray
pp 510 - 512; DOI:
10.1021/ja00288a044
PDF
The mechanism of oxygen atom transfer to tetraphenylporphinato chromic chloride
Lung Chi Yuan and Thomas C. Bruice
pp 512 - 513; DOI:
10.1021/ja00288a045
PDF
Homolytic and heterolytic oxygen-oxygen bond scissions accompanying oxygen transfer to iron(III) porphyrins by percarboxylic acids and hydroperoxides. A mechanistic criterion for peroxidase and cytochrome P-450
William A. Lee and Thomas C. Bruice
pp 513 - 514; DOI:
10.1021/ja00288a046
PDF
Electron-transfer reactions of trivalent uranium. Preparation and structure of the uranium metallocene compounds (MeC5H4)3U:NPh and [(MeC5H4)3U]2[.mu.-.eta.1,.eta.2-PhNCO]
John G. Brennan and Richard A. Andersen
pp 514 - 516; DOI:
10.1021/ja00288a047
PDF
Stereocontrolled syntheses of (E)- and (Z)-.gamma.-bisabolene 8,9-epoxide
Julio D. Martin, Cirilo Perez, and Jose L. Ravelo
pp 516 - 518; DOI:
10.1021/ja00288a048
PDF
Gas phase platinum cluster reactions with benzene and several hexanes: evidence of extensive dehydrogenation and size-dependent chemisorption
D. J. Trevor, R. L. Whetten, D. M. Cox, and A. Kaldor
pp 518 - 519; DOI:
10.1021/ja00288a049
PDF
Total synthesis of (.+-.)-O-methylorantine
Harry H. Wasserman, Rudolf K. Brunner, John D. Buynak, Charles G. Carter, Teruo Oku, and Ralph P. Robinson
pp 519 - 521; DOI:
10.1021/ja00288a050
PDF
Novel cyclization of type II biradicals from .alpha.,.beta.-acetylenic ketones
V. Bhaskar Rao, Steven Wolff, and William C. Agosta
pp 521 - 522; DOI:
10.1021/ja00288a051
PDF
Experimental evidence of the stepwise mechanism of a biomimetic olefin cyclization: trapping of cationic intermediates
Mugio Nishizawa, Hideyuki Takenaka, and Yuji Hayashi
pp 522 - 523; DOI:
10.1021/ja00288a052
PDF
Additions and Corrections - Spectroscopic and Kinetic Evidence for the Tautomer of 7-Deoxyaklavinone as an Intermediate in the Reductive Coupling of Aclacinomycin
Don L. Kleyer, Giorgio Gaudiano, and Tad H. Koch
pp 524 - 524; DOI:
10.1021/ja00288a600
PDF
Additions and Corrections - A Regioselective Synthesis of Iridoids Based on the Paterno-Buchi Enone Photoannulation Reaction
Ratan K. Chaudhuri, Takafumi Ikeda, and C. Richard Hutchinson
pp 524 - 524; DOI:
10.1021/ja00288a601
PDF
Additions and Corrections - Synthesis and Characterization of a Homoleptic Actinide Alkyl. The Heptamethylthorate(IV) Ion: A Complex with Seven Metal-Carbon Bonds
Harald Lauke, Paul J. Swepston, and Tobin J. Marks
pp 524 - 524; DOI:
10.1021/ja00288a602
PDF
Additions and Corrections - Photochemistry and Electronic Structure of the (η5C5H5)2TiS5Complex
Alice E. Bruce, Mitchell R. M. Bruce, and David R. Tyler
pp 524 - 524; DOI:
10.1021/ja00288a603
PDF
Additions and Corrections - 29Si Magic Angle Spinning NMR Study on Local Silicon Environments in Amorphous and Crystalline Lithium Silicates
Charles M. Schramm, B. H. W. S. De Jong, and Victor E. Parziale
pp 524 - 524; DOI:
10.1021/ja00288a604
PDF
Book Reviews

pp 524 - 524; DOI:
10.1021/ja00288a605
PDF

Issue 3


Solid-state structure and reactivity in solution. 6. Flash photolysis and structural investigations of (1-(diethylamino)-2-(diphenylphosphino)ethane)tetracarbonylmolybdenum(0)
Gerard R. Dobson, Ivan Bernal, George M. Reisner, B. Dobson, and Saber E. Mansour
pp 525 - 532; DOI:
10.1021/ja00289a001
PDF
Small-ring cyclic cumulenes: theoretical studies of the structure and barrier to inversion in cyclic allenes
Richard O. Angus, Michael W. Schmidt, and Richard P. Johnson
pp 532 - 537; DOI:
10.1021/ja00289a002
PDF
Structural and energetic features of fully substituted silylenes, disilenes, and silylsilylenes (SiX2, X2SiSiX2, and XSiSiX3; X = lithium, methyl, and fluorine)
Karsten Krogh-Jespersen
pp 537 - 543; DOI:
10.1021/ja00289a003
PDF
Adsorption and hydrogenolysis of cyclopropanecarboxylic acid on aluminum oxide
M. K. Templeton and W. H. Weinberg
pp 544 - 551; DOI:
10.1021/ja00289a004
PDF
Estimation of the rate of electron transfers between two contacting polymer surfaces
C. R. Leidner and Royce W. Murray
pp 551 - 556; DOI:
10.1021/ja00289a005
PDF
New synthesis and properties of 11,11,12,12-tetracyano-9,10-anthraquinodimethane: an electron acceptor displaying a single-wave, two-electron reduction and a coproportionation pathway to the radical anion
Aravinda M. Kini, Dwaine O. Cowan, Fabian Gerson, and Reinhart Moeckel
pp 556 - 562; DOI:
10.1021/ja00289a006
PDF
Infrared spectrum of the lithium acetylene molecule in solid argon
Laurent Manceron and Lester Andrews
pp 563 - 568; DOI:
10.1021/ja00289a007
PDF
Optimized intermolecular potential functions for amides and peptides. Structure and properties of liquid amides
William L. Jorgensen and Carol J. Swenson
pp 569 - 578; DOI:
10.1021/ja00289a008
PDF
How carbon monoxide bonds to metal surfaces
Shen Shu Sung and Roald Hoffmann
pp 578 - 584; DOI:
10.1021/ja00289a009
PDF
Nucleophilic activation of coordinated carbon monoxide. 3. Hydroxide and methoxide reactions with the trinuclear clusters M3(CO)12 (M = Fe, Ru, or Os). Implications with regard to catalysis of the water gas shift reaction
David C. Gross and Peter C. Ford
pp 585 - 593; DOI:
10.1021/ja00289a010
PDF
4-Azahomoadamant-3-ene: spectroscopic characterization and photoresolution of a highly reactive strained bridgehead imine
Juliusz G. Radziszewski, John W. Downing, Mikolaj Jawdosiuk, Peter Kovacic, and Josef Michl
pp 594 - 603; DOI:
10.1021/ja00289a011
PDF
Anthracene heme cyclophanes. Steric effects in carbon monoxide, molecular oxygen, and RNC binding
T. G. Traylor, Shinji Tsuchiya, Dwane Campbell, Michael Mitchell, Dennis Stynes, and Noboru Koga
pp 604 - 614; DOI:
10.1021/ja00289a012
PDF
Model studies of iron-tyrosinate proteins
Joseph W. Pyrz, A. Lawrence Roe, Lawrence J. Stern, and Lawrence Que
pp 614 - 620; DOI:
10.1021/ja00289a013
PDF
Kinetics and thermodynamics of intra- and intermolecular carbon-hydrogen bond activation
William D. Jones and Frank J. Feher
pp 620 - 631; DOI:
10.1021/ja00289a014
PDF
Reactions of Re2(CO)8[.mu.-(L-L)] (L-L = dppm, dmpm) and Re2(CO)7[.mu.-(L-L)]NCMe) with alkynes
Kang Wook Lee, William T. Pennington, A. Wallace Cordes, and Theodore L. Brown
pp 631 - 641; DOI:
10.1021/ja00289a015
PDF
Supported organoactinides. Surface chemistry and catalytic properties of alumina-bound cyclopentadienyl and pentamethylcyclopentadienyl thorium and uranium hydrocarbyls and hydrides
Ming Yuan He, Guoxing Xiong, Paul J. Toscano, Robert L. Burwell, and Tobin J. Marks
pp 641 - 652; DOI:
10.1021/ja00289a016
PDF
Supported organoactinides. High-resolution solid-state carbon-13 NMR studies of catalytically active, alumina-bound pentamethylcyclopentadienyl)thorium methyl and hydride complexes
Paul J. Toscano and Tobin J. Marks
pp 653 - 659; DOI:
10.1021/ja00289a017
PDF
Copper(II) complexes of tyrosine-containing dipeptides. Effects of side-chain groups on spectral and solution chemical properties and their structural implication
Osamu Yamauchi, Kiyokazu Tsujide, and Akira Odani
pp 659 - 666; DOI:
10.1021/ja00289a018
PDF
Kinetics of the reactions of (ethoxycarbonyl)methylcobalt tetracarbonyl with carbon-13 monoxide, triphenylphosphine, hydridocobalt tetracarbonyl, and hydrogen. A comparison of the reactivities of (ethoxycarbonyl)methyl-, ethoxycarbonyl-, and hydridocobalt tetracarbonyl complexes
Carl Hoff, F. Ungvary, R. B. King, and L. Marko
pp 666 - 671; DOI:
10.1021/ja00289a019
PDF
Theoretical studies of radical recombination reactions. 1. Allyl and azaallyl radicals
J. J. Dannenberg and K. Tanaka
pp 671 - 674; DOI:
10.1021/ja00289a020
PDF
Poly(methylene ditelluride)
C. W. Dirk, D. Nalewajek, Graciela B. Blanchet, Howard Schaffer, F. Moraes, R. M. Boysel, and F. Wudl
pp 675 - 677; DOI:
10.1021/ja00289a021
PDF
Photolysis of dibenzyl ketones adsorbed on zeolite molecular sieves. Correlation of observed cage effects with carbonyl carbon-13 enrichment efficiencies
Nicholas J. Turro and Peter Wan
pp 678 - 682; DOI:
10.1021/ja00289a022
PDF
An enantioselective synthesis of 2,2',6-trisubstituted biphenyls
A. I. Meyers and Richard J. Himmelsbach
pp 682 - 685; DOI:
10.1021/ja00289a023
PDF
Synthesis of [4]peristylane and functionalized derivatives of this hemispherical ring system
Leo A. Paquette, John W. Fischer, Alan R. Browne, and Christopher W. Doecke
pp 686 - 691; DOI:
10.1021/ja00289a024
PDF
Bilayer membranes of triple-chain, fluorocarbon amphiphiles
Toyoki Kunitake and Nobuyuki Higashi
pp 692 - 696; DOI:
10.1021/ja00289a025
PDF
Chain growth rates in Fischer-Tropsch synthesis on an iron catalyst: an isotopic transient study
Charles A. Mims and L. E. McCandlish
pp 696 - 697; DOI:
10.1021/ja00289a026
PDF
Crystal structure of the neutral diarylcuprate Cu2Li2(C6H4CH2NMe2-2)4: the asymmetric bonding configuration of organo groups bridging copper and lithium
G. Van Koten, J. T. B. H. Jastrzebski, F. Muller, and C. H. Stam
pp 697 - 698; DOI:
10.1021/ja00289a027
PDF
Tris(diphenylmethylene)methane dianion. Direct evidence for Y-aromaticity
Andrzej Rajca and Laren M. Tolbert
pp 698 - 699; DOI:
10.1021/ja00289a028
PDF
(Z)-1-Methoxybut-1-en-3-yne. A versatile synthon for 1,4-bis(trimethylsilyl)-1,3-butadiyne as well as for nucleophilic aldehyde and butadiyne equivalents
George Zweifel and Shyamala Rajagopalan
pp 700 - 701; DOI:
10.1021/ja00289a029
PDF
Reactivity of dioxygen with group 4A alkoxy alkyls: epoxidation via metal alkyl mediated oxygen atom transfer
Timothy V. Lubben and Peter T. Wolczanski
pp 701 - 703; DOI:
10.1021/ja00289a030
PDF
Cytidine-5'-triphosphate synthetase catalyzes the phosphorylation of uridine 5'-triphosphate by adenosine 5'-triphosphate
Wolfgang Von der Saal, Joseph J. Villafranca, and Paul M. Anderson
pp 703 - 704; DOI:
10.1021/ja00289a031
PDF
Inversion of the exo/endo rate ratio by inductive enhancement of oxygen participation
Joseph B. Lambert, Eric G. Larson, and Kent P. Steele
pp 704 - 705; DOI:
10.1021/ja00289a032
PDF
Applications of two-dimensional NMR methods in photochemically induced dynamic nuclear polarization spectroscopy
R. M. Scheek, S. Stob, R. Boelens, K. Dijkstra, and R. Kaptein
pp 705 - 706; DOI:
10.1021/ja00289a033
PDF
A protease mimic with turnover capabilities
F. M. Menger and L. G. Whitesell
pp 707 - 708; DOI:
10.1021/ja00289a034
PDF
Chiral discrimination in the covalent binding of bis(phenanthroline)dichlororuthenium(II) to B-DNA
Jacqueline K. Barton and Elias Lolis
pp 708 - 709; DOI:
10.1021/ja00289a035
PDF
Conversion of cationic alkene hydride complex of tungsten into a complex containing a terminal alkylidene ligand
Glenn A. Miller and N. John Cooper
pp 709 - 711; DOI:
10.1021/ja00289a036
PDF
Isotopic-label-directed observation of the nuclear Overhauser effect in poorly resolved proton NMR spectra
R. H. Griffey, M. A. Jarema, S. Kunz, P. R. Rosevear, and A. G. Redfield
pp 711 - 712; DOI:
10.1021/ja00289a037
PDF
Syntheses and x-ray structures of the lithium, nickel, and cobalt complexes [Li(THF)4][Ni(NPh2)3].0.5C7H8, [{Ni(NPh2)2}2] and [{Co(NPh2)2}2]: structural characterization of three coordinate first row d7 and d8 complexes
Hakon Hope, Marilyn M. Olmstead, Brendan D. Murray, and Philip P. Power
pp 712 - 713; DOI:
10.1021/ja00289a038
PDF
A new class of irreversible inhibitors of leukotriene biosynthesis
E. J. Corey, John R. Cashman, Thomas M. Eckrich, and David R. Corey
pp 713 - 715; DOI:
10.1021/ja00289a039
PDF
Distonic radical ions. Stepwise elimination of acetaldehyde from ionized benzyl ethyl ether
Chrysostomos Wesdemiotis, Rong Feng, and Fred W. McLafferty
pp 715 - 716; DOI:
10.1021/ja00289a040
PDF
Radical cation of dicyclopentadiene. Evidence for a singly bridged structure
Heinz D. Roth and Marcia L. M. Schilling
pp 716 - 718; DOI:
10.1021/ja00289a041
PDF
F-2,4-Dimethyl-3-ethyl-3-pentyl and F-2,4-dimethyl-3-isopropyl-3-pentyl; stable tert-perfluoroalkyl radicals prepared by addition of fluorine or trifluoromethyl to a perfluoroalkene
Kirby V. Scherer, Taizo Ono, Kouichi Yamanouchi, Richard Fernandez, and Philip Henderson
pp 718 - 719; DOI:
10.1021/ja00289a042
PDF
Dimethyl(methylthio)sulfonium tetrafluoroborate initiated organometallic additions to and macrocyclizations of thioketals
Barry M. Trost and Toshio Sato
pp 719 - 721; DOI:
10.1021/ja00289a043
PDF
Chemoselectivity in palladium-mediated cycloadditions of substituted trimethylenemethanes
Barry M. Trost, Thomas N. Nanninga, and Tsuyoshi Satoh
pp 721 - 723; DOI:
10.1021/ja00289a044
PDF
Dewar thiophene: its generation and trapping with furan
W. A. Rendall, M. Torres, and O. P. Strausz
pp 723 - 724; DOI:
10.1021/ja00289a045
PDF
Systematic substitution on the cubane nucleus. Amide activation for metalation of "saturated" systems
Philip E. Eaton and Graziano Castaldi
pp 724 - 726; DOI:
10.1021/ja00289a046
PDF
Use of the pyroelectric effect to determine the absolute orientation of the polar axis in molecular crystals
Anjali A. Patil, David Y. Curtin, and Iain C. Paul
pp 726 - 727; DOI:
10.1021/ja00289a047
PDF
Hydrogen exchange between the methyl and hydride ligands of dicyclopentadienylhydridomethyltungsten prior to methane elimination
R. Morris Bullock, Christine E. L. Headford, Susan E. Kegley, and Jack R. Norton
pp 727 - 729; DOI:
10.1021/ja00289a048
PDF
Formyl, acyl, and carbene derivatives of Fe3(.mu.3-EPh)2(CO)9 (E = nitrogen or phosphorus). Unique examples of carbene-nitrene and carbene-phosphinidene coupling
Gregory D. Williams, Gregory L. Geoffroy, Robert R. Whittle, and Arnold L. Rheingold
pp 729 - 731; DOI:
10.1021/ja00289a049
PDF
Synthesis and thermal ring expansion of 2-methylene-1,1-dimethylsilacyclobutane
Robert T. Conlin, Holly B. Huffaker, and Young Woo Kwak
pp 731 - 732; DOI:
10.1021/ja00289a050
PDF
Chromatographic resolution of enantiomers having aromatic groups by an optically active clay-chelate adduct
Akihiko Yamagishi
pp 732 - 734; DOI:
10.1021/ja00289a051
PDF
New strategy for [3 + 2] annulation: applications to the synthesis of functionalized di- and triquinanes
Joseph P. Marino and Edgardo Laborde
pp 734 - 735; DOI:
10.1021/ja00289a052
PDF
(Diethylamino)sulfur trifluoride in organic synthesis. 2. The transformation of sulfoxides to .alpha.-fluoro thioethers
James R. McCarthy, Norton P. Peet, Michael E. LeTourneau, and Muthiah Inbasekaran
pp 735 - 737; DOI:
10.1021/ja00289a053
PDF
Metal-catalyzed rearrangement of alkene-alkynes and the stereochemistry of metallacyclobutene ring opening
Thomas J. Katz and Timothy M. Sivavec
pp 737 - 738; DOI:
10.1021/ja00289a054
PDF
Quenching of zinc-substituted cytochrome c excited states by cytochrome b5
George L. McLendon, Jay R. Winkler, Daniel G. Nocera, Marcia R. Mauk, A. Grant Mauk, and Harry B. Gray
pp 739 - 740; DOI:
10.1021/ja00289a055
PDF
Additions and Corrections - The Relaxational Behavior of Self-Associated 6-Methylpurine
Heinz Sterk, and Hermann Gruber
pp 740 - 740; DOI:
10.1021/ja00289a600
PDF
Book Reviews

pp 740 - 742; DOI:
10.1021/ja00289a601
PDF

Issue 4


Intermolecular conversion over a low barrier. 3. Gas-phase NMR studies of a hydrogen-bond association
S. H. Bauer, Tomoko Yamazaki, K. I. Lazaar, and N. S. Chiu
pp 743 - 747; DOI:
10.1021/ja00290a001
PDF
Charge-transfer complexes of aryl derivatives of Group 14 and 15 elements with tetracyanoethylene
John E. Frey, Roger D. Cole, Elizabeth C. Kitchen, Lori M. Suprenant, and Mary Sue Sylwestrzak
pp 748 - 755; DOI:
10.1021/ja00290a002
PDF
Chemical reactions on clusters. 4. Gas phase unimolecular decomposition of the acetone and acetone-d6 ions in association with argon and carbon dioxide clusters
A. J. Stace
pp 755 - 761; DOI:
10.1021/ja00290a003
PDF
Mechanistic information from infrared multiple photon decomposition. The ethylisopropylamine proton-transfer system
Christopher R. Moylan and John I. Brauman
pp 761 - 765; DOI:
10.1021/ja00290a004
PDF
Fluoride and chloride affinities of main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of Lewis acidities from ion cyclotron resonance halide-exchange equilibria
J. W. Larson and T. B. McMahon
pp 766 - 773; DOI:
10.1021/ja00290a005
PDF
Decomposition of phosphonate esters adsorbed on aluminum oxide
M. K. Templeton and W. Henry Weinberg
pp 774 - 779; DOI:
10.1021/ja00290a006
PDF
Structures of organic cations in the gas phase. Neutral products from fluoride abstraction examined by NMR
Eric W. Redman, Kamalesh K. Johri, and Thomas Hellman Morton
pp 780 - 784; DOI:
10.1021/ja00290a007
PDF
Electron spin-echo modulation studies of doxylstearic acid spin probes in sodium and tetramethylammonium dodecyl sulfate micelles: interaction of the spin probe with deuterated water and with deuterated terminal methyl groups in the surfactant molecules
E. Szajdzinska-Pietek, Rene Maldonado, Larry Kevan, Richard R. M. Jones, and Michael J. Coleman
pp 784 - 788; DOI:
10.1021/ja00290a008
PDF
Anion effects on the kinetics of sodium(1+) ion-18-crown-6 complexation in tetrahydrofuran solutions
Bruce O. Strasser, Klaas Hallenga, and Alexander I. Popov
pp 789 - 792; DOI:
10.1021/ja00290a009
PDF
Conformational analysis by ESR spectroscopy. 3. Radicals derived from cyclohexanone
H. F. Walter, W. T. Beaudry, D. M. Camaioni, and D. W. Pratt
pp 793 - 800; DOI:
10.1021/ja00290a010
PDF
Reductive transformations. 5. Alternative routes for reductive alkylations in liquid ammonia and their selection via spectroscopic evidence
Klaus Muellen, Walter Huber, Gerd Neumann, Christoph Schnieders, and Heinz Unterberg
pp 801 - 807; DOI:
10.1021/ja00290a011
PDF
Picosecond photodissociation of six-coordinate iron(II) porphyrins
Dabney White Dixon, Christine Kirmaier, and Dewey Holten
pp 808 - 813; DOI:
10.1021/ja00290a012
PDF
Copper carbonyls, Cu(CO) and Cu(CO)3: matrix isolation ESR study
Paul H. Kasai and Paul M. Jones
pp 813 - 818; DOI:
10.1021/ja00290a013
PDF
NMR chemical shift and NMR isotope shift evidence for the influence of nonbonded interactions on charge distribution in .alpha.,.beta.-unsaturated methoxycarbenium ions
David A. Forsyth, Virginia M. Osterman, and John R. DeMember
pp 818 - 822; DOI:
10.1021/ja00290a014
PDF
Photochemical rearrangements of o- and m-dichlorobenzene cations to p-dichlorobenzene cation in solid argon
Ronald S. Friedman and Lester Andrews
pp 822 - 826; DOI:
10.1021/ja00290a015
PDF
Valence transitions in cis- and trans-hexatrienes
Ruth McDiarmid, A. Sabljic, and J. P. Doering
pp 826 - 829; DOI:
10.1021/ja00290a016
PDF
Electronegativity equalization: application and parametrization
Wilfried J. Mortier, Karin Van Genechten, and Johann Gasteiger
pp 829 - 835; DOI:
10.1021/ja00290a017
PDF
Theoretical study of the ground and excited singlet states of styrene
R. J. Hemley, U. Dinur, V. Vaida, and Martin Karplus
pp 836 - 844; DOI:
10.1021/ja00290a018
PDF
Dependence of carbon-carbon and carbon-hydrogen bond activation on d band position: acetylene on platinum(111) and iron(100). An electrochemical model
S. P. Mehandru and Alfred B. Anderson
pp 844 - 849; DOI:
10.1021/ja00290a019
PDF
Aromatic stability of heterocyclic conjugated systems
M. Randic, N. Trinajstic, J. V. Knop, and Z. Jericevic
pp 849 - 859; DOI:
10.1021/ja00290a020
PDF
MNDO and ab initio study of the mechanism of organolithium amination by lithium alkoxyamides
Michael L. McKee
pp 859 - 864; DOI:
10.1021/ja00290a021
PDF
Ab initio second-order Moeller-Plesset calculation of the vibrational spectrum of tetrahedrane
B. Andes Hess and L. J. Schaad
pp 865 - 866; DOI:
10.1021/ja00290a022
PDF
Trimethylenemethane dianion and the controversial notion of Y-aromaticity
Israel Agranat and Anne Skancke
pp 867 - 871; DOI:
10.1021/ja00290a023
PDF
The potential dependence of electrical conductivity and chemical charge storage of poly(pyrrole) films on electrodes
B. J. Feldman, Paul Burgmayer, and Royce W. Murray
pp 872 - 878; DOI:
10.1021/ja00290a024
PDF
Charge density topological approach to the dinorcaradiene .dblharw. [10]annulene equilibrium in some 11,11-disubstituted 1,6-methano[10]annulenes
Carlo Gatti, Mario Barzaghi, and Massimo Simonetta
pp 878 - 887; DOI:
10.1021/ja00290a025
PDF
Electrochemical reduction and reoxidation accompanied by reversible geometric isomerization. Electrochemistry of bis(dicarbonyl-.mu.-di-tert-butylphosphidorhodium). Isolation and x-ray crystal structure of bis(tetra-n-butylammonium) bis(dicarbonyl-.mu.-di-tert-butylphosphidorhodate)
John G. Gaudiello, Thomas C. Wright, Richard A. Jones, and Allen J. Bard
pp 888 - 897; DOI:
10.1021/ja00290a026
PDF
Synthesis and characterization of blocked and ligand-appended hemes derived from atropisomeric meso-diphenylporphyrins
Richard Young and Chris K. Chang
pp 898 - 909; DOI:
10.1021/ja00290a027
PDF
Hexacyclen complexes of inorganic anions. 2. Bonding forces, structures, and selectivity
Robert I. Gelb, Brenda T. Lee, and Leverett J. Zompa
pp 909 - 916; DOI:
10.1021/ja00290a028
PDF
Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties
Jeremy M. Berg and R. H. Holm
pp 917 - 925; DOI:
10.1021/ja00290a029
PDF
Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis
Jeremy M. Berg and R. H. Holm
pp 925 - 932; DOI:
10.1021/ja00290a030
PDF
Synthesis, structural characterization, and stereospecificity in the formation of bimetallic rhodacarborane clusters containing rhodium-hydrogen-boron bridge interactions
Paul E. Behnken, Todd B. Marder, R. Thomas Baker, Carolyn B. Knobler, Michael R. Thompson, and M. Frederick Hawthorne
pp 932 - 940; DOI:
10.1021/ja00290a031
PDF
Solution synthesis and crystallographic characterization of the divalent organosamarium complexes (C5Me5)2Sm(THF)2 and [(C5Me5)Sm(.mu.-I)(THF)2]2
William J. Evans, Jay W. Grate, Henry W. Choi, Ira Bloom, William E. Hunter, and Jerry L. Atwood
pp 941 - 946; DOI:
10.1021/ja00290a032
PDF
Hydrolysis chemistry of the metallocene dichlorides M(.eta.5-C5H5)2Cl2, M = titanium, vanadium, or zirconium. Aqueous kinetics, equilibria, and mechanistic implications for a new class of antitumor agents
Jeffrey H. Toney and Tobin J. Marks
pp 947 - 953; DOI:
10.1021/ja00290a033
PDF
Metastable iron/sulfur clusters. The synthesis, electronic structure, and transformations of the [Fe6S6(L)6]3- clusters (L = Cl-, Br, I-, RS-, RO-) and the structure of [(C2H5)4N]3[Fe6S6Cl6]
M. G. Kanatzidis, W. R. Hagen, W. R. Dunham, R. K. Lester, and Dimitri K. Coucouvanis
pp 953 - 961; DOI:
10.1021/ja00290a034
PDF
Molecular free surface: a novel method of calculation and its uses in conformational studies and in organic crystal chemistry
A. Gavezzotti
pp 962 - 967; DOI:
10.1021/ja00290a035
PDF
Photochemical disproportionation of bis(.eta.5-methylcyclopentadienyl)dimolybdenum hexacarbonyl by halides
Albert E. Stiegman and David R. Tyler
pp 967 - 971; DOI:
10.1021/ja00290a036
PDF
Novel and convenient method for the stereo- and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes
Norio Miyaura, Kinji Yamada, Hiroshi Suginome, and Akira Suzuki
pp 972 - 980; DOI:
10.1021/ja00290a037
PDF
Trifluoroethylidynesulfur trifluoride, CF3C.tplbond.SF3, and its dimer
Brigitte Poetter, Konrad Seppelt, Arndt Simon, Eva Maria Peters, and Bernhard Hettich
pp 980 - 985; DOI:
10.1021/ja00290a038
PDF
Comparative study of nucleophilic addition to free and metal-coordinated carbocations
T. J. Alavosus and D. A. Sweigart
pp 985 - 987; DOI:
10.1021/ja00290a039
PDF
Electrophilic cleavage of cyclopropanes. Acetolysis of alkylcyclopropanes
Kenneth B. Wiberg and Steven R. Kass
pp 988 - 995; DOI:
10.1021/ja00290a040
PDF
Electrophilic cleavage of cyclopropanes. Acetolysis of bicyclo[2.1.0]pentane and bicyclo[3.1.0]hexane
Kenneth B. Wiberg, Steven R. Kass, and K. C. Bishop
pp 996 - 1002; DOI:
10.1021/ja00290a041
PDF
Electrophilic cleavage of cyclopropanes. Acetolysis of bicyclic and tricyclic cyclopropanes
Kenneth B. Wiberg, Steven R. Kass, Armin De Meijere, and K. C. Bishop
pp 1003 - 1007; DOI:
10.1021/ja00290a042
PDF
Stable simple enols. 8. Synthesis and keto .dblharw. enol equilibria of the elusive 2,2-dimesitylethanal and 1,2,2-trimesitylethanone. Conformations of 1,2,2-trimesitylethanone and 1,2,2-trimesitylethanol
Silvio E. Biali and Zvi Rappoport
pp 1007 - 1015; DOI:
10.1021/ja00290a043
PDF
Carbocation behavior in norbornyl-fused norbornyl systems. The kinetic and chemical consequences of fusing two norbornane units across framework bonds of various type
Leo A. Paquette, George DeLucca, Katsuo Ohkata, and Judith C. Gallucci
pp 1015 - 1023; DOI:
10.1021/ja00290a044
PDF
Photoresponsive molecular tweezers. Photoregulated ion capture and release using thioindigo derivatives having ethylenedioxy side groups
Masahiro Irie and Masatoshi Kato
pp 1024 - 1028; DOI:
10.1021/ja00290a045
PDF
On a tandem 1,2-elimination/[1,7]-sigmatropic shift: synthesis of double bond shifted isomers of vitamin A
Yeshpal S. Chauhan, Roshantha A. S. Chandraratna, Donald A. Miller, Richard W. Kondrat, Wolfgang Reischl, and William H. Okamura
pp 1028 - 1033; DOI:
10.1021/ja00290a046
PDF
Allenyldiene electrocyclization, a stereospecific tandem center-axis-center chirality transfer: synthesis of drimatrienes and related trans-decalins
William H. Okamura, Roland Peter, and Wolfgang Reischl
pp 1034 - 1041; DOI:
10.1021/ja00290a047
PDF
Divalent metal ion catalysis in the hydrolysis of esters of picolinic acid. Metal ion promoted hydroxide ion and water catalyzed reactions
Thomas H. Fife and Theodore J. Przystas
pp 1041 - 1047; DOI:
10.1021/ja00290a048
PDF
Models for the interaction of zinc(2+) ion with DNA. The synthesis and x-ray structural characterization of two octahedral zinc complexes with monomethyl phosphate esters of 6-oxopurine 5'-monophosphate nucleotides
Sandra K. Miller, Donald G. VanDerveer, and Luigi G. Marzilli
pp 1048 - 1055; DOI:
10.1021/ja00290a049
PDF
Synthesis and crystal structure of the bismuth-iron carbonyl cluster [Et4N]2[Bi4Fe4(CO)13]. Discovery of a hybrid Zintl-metal carbonyl cluster
Kenton H. Whitmire, Melvyn Rowen Churchill, and James C. Fettinger
pp 1056 - 1057; DOI:
10.1021/ja00290a050
PDF
Kinetically stable conformers of 3,4,5,6-tetramethyl-9,10-dihydroxy-9,10-dihydrophenanthrene as probes of the conformer specificity of UDPglucuronosyltransferase
Richard N. Armstrong, Deborah A. Lewis, Herman L. Ammon, and Satya M. Prasad
pp 1057 - 1058; DOI:
10.1021/ja00290a051
PDF
Calculation of substrate dissociation constants from steady-state isotope effects in enzyme-catalyzed reactions
Judith P. Klinman and Rowena G. Matthews
pp 1058 - 1060; DOI:
10.1021/ja00290a052
PDF
Two-alkyne annulations of transition-metal carbene complexes via in situ generated vinyl carbene complexes
William D. Wulff, Ralph W. Kaesler, Glen A. Peterson, and Peng Cho Tang
pp 1060 - 1062; DOI:
10.1021/ja00290a053
PDF
A tungsten-bismuth cluster featuring dibismuth as a four-electron donor and a bridging bismuthinidene
Atta M. Arif, Alan H. Cowley, Nicholas C. Norman, and Marek Pakulski
pp 1062 - 1063; DOI:
10.1021/ja00290a054
PDF
Meso deuterium NMR hyperfine shift as a probe for determining five- or six-coordination at heme iron binding site in ferric high-spin hemoproteins
Isao Morishima, Yoshitsugu Shiro, and Tomoyuki Wakino
pp 1063 - 1065; DOI:
10.1021/ja00290a055
PDF
Biosynthesis of clavulanic acid: origin of the C5 unit
Craig A. Townsend and Meng Fei Ho
pp 1065 - 1066; DOI:
10.1021/ja00290a056
PDF
Biosynthesis of clavulanic acid: origin of the C3 unit
Craig A. Townsend and Meng Fei Ho
pp 1066 - 1068; DOI:
10.1021/ja00290a057
PDF
Detailed rate studies on the Wittig reaction of nonstabilized phosphorus ylides via phosphorus-31, proton, carbon-13 NMR spectroscopy. Insight into kinetic vs. thermodynamic control of stereochemistry
Bruce E. Maryanoff, Allen B. Reitz, Martin S. Mutter, Ruth R. Inners, and Harold R. Almond
pp 1068 - 1070; DOI:
10.1021/ja00290a058
PDF
Species specificity of long-range electron transfer within the complex between zinc-substituted cytochrome c peroxidase and cytochrome c
Pui Shing Ho, Carol Sutoris, Nong Liang, E. Margoliash, and Brian M. Hoffman
pp 1070 - 1071; DOI:
10.1021/ja00290a059
PDF
Coupling of acyl and iminoacyl groups on zirconium and .sigma.2,.pi.-coordination of the resulting enamidolate ligand
Anne K. McMullen, Ian P. Rothwell, and John C. Huffman
pp 1072 - 1073; DOI:
10.1021/ja00290a060
PDF
Mechanistic and exploratory organic photochemical series. 142. Dynamic isotopic dilution as a general method for ascertaining partition of photochemical pathways potentially utilizing nondiscernible intermediates: application to a new reaction
Howard E. Zimmerman, Clint W. Carpenter, and Andrew M. Weber
pp 1073 - 1075; DOI:
10.1021/ja00290a061
PDF
Donor stereospecificity of palladium-mediated cycloadditions. A case of distal attack of acceptor on donor
Barry M. Trost and Thomas N. Nanninga
pp 1075 - 1076; DOI:
10.1021/ja00290a062
PDF
Competing pathways in the photolysis of bicyclo[1.1.0]butane
Alan F. Becknell, Jerome A. Berson, and R. Srinivasan
pp 1076 - 1078; DOI:
10.1021/ja00290a063
PDF
Unique structural features of a hexarhodium-.mu.4-tert-butylarsinidene complex, formed via arsenic-carbon bond cleavage. Synthesis and structure of a hexarhodium pentagonal pyramid: Rh6(CO)9(.mu.-CO)2(.mu.-tert-Bu2As)2(.mu.4-tert-BuAs)
Richard A. Jones and Bruce R. Whittlesey
pp 1078 - 1079; DOI:
10.1021/ja00290a064
PDF
Evidence for two different radical cation types derived from methylenecyclopropane
Tsutomu Miyashi, Yasutake Takahashi, Toshio Mukai, Heinz D. Roth, and Marcia L. M. Schilling
pp 1079 - 1080; DOI:
10.1021/ja00290a065
PDF
Dependence of rate constants for photoinduced charge separation and dark charge recombination on the free energy of reaction in restricted-distance porphyrin-quinone molecules
Michael R. Wasielewski, Mark P. Niemczyk, Walter A. Svec, and E. Bradley Pewitt
pp 1080 - 1082; DOI:
10.1021/ja00290a066
PDF
1,8-biphenylenediol is a double-hydrogen-bonding catalyst for reaction of an epoxide with a nucleophile
Jack Hine, Shwn Meei Linden, and V. M. Kanagasabapathy
pp 1082 - 1083; DOI:
10.1021/ja00290a067
PDF
Recognition of NMR proton spin systems of cyclosporin A via heteronuclear proton-carbon long-range couplings
Horst Kessler, Wolfgang Bermel, and Christian Griesinger
pp 1083 - 1084; DOI:
10.1021/ja00290a068
PDF
An unusual CIDEP observation in the photochemical reactions of benzophenone and ascorbyl palmitate: the elusive neutral ascorbate radical
Marjory T. Craw, M. Catherine Depew, and Jeffrey K. S. Wan
pp 1084 - 1085; DOI:
10.1021/ja00290a069
PDF
Aggregation of a bacteriochlorophyllide d: direct evidence for a nonsymmetric aggregate in solution
Raymond J. Abraham, Kevin M. Smith, Dane A. Goff, and Frank W. Bobe
pp 1085 - 1087; DOI:
10.1021/ja00290a070
PDF
Photoreactivities of o-alkoxy- and o-tert-butylphenyl ketones: a dramatic example of conformational inversion of selectivity
Peter J. Wagner, Michael A. Meador, B. P. Giri, and J. C. Scaiano
pp 1087 - 1088; DOI:
10.1021/ja00290a071
PDF
The synthesis and structure of the first 10-As-3 species
Scott Anthony Culley and Anthony J. Arduengo
pp 1089 - 1090; DOI:
10.1021/ja00290a072
PDF
Book Reviews

pp 1091 - 1092; DOI:
10.1021/ja00290a600
PDF

Issue 5


Gas-phase reactions of anions with methyl formate and N,N-dimethylformamide
Charles H. DePuy, Joseph J. Grabowski, Veronica M. Bierbaum, Steen Ingemann, and Nico M. M. Nibbering
pp 1093 - 1098; DOI:
10.1021/ja00291a001
PDF
Laboratory experiments on the interstellar species oxomethylium ([HCO]+) and hydroxymethyliumylidene ([COH]+)
Peter C. Burgers, John L. Holmes, and Alexander A. Mommers
pp 1099 - 1101; DOI:
10.1021/ja00291a002
PDF
Influence of micellization on complexing properties of amphiphilic ligands toward metal ions
Yves Chevalier and Claude Chachaty
pp 1102 - 1107; DOI:
10.1021/ja00291a003
PDF
Correlation between the iron-histidine stretching frequencies and oxygen affinity of hemoglobins. A continuous strain model
S. Matsukawa, K. Mawatari, Y. Yoneyama, and T. Kitagawa
pp 1108 - 1113; DOI:
10.1021/ja00291a004
PDF
Mechanism of fast intramolecular electron-transfer reactions
Edward M. Kosower
pp 1114 - 1118; DOI:
10.1021/ja00291a005
PDF
Computation of molecular volume
Michael L. Connolly
pp 1118 - 1124; DOI:
10.1021/ja00291a006
PDF
DNMR and molecular mechanics studies of the enantiomerization of long-chain (1,5)-naphthalenophanes
Moon Ho Chang, Brian B. Masek, and Dennis A. Dougherty
pp 1124 - 1133; DOI:
10.1021/ja00291a007
PDF
Proximity effect and excited-state dynamics of 9-carbonyl-substituted anthracenes
T. I. Lai and Edward C. Lim
pp 1134 - 1137; DOI:
10.1021/ja00291a008
PDF
Photochemistry and photophysics of bis(terpyridyl) complexes of ruthenium(II) in fluid solution. Evidence for the formation of an .eta.2-diphenylterpyridine complex
Jon R. Kirchhoff, David R. McMillin, Pascal A. Marnot, and Jean Pierre Sauvage
pp 1138 - 1141; DOI:
10.1021/ja00291a009
PDF
Quenching studies of *Cu(dpp)2+. Evidence for competitive electron-transfer and energy-transfer quenching by Cr(acac)3 derivatives
Roland E. Gamache, Rosemary A. Rader, and David R. McMillin
pp 1141 - 1146; DOI:
10.1021/ja00291a010
PDF
Modes of rearrangements in cis-M(AB)2XY six-coordinate bis chelate complexes 1. A theoretical study of the possibilities of 1D and 2D NMR
Rudolph Willem, Marcel Gielen, Henri Pepermans, Jean Brocas, Daniel Fastenakel, and Paolo Finocchiaro
pp 1146 - 1152; DOI:
10.1021/ja00291a011
PDF
Modes of rearrangements in cis-M(AB)2XY six-coordinate bis chelate complexes. 2. An experimental 2D NMR study of phenylchlorobis(benzoylacetonato)tin
Rudolph Willem, Marcel Gielen, Henri Pepermans, Klaas Hallenga, Antonino Recca, and Paolo Finocchiaro
pp 1153 - 1160; DOI:
10.1021/ja00291a012
PDF
Hartree-Fock MO theoretical approach to aromaticity. Interpretation of Hueckel resonance energy in terms of kinetic energy of .pi. electron
Hiroshi Ichikawa and Yukiko Ebisawa
pp 1161 - 1165; DOI:
10.1021/ja00291a013
PDF
Role of electrostatics in the structure, energy and dynamics of biomolecules: a model study of N-methylalanylacetamide
B. Montgomery Pettitt and Martin Karplus
pp 1166 - 1173; DOI:
10.1021/ja00291a014
PDF
Properties of some possible intermediate stages in the nitration of benzene and toluene
Peter Politzer, Keerthi Jayasuriya, Per Sjoberg, and Patricia R. Laurence
pp 1174 - 1177; DOI:
10.1021/ja00291a015
PDF
Factors favoring an M...H-C interaction in metal-methyl complexes. An MO analysis
Odile Eisenstein and Y. Jean
pp 1177 - 1186; DOI:
10.1021/ja00291a016
PDF
Ab initio study of the reaction of silene with formaldehyde
Steven M. Bachrach and Andrew Streitwieser
pp 1186 - 1190; DOI:
10.1021/ja00291a017
PDF
Stability of the reaction coordinate in the unimolecular reaction of thioformaldehyde
Akitomo Tachibana, Iwao Okazaki, Masahiko Koizumi, Kenzi Hori, and Tokio Yamabe
pp 1190 - 1196; DOI:
10.1021/ja00291a018
PDF
Synthesis of perfluoropolyethers via hydrocarbon polyesters: a new general method
D. F. Persico, G. E. Gerhardt, and R. J. Lagow
pp 1197 - 1201; DOI:
10.1021/ja00291a019
PDF
Synthesis and molecular and crystal structure of bis(borane)cyclenphosphorane. First stable compound with a bipyramidally surrounded element having two quaternized apical nitrogen atoms
Jean-Marc Dupart, Guy Le Borgne, Simonne Pace, and Jean G. Riess
pp 1202 - 1205; DOI:
10.1021/ja00291a020
PDF
A theoretical basis for low barriers in transition-metal complex 2.pi. + 2.pi. reactions: the isomerization of the dicyclopentadienyltitanium complex Cp2TiC3H6 to Cp2TiCH2(C2H4)
T. H. Upton and A. K. Rappe
pp 1206 - 1218; DOI:
10.1021/ja00291a021
PDF
A mechanistic study of the photochemically initiated oxidative addition of isopropyl iodide to dimethyl(1,10-phenanthroline)platinum(II)
Ross H. Hill and Richard J. Puddephatt
pp 1218 - 1225; DOI:
10.1021/ja00291a022
PDF
Electronic effects in transition-metal porphyrins. 6. The effect of unsymmetrical phenyl substitution on the formation constants of a series of (tetraphenylporphinato)iron(III)-bis(N-methylimidazole) complexes
Virginia L. Balke, F. Ann Walker, and Joyce T. West
pp 1226 - 1233; DOI:
10.1021/ja00291a023
PDF
Metal alkoxides: models for metal oxides. 7. Trinuclear and tetranuclear alkylidyne clusters of tungsten supported by alkoxide ligands
Malcolm H. Chisholm, Kirsten Folting, Joseph A. Heppert, David M. Hoffman, and John C. Huffman
pp 1234 - 1241; DOI:
10.1021/ja00291a024
PDF
Interconversions of .eta.5-cyclopentadienyl, .eta.1-cyclopentadienyl, and ionic ".eta.0"-cyclopentadienyl rhenium compounds - x-ray crystal structure of tetrakis(trimethylphosphine)methylnitrosylrhenium cyclopentadienide
Charles P. Casey, Joseph M. O'Connor, and Kenneth J. Haller
pp 1241 - 1246; DOI:
10.1021/ja00291a025
PDF
On the scope, mechanism and stereochemistry of the Lewis acid catalyzed cyclocondensation of activated dienes with aldehydes: an application to the erythronolide problem
Samuel Danishefsky, Eric Larson, David Askin, and Nobuo Kato
pp 1246 - 1255; DOI:
10.1021/ja00291a026
PDF
Chelation-controlled facially selective cyclocondensation reactions of chiral alkoxy aldehydes: syntheses of a mouse androgen and of a carbon-linked disaccharide
Samuel J. Danishefsky, William H. Pearson, Daniel F. Harvey, Clarence J. Maring, and James P. Springer
pp 1256 - 1268; DOI:
10.1021/ja00291a027
PDF
A new approach to the synthesis of hexoses: an entry to (.+-.)-fucose and (.+-.)-daunosamine
Samuel Danishefsky and Clarence Maring
pp 1269 - 1274; DOI:
10.1021/ja00291a028
PDF
A totally synthetic route to lincosamine: some observations on the diastereofacial selectivity of electrophilic reactions on the double bonds of various 5-(1-alkenyl)arabinopyranosides
Samuel Danishefsky, Eric Larson, and James Springer
pp 1274 - 1280; DOI:
10.1021/ja00291a029
PDF
Total synthesis of (.+-.)-3-deoxy-D-manno-2-octulopyranosate
Samuel J. Danishefsky, William H. Pearson, and Brigitte E. Segmuller
pp 1280 - 1285; DOI:
10.1021/ja00291a030
PDF
Total synthesis of vineomycinone B2 methyl ester
Samuel Danishefsky, Biing Jiun Uang, and George Quallich
pp 1285 - 1293; DOI:
10.1021/ja00291a031
PDF
Palladium-mediated cycloaddition approach to loganin aglucon
Barry M. Trost and Thomas N. Nanninga
pp 1293 - 1299; DOI:
10.1021/ja00291a032
PDF
Exciton approach to the optical activity of C3-cyclotriveratrylene derivatives
Josette Canceill, Andre Collet, Jacqueline Gabard, Giovanni Gottarelli, and Gian Piero Spada
pp 1299 - 1308; DOI:
10.1021/ja00291a033
PDF
Stereoelectronic effects in the cationic rearrangements of [4.3.2]propellanes
Amos B. Smith, Barry A. Wexler, Chin Yun Tu, and Joseph P. Konopelski
pp 1308 - 1320; DOI:
10.1021/ja00291a034
PDF
The unusual reactivity of hydroxymethylene
Sheikh N. Ahmed, Michael L. McKee, and Philip B. Shevlin
pp 1320 - 1324; DOI:
10.1021/ja00291a035
PDF
Passage of aryl-tipped alkyl groups through molecular cavities: the role of flexibility
Barbara J. Whitlock and Howard W. Whitlock
pp 1325 - 1329; DOI:
10.1021/ja00291a036
PDF
Photochemistry of 1-azatriptycene
Tadashi Sugawara and Hiizu Iwamura
pp 1329 - 1339; DOI:
10.1021/ja00291a037
PDF
Equilibrium constants for the interconversion of substituted 1-phenylethyl alcohols and ethers. A measurement of intramolecular electrostatic interactions
Marc E. Rothenberg, John P. Richard, and William P. Jencks
pp 1340 - 1346; DOI:
10.1021/ja00291a038
PDF
Preparation and dimerization of 1,2,4,6-thiatriazinyl radicals; crystal and molecular structure of bis(3,5-diphenyl-1,2,4,6-thiatriazine)
Patrick J. Hayes, Richard T. Oakley, A. Wallace Cordes, and William T. Pennington
pp 1346 - 1351; DOI:
10.1021/ja00291a039
PDF
Stereochemistry of the concerted SN2' reaction of 3-chloropropene: a theoretical study
Robert D. Bach and Gregory J. Wolber
pp 1352 - 1357; DOI:
10.1021/ja00291a040
PDF
Catalytic reaction on both sides of a metalloporphyrin plane. Alternating copolymerization of phthalic anhydride and epoxypropane with an aluminum porphyrin-quaternary salt system
Takuzo Aida and Shohei Inoue
pp 1358 - 1364; DOI:
10.1021/ja00291a041
PDF
Selective monomethyl esterification of dicarboxylic acids by use of monocarboxylate chemisorption on alumina
Haruo Ogawa, Teiji Chihara, and Kazuo Taya
pp 1365 - 1369; DOI:
10.1021/ja00291a042
PDF
.alpha.- and .beta.-Carboxylic groups as primary ligating groups in promoting amide deprotonation. Solid-state behavior of N-tosylalaninate-copper(II) complexes: crystal and molecular structures of bis(N-tosyl-.beta.-alaninato)bis(imidazole)copper(II), polymeric (N-tosyl-.alpha.-alaninato)diaquacopper(II) monohydrate, and dipiperidinium bis(N-tosyl-.alpha.-alaninato)cuprate(II) monohydrate complexes
L. Antolini, L. P. Battaglia, A. Bonamartini Corradi, G. Marcotrigiano, L. Menabue, and G. C. Pellacani
pp 1369 - 1375; DOI:
10.1021/ja00291a043
PDF
Capture of electron-deficient species with aryl halides. New syntheses of hypervalent iodonium ylides
Robert M. Moriarty, B. R. Bailey, O. Prakash, and Indra Prakash
pp 1375 - 1378; DOI:
10.1021/ja00291a044
PDF
Steric hindrance to benzocyclobutene openings. First synthesis of a 1,2,3-tris(trimethylsilylated) arene by cobalt-catalyzed alkyne cyclizations and application of fully coupled two-dimensional chemical shift correlations to a structural problem
Ronald L. Halterman, Nhan H. Nguyen, and K. Peter C. Vollhardt
pp 1379 - 1387; DOI:
10.1021/ja00291a045
PDF
Base-induced proton tautomerism in the primary photocyclization product of stilbenes
J. B. M. Somers, A. Couture, A. Lablache-Combier, and W. H. Laarhoven
pp 1387 - 1394; DOI:
10.1021/ja00291a046
PDF
Structural studies of a new antitumor and antiviral agent: selenazofurin and its .alpha. anomer
Barry M. Goldstein, Fusao Takusagawa, Helen W. Berman, Prem C. Srivastava, and Roland K. Robins
pp 1394 - 1400; DOI:
10.1021/ja00291a047
PDF
Conformational analysis of a cyclic pentapeptide by one- and two-dimensional nuclear Overhauser effect spectroscopy
Martha D. Bruch, Joseph H. Noggle, and Lila M. Gierasch
pp 1400 - 1407; DOI:
10.1021/ja00291a048
PDF
Relative sulfur-36-sulfur-34 kinetic isotope effects
Piotr Paneth and Wladyslaw Reimschuessel
pp 1407 - 1408; DOI:
10.1021/ja00291a049
PDF
Sulfur-34, sulfur-36, and oxygen-18 isotope effects on phosphorus-31 chemical shifts in thiophosphate anhydrides
C. Roeske, Piotr Paneth, M. H. O'Leary, and Wladyslaw Reimschuessel
pp 1409 - 1411; DOI:
10.1021/ja00291a050
PDF
Organometallic nitrosyl chemistry. 23. Novel 16-electron organometallic complexes of molybdenum and tungsten: (.eta.5-C5H5)M(NO)(alkyl)2
Peter Legzdins, Steven J. Rettig, Luis Sanchez, Bruce E. Bursten, and Michael G. Gatter
pp 1411 - 1413; DOI:
10.1021/ja00291a051
PDF
X-ray photoelectron spectra of methyllithium and dilithiomethane
Gregory F. Meyers, Michael B. Hall, John W. Chinn, and Richard J. Lagow
pp 1413 - 1414; DOI:
10.1021/ja00291a052
PDF
Resonance Raman spectra of ground and low-lying excited states of ruthenium(II) pentaammine pyridine derivatives
Y. C. Chung, N. Leventis, Peter J. Wagner, and G. E. Leroi
pp 1414 - 1416; DOI:
10.1021/ja00291a053
PDF
Resonance Raman spectra of ground and lowest excited electronic states of some ruthenium(II) mixed-ligand complexes
Y. C. Chung, N. Leventis, Peter J. Wagner, and G. E. Leroi
pp 1416 - 1417; DOI:
10.1021/ja00291a054
PDF
Studies of enzyme stereochemistry. Elucidation of the stereochemistry of the reaction catalyzed by S-adenosylhomocysteine hydrolase
Ronald J. Parry and Leslie J. Askonas
pp 1417 - 1418; DOI:
10.1021/ja00291a055
PDF
Microporous aluminum oxide films at electrodes
Cary J. Miller and Marcin Majda
pp 1419 - 1420; DOI:
10.1021/ja00291a056
PDF
Hydride sponge: 1,8-naphthalenediylbis(dimethylborane)
Howard Edan Katz
pp 1420 - 1421; DOI:
10.1021/ja00291a057
PDF
Total synthesis of quinocarcinol methyl ester
Samuel J. Danishefsky, Peter J. Harrison, Robert R. Webb, and Brian T. O'Neill
pp 1421 - 1423; DOI:
10.1021/ja00291a058
PDF
Synthesis of (+)-antimycin A3. Use of the oxazole ring in protecting and activating functions
Harry H. Wasserman and Ronald J. Gambale
pp 1423 - 1424; DOI:
10.1021/ja00291a059
PDF
An extremely efficient method for one-pot, three-component, 2 + 2 + 2 construction of functionalized cyclohexenes
Gary H. Posner and Shu Bin Lu
pp 1424 - 1426; DOI:
10.1021/ja00291a060
PDF
Barrier to coupled internal rotation in bis(9-triptycyl) ether. Kinetics of intramolecular exciplex formation in racemic 2,3-benzo-9-triptycyl 2-(N,N-dimethylaminomethyl)-9-triptycyl ether
Noboru Koga and Hiizu Iwamura
pp 1426 - 1427; DOI:
10.1021/ja00291a061
PDF
Novel nucleophilic substitution reaction by radical cation intermediates. Photosensitized transacetalization via SON1 mechanism
S. Hashimoto, I. Kurimoto, Y. Fujii, and R. Noyori
pp 1427 - 1429; DOI:
10.1021/ja00291a062
PDF
Ester homologation via .alpha.-bromo .alpha.-keto dianion rearrangement
Conrad J. Kowalski, M. Serajul Haque, and Kevin W. Fields
pp 1429 - 1430; DOI:
10.1021/ja00291a063
PDF
Excited-state properties of a triply ortho-metalated iridium(III) complex
K. A. King, P. J. Spellane, and Richard J. Watts
pp 1431 - 1432; DOI:
10.1021/ja00291a064
PDF
Gas-phase photofragmentation of chromium hexacarbonyl: time-resolved infrared spectrum and decay kinetics of "naked" chromium pentacarbonyl
T. A. Seder, Stephen P. Church, A. J. Ouderkirk, and Eric Weitz
pp 1432 - 1433; DOI:
10.1021/ja00291a065
PDF
Isotopic multiplets in the carbon-13 NMR spectra of partially deuterated ammonium derivatives. Spectral effects of isotopic asymmetry at a nitrogen atom
Jacques Reuben
pp 1433 - 1435; DOI:
10.1021/ja00291a066
PDF
Stereoelectronic controlling features of allylic asymmetry. Application to ester enolate alkylations
Glenn J. McGarvey and J. Michael Williams
pp 1435 - 1437; DOI:
10.1021/ja00291a067
PDF
Effect of temperature on the transport capabilities of some common ionophores
Charles J. Thoman
pp 1437 - 1438; DOI:
10.1021/ja00291a068
PDF
A new synthetic strategy for the penems. Total synthesis of (5R,6S,8R)-6-(.alpha.-hydroxyethyl)-2-(hydroxymethyl)penem-3-carboxylic acid
Stephen Hanessian, Angelo Bedeschi, Carlo Battistini, and Nicola Mongelli
pp 1438 - 1439; DOI:
10.1021/ja00291a069
PDF
Molecular and electronic structures of metallaspiropentanes
Mark S. Gordon and Philip Boudjouk
pp 1439 - 1440; DOI:
10.1021/ja00291a070
PDF
Stereoselective acyclic enolate formation via conjugate reduction: correlation with enone conformational preferences
A. Richard Chamberlin and Siegfried H. Reich
pp 1440 - 1441; DOI:
10.1021/ja00291a071
PDF
Picosecond dynamics of the excited trans-stilbene/fumaronitrile charge-transfer complex
Joshua L. Goodman and Kevin S. Peters
pp 1441 - 1442; DOI:
10.1021/ja00291a072
PDF
Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst
Gregory F. Schmidt and Maurice Brookhart
pp 1443 - 1444; DOI:
10.1021/ja00291a073
PDF
Penem synthesis through C3-N ring closure of a .beta.-lactam precursor
Harry H. Wasserman and William T. Han
pp 1444 - 1446; DOI:
10.1021/ja00291a074
PDF
Dynamic NMR and molecular mechanics study of the rotation of a 1-adamantyl, a 1-bicyclooctyl, a 1-norbornyl, and a tert-butyl group. The relative size of an adamantyl group. The dilemma of calculated barriers to rotation
J. E. Anderson, H. Pearson, and D. I. Rawson
pp 1446 - 1447; DOI:
10.1021/ja00291a075
PDF
Isolation and characterization of iron methylene (FeCH2) via FTIR matrix isolation
Sou Chan Chang, Zakya H. Kafafi, Robert H. Hauge, W. Edward Billups, and John L. Margrave
pp 1447 - 1448; DOI:
10.1021/ja00291a076
PDF
Tandem radical approach to linear condensed cyclopentanoids. Total synthesis of (.+-.)-hirsutene
Dennis P. Curran and Donna M. Rakiewicz
pp 1448 - 1449; DOI:
10.1021/ja00291a077
PDF
Ab initio study of the infrared spectrum of methylenecyclopropene
B. Andre Hess, D. Michalska, and Laurence J. Schaad
pp 1449 - 1450; DOI:
10.1021/ja00291a078
PDF
Electron transfer processes. 33. An inverted reactivity series in the reaction of tert-butyl radical with nucleophiles
Glen A. Russell and R. K. Khanna
pp 1450 - 1452; DOI:
10.1021/ja00291a079
PDF
Alkynyl sulfonate esters. Preparation and characterization of acetylenic tosylates, RC.tplbond.COTs
Peter J. Stang and Bruce W. Surber
pp 1452 - 1453; DOI:
10.1021/ja00291a080
PDF
Thermodynamic and kinetic properties of the metaphosphate anion, PO3-, in the gas phase
Michael Henchman, A. A. Viggiano, John F. Paulson, A. Freedman, and J. Wormhoudt
pp 1453 - 1455; DOI:
10.1021/ja00291a081
PDF
Transient ferracyclobutanes during protonation of .eta.3-homoallyliron(0) complexes
Martin F. Semmelhack and Hanh T. M. Le
pp 1455 - 1457; DOI:
10.1021/ja00291a082
PDF
Additions and Corrections - Triplet Exciplex Formation in the External Heavy-Atom Effect
Maria C. Tamargo, and Dwaine O. Cowan
pp 1457 - 1457; DOI:
10.1021/ja00291a600
PDF
Additions and Corrections - Structures and Stabilities of α-Hetero-Substituted Organolithium and Organosodium Compounds. Energetic Unimportance of Second Row d-Orbital Effects
Paul von Rague Schleyer, Timothy Clark, Alexander J. Kos, Gunther W. Spitznagel, Cornelia Rohde, Dorit Arad, K. N. Houk, and Nelson G. Rondan
pp 1457 - 1457; DOI:
10.1021/ja00291a601
PDF
Additions and Corrections - Chain-Folding Initiation Structures in Ribonuclease A: Conformational Analysis of trans-Ac-Asn-Pro-Tyr NHMe and trans-Ac-Tyr-Pro-Asn-NHMe in Water and in the Solid State
G. T. Montelione, E. Arnold, Y. C. Meinwald, E. R. Stimson, J. B. Denton, S.-G. Huang, J. Clardy, and H. A. Scheraga
pp 1457 - 1457; DOI:
10.1021/ja00291a602
PDF
Additions and Corrections - Chain-Folding Initiation Structures in Ribonuclease A: Conformational Free Energy Calculations on Ac-Asn-Pro-Tyr-NHMe, Ac-Tyr-Pro-Asn-NHMe, and Related Peptides
M. Oka, G. T. Montelione, and H. A. Scheraga
pp 1457 - 1457; DOI:
10.1021/ja00291a603
PDF
Book Reviews

pp 1457 - 1458; DOI:
10.1021/ja00291a604
PDF

Issue 6


Catalytic formation of hydrogen and carbon-carbon bonds on illuminated zinc sulfide generated from zinc dithiolenes
N. Zeug, J. Buecheler, and Horst Kisch
pp 1459 - 1465; DOI:
10.1021/ja00292a001
PDF
Kinetic evidence for the formation of the carbene anion radical (EtO2C)2C-.cntdot.
Dean A. Van Galen, Mark P. Young, M. Dale Hawley, and Richard N. McDonald
pp 1465 - 1470; DOI:
10.1021/ja00292a002
PDF
Supercritical carbon dioxide: behavior of .pi.* and .beta. solvatochromic indicators in media of different densities
Michael E. Sigman, Susan M. Lindley, and John E. Leffler
pp 1471 - 1472; DOI:
10.1021/ja00292a003
PDF
Direct electrochemistry of the photosynthetic blue copper protein plastocyanin. Electrostatic promotion of rapid charge transfer at an edge-oriented pyrolytic graphite electrode
Fraser A. Armstrong, H. Allen, O. Hill, B. Nigel Oliver, and David Whitford
pp 1473 - 1476; DOI:
10.1021/ja00292a004
PDF
A comprehensive investigation of the mechanism and photophysics of isomerization of a protonated and unprotonated Schiff base of 11-cis-retinal
Ralph S. Becker and Kenn Freedman
pp 1477 - 1485; DOI:
10.1021/ja00292a005
PDF
Observation of a common intermediate in the photocycloaddition and photocycloreversion of linked anthracenes
Lewis E. Manring, Kevin S. Peters, Guilford Jones, and William R. Bergmark
pp 1485 - 1489; DOI:
10.1021/ja00292a006
PDF
Optimized intermolecular potential functions for amides and peptides. Hydration of amides
William L. Jorgensen and Carol J. Swenson
pp 1489 - 1496; DOI:
10.1021/ja00292a007
PDF
Magnitude and origin of the .beta.-silicon effect on carbenium ions
Scott G. Wierschke, Jayaraman Chandrasekhar, and William L. Jorgensen
pp 1496 - 1500; DOI:
10.1021/ja00292a008
PDF
Novel polycyclic dianions: metal reduction of nitrogen heterocycles
Abraham Minsky, Yoram Cohen, and Mordecai Rabinovitz
pp 1501 - 1505; DOI:
10.1021/ja00292a009
PDF
Mn(CNR)6+/2+ electron self-exchange in acetonitrile. A possible distance dependence for a bimolecular electron-transfer reaction in solution
Roger M. Nielson and Scot Wherland
pp 1505 - 1510; DOI:
10.1021/ja00292a010
PDF
Molecular order and dynamics of liquid-crystal side-chain polymers: an electron spin resonance study employing rigid nitroxide spin probes
Karl Heinz Wassmer, Ernst Ohmes, Michael Portugall, Helmut Ringsdorf, and Gerd Kothe
pp 1511 - 1519; DOI:
10.1021/ja00292a011
PDF
Ultraviolet resonance Raman spectroscopy of the nucleotides with 266-, 240-, 218-, and 200-nm pulsed laser excitation
Stephen P. A. Fodor, Richard P. Rava, Thomas R. Hays, and Thomas G. Spiro
pp 1520 - 1529; DOI:
10.1021/ja00292a012
PDF
Elucidation of cross-relaxation pathways in phospholipid vesicles utilizing two-dimensional proton NMR spectroscopy
Jeffrey F. Ellena, William C. Hutton, and David S. Cafiso
pp 1530 - 1537; DOI:
10.1021/ja00292a013
PDF
Chemical applications of the two-dimensional deuteron-{carbon-13} NMR shift correlation experiment
Joachim R. Wesener and Harald Guenther
pp 1537 - 1540; DOI:
10.1021/ja00292a014
PDF
Acid sites in zeolite Y: a solid-state NMR and infrared study using trimethylphosphine as a probe molecule
Jack H. Lunsford, William P. Rothwell, and Wenxia Shen
pp 1540 - 1547; DOI:
10.1021/ja00292a015
PDF
Vibrational circular dichroism in amino acids and peptides. 9. Carbon-hydrogen stretching spectra of the amino acids and selected transition-metal complexes
M. Reza Oboodi, Brij B. Lal, Daryl A. Young, Teresa B. Freedman, and Laurence A. Nafie
pp 1547 - 1556; DOI:
10.1021/ja00292a016
PDF
Intramolecular selectivity of the alkylation of substituted anilines by gaseous cations
Marina Attina, Fulvio Cacace, and Giulia De Petris
pp 1556 - 1561; DOI:
10.1021/ja00292a017
PDF
Transient absorption and two-step laser excitation fluorescence studies of photoisomerization in 2-(2-hydroxyphenyl)benzoxazole and 2-(2-hydroxyphenyl)benzothiazole
Michiya Itoh and Yoshihisa Fujiwara
pp 1561 - 1565; DOI:
10.1021/ja00292a018
PDF
Gas-phase reactions of transition-metal ions with methyl nitrite and nitromethane
C. J. Cassady and B. S. Freiser
pp 1566 - 1573; DOI:
10.1021/ja00292a019
PDF
Gas phase reactions of Group 8-10 transition-metal ions with nitroalkanes
C. J. Cassady and Ben S. Freiser
pp 1573 - 1580; DOI:
10.1021/ja00292a020
PDF
Heteronuclear diatomic transition-metal cluster ions in the gas phase. Reactions of cobalt-iron(1+) ion with hydrocarbons
D. B. Jacobson and Ben S. Freiser
pp 1581 - 1589; DOI:
10.1021/ja00292a021
PDF
Bare tetranuclear transition-metal cluster ions in the gas phase. Reactivity of tetrascandium(1+) ion with small molecules
M. B. Wise, D. B. Jacobson, and Ben S. Freiser
pp 1590 - 1595; DOI:
10.1021/ja00292a022
PDF
Kinetics of the chromium hexacarbonyl and tungsten hexacarbonyl catalyzed water gas shift reaction: photoinitiated formate decomposition as a probe of the catalytic cycle
Bruce H. Weiller, Jian Ping Liu, and Edward R. Grant
pp 1595 - 1604; DOI:
10.1021/ja00292a023
PDF
Kinetic isotope effects for hydrogen abstraction from a series of cycloalkanes and branched alkanes by hydrogen atoms in the gaseous phase
Noboru Fujisaki, Amanz Ruf, and Tino Gaeumann
pp 1605 - 1610; DOI:
10.1021/ja00292a024
PDF
On the role of uniform and mixed sugar puckers in DNA double-helical structures
Shashidhar N. Rao and Peter Kollman
pp 1611 - 1617; DOI:
10.1021/ja00292a025
PDF
Ab initio study of the photodissociation of nitrosoalkanes and nitrosamines
Renzo Cimiraglia, Maurizio Persico, and Jacopo Tomasi
pp 1617 - 1622; DOI:
10.1021/ja00292a026
PDF
Theoretical study of regioselectivity in radical additions to substituted alkenes. 1. Hydrogen addition to ethylene, vinylamine, and vinylborane
F. Delbecq, D. Ilavsky, Nguyen Trong Anh, and J. M. Lefour
pp 1623 - 1631; DOI:
10.1021/ja00292a027
PDF
Investigation of ab initio HF-SCF-CI methods for calculating rotatory strengths in (R)-3-methylcyclobutene
C. F. Chabalowski, G. M. Maggiora, and R. E. Christoffersen
pp 1632 - 1640; DOI:
10.1021/ja00292a028
PDF
Application of the rotating photoelectrode to the detection of an organotransition-metal intermediate. Photoelectrochemical detection of triacetonitrile(.eta.5-cyclopentadienyl)iron(1+) ion
David C. Boyd, David A. Bohling, and Kent R. Mann
pp 1641 - 1644; DOI:
10.1021/ja00292a029
PDF
Intervalence transfer in cyano-bridged bi- and trinuclear ruthenium complexes
Carlo Alberto Bignozzi, Sergio Roffia, and Franco Scandola
pp 1644 - 1651; DOI:
10.1021/ja00292a030
PDF
The iron(III) complex of N-[2-((o-hydroxyphenyl)glycino)ethyl]salicylidenimine. A model complex for the iron(III) environment in the transferrins
Carl J. Carrano, K. Spartalian, G. V. N. Appa Rao, Vincent L. Pecoraro, and M. Sundaralingam
pp 1651 - 1658; DOI:
10.1021/ja00292a031
PDF
Alkyne-induced carbyne-carbyne coupling in the trinuclear bis(carbyne) iron cluster Fe3(CO)9(.mu.3-COC2H5)(.mu.3-CCH3). X-ray structures of Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] and Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(CH3)C(OC2H5)C(Si(CH3)3)C(Si(CH3)3)]
Didier Nuel, Francoise Dahan, and Rene Mathieu
pp 1658 - 1664; DOI:
10.1021/ja00292a032
PDF
Cobalt-mediated synthesis of tricyclic dienes incorporating fused four-membered rings. Unprecedented rearrangements and structural characterization of a cobalt-diene complex by two-dimensional NMR spectroscopy
Elisabet Dunach, Ronald L. Halterman, and K. Peter C. Vollhardt
pp 1664 - 1671; DOI:
10.1021/ja00292a033
PDF
Organolanthanide and organoyttrium hydride chemistry. 7. Reaction of the samarium-hydrogen bond in the organosamarium hydride [(C5Me5)2SmH]2 with carbon monoxide: formation, isomerization, and x-ray crystallographic characterization of the samarium complexes cis- and trans-{(C5Me5)2[(C6H5)3PO]Sm}2(.mu.-OCH:CHO)
William J. Evans, Jay W. Grate, and Robert J. Doedens
pp 1671 - 1679; DOI:
10.1021/ja00292a034
PDF
Preparation and x-ray structure determination of the lithium-silver cation [Li6Br4(Et2O)10]2+[Ag3Li2Ph6]2-: an unusual cation composed of a solvated "salt cluster"
Michael Y. Chiang, Elmar Bohlen, and Robert Bau
pp 1679 - 1681; DOI:
10.1021/ja00292a035
PDF
Structures of the copper-containing Cu4MgPh6 and [Cu4LiPh6]- clusters: first example of a magnesium-containing transition-metal cluster compound
Saeed I. Khan, Peter G. Edwards, Hanna S. H. Yuan, and Robert Bau
pp 1682 - 1684; DOI:
10.1021/ja00292a036
PDF
Thermochromic transformations of 2,6-diorgano-1,3,5,7-tetraoxa-2,6-dibora-4,8-octalindiones: a model for solid-state phase transformations and hysteresis
Mohamed Yalpani, Walter R. Scheidt, and Klaus Seevogel
pp 1684 - 1690; DOI:
10.1021/ja00292a037
PDF
Total synthesis of elfamycins: aurodox and efrotomycin. 1. Strategy and construction of key intermediates
R. E. Dolle and K. C. Nicolaou
pp 1691 - 1694; DOI:
10.1021/ja00292a038
PDF
Total synthesis of elfamycins: aurodox and efrotomycin. 2. Coupling of key intermediates and completion of the synthesis
R. E. Dolle and K. C. Nicolaou
pp 1695 - 1698; DOI:
10.1021/ja00292a039
PDF
A convenient synthesis of 4-unsubstituted .beta.-lactams
Larry E. Overman and Tatsushi Osawa
pp 1698 - 1701; DOI:
10.1021/ja00292a040
PDF
Stable simple enols. 9. Solid state structures and conformations of several simple enols and their keto tautomers
Menahem Kaftory, Silvio E. Biali, and Zvi Rappoport
pp 1701 - 1709; DOI:
10.1021/ja00292a041
PDF
Studies dealing with the intramolecular ene reaction of cyclopropene derivatives
Albert Padwa, William F. Rieker, and Robert J. Rosenthal
pp 1710 - 1717; DOI:
10.1021/ja00292a042
PDF
Aliphatic semidiones. 43. Conformational studies of macrocyclic 1,2-semidiones
Glen A. Russell and N. K. Suleman
pp 1717 - 1720; DOI:
10.1021/ja00292a043
PDF
Deuterium isotope effects on carbon-13 chemical shifts of protoadamantane. Evidence for geometrical dependence of 3.DELTA. and 4.DELTA. effects
Zdenko Majerski, Miljenko Zuanic, and Biserka Metelko
pp 1721 - 1726; DOI:
10.1021/ja00292a044
PDF
Cyclization of acetylenic carbonyl compounds via their silyl enol ether derivatives: a new intramolecular C-vinylation induced by mercury(II) salts. Stereochemistry and functionalization of the intermediate vinylmercurial
Jacques Drouin, Maria Amelia Boaventura, and Jean Marie Conia
pp 1726 - 1729; DOI:
10.1021/ja00292a045
PDF
The structure of a B12 coenzyme: methylcobalamin studies by x-ray and NMR methods
Miriam Rossi, Jenny P. Glusker, Lucio Randaccio, Michael F. Summers, Paul J. Toscano, and Luigi G. Marzilli
pp 1729 - 1738; DOI:
10.1021/ja00292a046
PDF
Rhizobactin, a structurally novel siderophore from Rhizobium meliloti
M. J. Smith, J. N. Shoolery, B. Schwyn, I. Holden, and J. B. Neilands
pp 1739 - 1743; DOI:
10.1021/ja00292a047
PDF
Kinetic analysis of the photoinitiated autocatalytic chain decomposition of phenyl azide. A molecular explosion in solution
Joseph P. Costantino, Helen W. Richter, Celia H. Lee Go, and Walter H. Waddell
pp 1744 - 1747; DOI:
10.1021/ja00292a048
PDF
Isotopic multiplets in the carbon-13 NMR spectra of polyols with partially deuterated hydroxyls. 4. Molecular structure as reflected in the carbon-13 NMR spectra of oligosaccharides with partially deuterated hydroxyls
Jacques Reuben
pp 1747 - 1755; DOI:
10.1021/ja00292a049
PDF
Isotopic multiplets in the carbon-13 NMR spectra of polyols with partially deuterated hydroxyls. 5. .beta.-Diols
Jacques Reuben
pp 1756 - 1759; DOI:
10.1021/ja00292a050
PDF
Multiple mixed-metal condensation leading to the trigonal bipyramidal iridium copper hexahydride Ir2Cu3H6(MeCN)3(PMe2Ph)63+
Larry F. Rhodes, John C. Huffman, and Kenneth G. Caulton
pp 1759 - 1760; DOI:
10.1021/ja00292a051
PDF
Formation of a planar hexametallic cluster containing a triangle of silver atoms within a triangle of rhodium atoms
Juerg Ott and Luigi M. Venanzi
pp 1760 - 1761; DOI:
10.1021/ja00292a052
PDF
Electrophilic intermediate in the reactions of a 2-(hydroxyamino)imidazole. A model for biological effects of reduced nitroimidazoles
Robert A. McClelland, Rick Panicucci, and A. Michael Rauth
pp 1762 - 1763; DOI:
10.1021/ja00292a053
PDF
Total synthesis of streptazolin - an application of the aza-analogue of the ferrier rearrangement
Alan P. Kozikowski and Pyeong Uk Park
pp 1763 - 1765; DOI:
10.1021/ja00292a054
PDF
Charge-transfer-biradical excited states: relation to anomalous fluorescence. "Negative" S1-T1 splitting in twisted aminoborane
Vlasta Bonacic-Koutecky and Josef Michl
pp 1765 - 1766; DOI:
10.1021/ja00292a055
PDF
Reaction of dicyclopentadienylmethylenetitanium with organic halides: Evidence for a radical mechanism
Stephen L. Buchwald, Eric V. Anslyn, and Robert H. Grubbs
pp 1766 - 1768; DOI:
10.1021/ja00292a056
PDF
Aza Diels-Alder reactions in aqueous solution: cyclocondensation of dienes with simple iminium salts generated under Mannich conditions
Scott D. Larsen and Paul A. Grieco
pp 1768 - 1769; DOI:
10.1021/ja00292a057
PDF
Total synthesis of (-)-paspaline
Amos B. Smith and Richard Mewshaw
pp 1769 - 1771; DOI:
10.1021/ja00292a058
PDF
Structure of a heteropoly blue. The four-electron reduced .beta.-12-molybdophosphate anion
Julie N. Barrows, Geoffrey B. Jameson, and Michael T. Pope
pp 1771 - 1773; DOI:
10.1021/ja00292a059
PDF
Effect of semiconductor on photocatalytic decomposition of lactic acid
H. Harada, T. Sakata, and T. Ueda
pp 1773 - 1774; DOI:
10.1021/ja00292a060
PDF
2,4-Dimethylene-1,3-cyclobutadiyl
Gary J. Snyder and Dennis A. Dougherty
pp 1774 - 1775; DOI:
10.1021/ja00292a061
PDF
Two-dimensional proton-cadmium-113 chemical-shift correlation maps by proton-detected multiple-quantum NMR in metal complexes and metalloproteins
David Live, Ian M. Armitage, David C. Dalgarno, and David Cowburn
pp 1775 - 1777; DOI:
10.1021/ja00292a062
PDF
Total synthesis of (-)-tirandamycin A
R. H. Schlessinger, G. R. Bebernitz, Peter Lin, and A. J. Poss
pp 1777 - 1778; DOI:
10.1021/ja00292a063
PDF
Diastereoselective [3 + 2]-type heterocyclic synthesis via [2-(acetoxymethyl)-3-allyl]tri-n-butylstannane
Barry M. Trost and Peter J. Bonk
pp 1778 - 1781; DOI:
10.1021/ja00292a064
PDF
Cyclization via isomerization: a palladium(2+)-catalyzed carbocyclization of 1,6-enynes to 1,3- and 1,4-dienes
Barry M. Trost and Mark Lautens
pp 1781 - 1783; DOI:
10.1021/ja00292a065
PDF
The chemistry of sulfines. 10. 2-Thiabicyclo[2.2.1]hept-5-ene endo-2-oxide derivatives: stereospecific formation, rearrangement to bicyclic sultenes, and conversion to 5-alkylidene-2-cyclopentenones
Eric Block, Alan Wall, and Jon Zubieta
pp 1783 - 1784; DOI:
10.1021/ja00292a066
PDF
Persulfide-bridged iron-molybdenum-sulfur clusters of biological relevance: two synthetic routes and the structures of intermediate and product clusters
Julie A. Kovacs, J. K. Bashkin, and R. H. Holm
pp 1784 - 1786; DOI:
10.1021/ja00292a067
PDF
Ferro- and antiferromagnetic interaction between two diphenylcarbene units incorporated in the [2.2]paracyclophane skeleton
Akira Izuoka, Shigeru Murata, Tadashi Sugawara, and Hiizu Iwamura
pp 1786 - 1787; DOI:
10.1021/ja00292a068
PDF
Observation of a novel low-lying excited state in zinc(II) complexes
K. A. Truesdell and G. A. Crosby
pp 1787 - 1788; DOI:
10.1021/ja00292a069
PDF
Product translational energy distributions as a probe of organometallic reaction mechanisms: dehydrogenation of alkanes by Group 8-10 metal ions
Maureen A. Hanratty, Jesse L. Beauchamp, Andreas J. Illies, and M. T. Bowers
pp 1788 - 1789; DOI:
10.1021/ja00292a070
PDF
Resolution and structural determination of unsymmetrically 6A6D-disubstituted .beta.-cyclodextrin
Kahee Fujita, Atsuo Matsunaga, Taiji Imoto, Ken Hirotsu, Shigehiro Kamitori, and Taiichi Higuchi
pp 1790 - 1791; DOI:
10.1021/ja00292a071
PDF
Organometallic nitrosyl chemistry. 24. Very twisted .eta.4-trans-diene complexes
Allen D. Hunter, Peter Legzdins, Charles R. Nurse, Frederick W. B. Einstein, and Anthony C. Willis
pp 1791 - 1792; DOI:
10.1021/ja00292a072
PDF
Specific long-range effects on relaxation of local stress during a solid-state reaction
Mark D. Hollingsworth and J. Michael McBride
pp 1792 - 1793; DOI:
10.1021/ja00292a073
PDF
Synthesis and characterization of the first example of an organoplatinum complex containing a platinum(IV)-olefin bond
Edith J. Parsons, Raymond D. Larsen, and P. W. Jennings
pp 1793 - 1794; DOI:
10.1021/ja00292a074
PDF
Flash photolysis investigations of bis(triphenylphosphine)carbonylchlororhodium: reaction dynamics of the Wilkinson's catalysis intermediate "bis(triphenylphosphine)chlororhodium"
David Wink and Peter C. Ford
pp 1794 - 1796; DOI:
10.1021/ja00292a075
PDF
Seven coordinate aluminum in (benzo-15-crown-5)dichloroaluminum ethyltrichloroaluminate
Simon G. Bott, Hosny Elgamal, and Jerry L. Atwood
pp 1796 - 1797; DOI:
10.1021/ja00292a076
PDF
Carbamate-mediated functionalization of unsaturated alcohols. 3. Intramolecular Michael addition of O-carbamates to .alpha.,.beta.-unsaturated esters. A new diastereoselective amination in an acyclic system
Masahiro Hirama, Takeo Shigemoto, Yutaka Yamazaki, and Sho Ito
pp 1797 - 1798; DOI:
10.1021/ja00292a077
PDF
Additions and Corrections - Free Radical Rearrangement Involving the 1,2-Migration of a Thioester Group. Model for the Coenzyme B12 Dependent Methylmalonyl-CoA Mutase Reaction
Susan Wollowitz, and Jack Halpern
pp 1798 - 1798; DOI:
10.1021/ja00292a601
PDF
Book Reviews

pp 1799 - 1804; DOI:
10.1021/ja00292a600
PDF

Issue 7


High-field proton NMR study of the aggregation and complexation of n-butyllithium in tetrahydrofuran
John F. McGarrity and Craig A. Ogle
pp 1805 - 1810; DOI:
10.1021/ja00293a001
PDF
A rapid-injection (RI) NMR study of the reactivity of butyllithium aggregates in tetrahydrofuran
John F. McGarrity, Craig A. Ogle, Zdenek Brich, and Hans Rudolf Loosli
pp 1810 - 1815; DOI:
10.1021/ja00293a002
PDF
Kinetics and mechanism of self-protonation reactions in organic electrochemical processes
Christian Amatore, Giulio Capobianco, Giuseppe Farnia, Giancarlo Sandona, Jean Michel Saveant, Maria Gabriella Severin, and Elio Vianello
pp 1815 - 1824; DOI:
10.1021/ja00293a003
PDF
.beta.-Turns in model dipeptides. An infrared quantitative analysis with NMR correlation
Guy Boussard and Michel Marraud
pp 1825 - 1828; DOI:
10.1021/ja00293a004
PDF
Electron density distribution analysis for nitromethane, nitromethide, and nitramide
James P. Ritchie
pp 1829 - 1837; DOI:
10.1021/ja00293a005
PDF
Kinetics of polyatomic free radicals produced by laser photolysis. 4. Study of the equilibrium isopropyl + oxygen .tautm. isopropylperoxy between 592 and 692 K
Irene R. Slagle, Emil Ratajczak, Michael C. Heaven, David Gutman, and Albert F. Wagner
pp 1838 - 1845; DOI:
10.1021/ja00293a006
PDF
Electrocatalysis of proton-coupled electron-transfer reactions at glassy carbon electrodes
George E. Cabaniss, A. A. Diamantis, W. Rorer Murphy, R. W. Linton, and T. J. Meyer
pp 1845 - 1853; DOI:
10.1021/ja00293a007
PDF
A general model for dispersed kinetics in heterogeneous systems
W. John Albery, Philip N. Bartlett, C. Paul Wilde, and James R. Darwent
pp 1854 - 1858; DOI:
10.1021/ja00293a008
PDF
Phase-transfer-aided FMNH production using artificial photosynthesis cells of bacterial type. Cell system optimization by the concept of flux conjugation
Iwao Tabushi and Shinichi Kugimiya
pp 1859 - 1863; DOI:
10.1021/ja00293a009
PDF
Gas-phase ion decomposition occurring remote to a charge site
Nancy J. Jensen, Kenneth B. Tomer, and Michael L. Gross
pp 1863 - 1868; DOI:
10.1021/ja00293a010
PDF
Spectroscopy and photochemistry of a derivative of an anthracene-naphthalene phane
James Ferguson, Miroslav Puza, and Raymond J. Robbins
pp 1869 - 1874; DOI:
10.1021/ja00293a011
PDF
Photophysical studies on 1-(p-aminophenyl)pyrene. Characterization of an intramolecular charge-transfer state with application to proton-transfer dynamics
Sair Hagopian and Lawrence A. Singer
pp 1874 - 1880; DOI:
10.1021/ja00293a012
PDF
Tautomer characterization by energy resolved mass spectrometry. Dimethyl phosphite and dimethyl phosphonate ions
Hilkka I. Kenttamaa and R. Graham Cooks
pp 1881 - 1886; DOI:
10.1021/ja00293a013
PDF
Electron spin resonance study of tris[2-aminobenzenethiolato(2-)-S,N]technetium(VI) and -rhenium(VI) chelates: evidence for molecular aggregation in solution
John Baldas, John F. Boas, John Bonnyman, John R. Pilbrow, and Geoffrey A. Williams
pp 1886 - 1891; DOI:
10.1021/ja00293a014
PDF
The influence of a second magnesium atom in unsolvated magnesium-hydrogen halide reactions
Paul G. Jasien and Clifford E. Dykstra
pp 1891 - 1895; DOI:
10.1021/ja00293a015
PDF
Dicyclopenta[ef,kl]heptalene (azupyrene) chemistry. Electrophilic monosubstitution. Theory and experiment
Arthur G. Anderson, Ernest R. Davidson, Edward D. Daugs, L. Glenn Kao, Richard L. Lindquist, and Kristine A. Quenemoen
pp 1896 - 1899; DOI:
10.1021/ja00293a016
PDF
Ab initio and MNDO study of nitromethane and the nitromethyl radical
Michael L. McKee
pp 1900 - 1904; DOI:
10.1021/ja00293a017
PDF
Ab initio heats of formation of medium-sized hydrocarbons. 2. Use of second-order correlation energies
Raymond L. Disch, Jerome M. Schulman, and Michael L. Sabio
pp 1904 - 1906; DOI:
10.1021/ja00293a018
PDF
Molecular mechanics calculations on aliphatic amines
S. Profeta and N. L. Allinger
pp 1907 - 1918; DOI:
10.1021/ja00293a019
PDF
A theoretical model of bonding in hyperlithiated carbon compounds
Alan E. Reed and Frank Weinhold
pp 1919 - 1921; DOI:
10.1021/ja00293a020
PDF
Electronic structure of the phosphoryl and thiophosphoryl bonds
Michael W. Schmidt and Mark S. Gordon
pp 1922 - 1930; DOI:
10.1021/ja00293a021
PDF
Picosecond studies of ruthenium(II) and ruthenium(III) porphyrin photophysics
C. Drew Tait, Dewey Holten, Mark Barley, David Dolphin, and Brian R. James
pp 1930 - 1934; DOI:
10.1021/ja00293a022
PDF
Product branching in infrared multiple photon decomposition of gas-phase ions. Mechanistic implications for proton-transfer reactions
Christopher R. Moylan, Joseph M. Jasinski, and John I. Brauman
pp 1934 - 1940; DOI:
10.1021/ja00293a023
PDF
Origin of the temperature-dependent product variation in carbene reaction with alcohol
Setsuko Oikawa and Minoru Tsuda
pp 1940 - 1946; DOI:
10.1021/ja00293a024
PDF
Solid-state NMR of cyclic pentapeptides
M. H. Frey, S. J. Opella, A. L. Rockwell, and L. M. Gierasch
pp 1946 - 1951; DOI:
10.1021/ja00293a025
PDF
Conformations, possible hydrogen bonding, and microwave spectrum of 3-buten-2-ol
Zuzana Smith, Norberto Carballo, E. Bright Wilson, Karl Magnus Marstokk, and Harald Moellendal
pp 1951 - 1957; DOI:
10.1021/ja00293a026
PDF
Electrochemical switching of lariat ethers. Survey of cation binding by neutral and reduced forms of one- and two-armed carbon- and nitrogen-pivot lariat ethers
Angel Kaifer, Deborah Ann Gustowski, Luis Echegoyen, Vincent J. Gatto, Rose Ann Schultz, Thomas P. Cleary, Charles R. Morgan, D. M. Goli, Angel M. Rios, and George W. Gokel
pp 1958 - 1965; DOI:
10.1021/ja00293a027
PDF
Ab initio structures of phosphorus acids and esters. 1. Phosphinic, phosphonic, and phosphoric acids
Carl S. Ewig and John R. Van Wazer
pp 1965 - 1971; DOI:
10.1021/ja00293a028
PDF
Torsional and steric control of stereoselectivity in isodicyclopentadiene cycloadditions
Frank K. Brown and K. N. Houk
pp 1971 - 1978; DOI:
10.1021/ja00293a029
PDF
[26](1,2,4,5)Cyclophane (deltaphane) and related compounds. Simultaneous .pi.-electron interaction among three benzene rings
Hee Chol Kang, A. W. Hanson, Bruce Eaton, and V. Boekelheide
pp 1979 - 1985; DOI:
10.1021/ja00293a030
PDF
Spectroscopy and photochemistry of conjugated nonprotonated Schiff bases: application of an ab initio derived Heisenberg effective Hamiltonian
J. Sanchez-Marin and J. P. Malrieu
pp 1985 - 1992; DOI:
10.1021/ja00293a031
PDF
Localized molecular orbital studies on transition-metal complexes. III. Localized valence structures of transition-metal carbene complexes
Dennis S. Marynick and Carol M. Kirkpatrick
pp 1993 - 1994; DOI:
10.1021/ja00293a032
PDF
Crystal-field effects on the far-infrared cation vibrations of transition metal (2+) ion exchanged faujasite zeolites
Geoffrey A. Ozin, Mark D. Baker, John Godber, and Shihua Wu
pp 1995 - 2000; DOI:
10.1021/ja00293a033
PDF
Epoxidation of olefins by cytochrome P-450 model compounds: kinetics and stereochemistry of oxygen atom transfer and origin of shape selectivity
James P. Collman, John I. Brauman, Bernard Meunier, Teruyuki Hayashi, Thomas Kodadek, and Scott A. Raybuck
pp 2000 - 2005; DOI:
10.1021/ja00293a034
PDF
Homogeneous catalysis of the photoreduction of water. 6. Mediation by polypyridine complexes of ruthenium(II) and cobalt(II) in alkaline media
C. V. Krishnan, Bruce S. Brunschwig, Carol Creutz, and Norman Sutin
pp 2005 - 2015; DOI:
10.1021/ja00293a035
PDF
Metal ion promoted elimination reactions. Conversion of .beta.-hydroxy .alpha.-amino acids to .alpha.-imino acids
E. K. Chong, J. MacB. Harrowfield, W. G. Jackson, Alan M. Sargeson, and J. Springborg
pp 2015 - 2022; DOI:
10.1021/ja00293a036
PDF
Synthesis and chemistry of a bridging vinylidenedicobalt complex. Evidence for a nonchain radical mechanism in its reaction with metal hydrides to give heteronuclear clusters
Eric N. Jacobsen and Robert G. Bergman
pp 2023 - 2032; DOI:
10.1021/ja00293a037
PDF
Asymmetric synthesis. Asymmetric catalytic allylation using palladium chiral phosphine complexes
Pamela R. Auburn, Peter B. Mackenzie, and B. Bosnich
pp 2033 - 2046; DOI:
10.1021/ja00293a038
PDF
Asymmetric synthesis. Mechanism of asymmetric catalytic allylation
Peter B. Mackenzie, John Whelan, and B. Bosnich
pp 2046 - 2054; DOI:
10.1021/ja00293a039
PDF
Structure of the palladium complex [Pd(.eta.3-C(Xyl)2CHCHPh)(S,S-PPh2(CHMe)2PPh2)]BPh4: a catalyst for asymmetric allylic alkylation reactions
David H. Farrar and Nicholas C. Payne
pp 2054 - 2058; DOI:
10.1021/ja00293a040
PDF
Homogeneous catalysis. Transition-metal-catalyzed Claisen rearrangements
Terry G. Schenck and B. Bosnich
pp 2058 - 2066; DOI:
10.1021/ja00293a041
PDF
Tautomerism and steric effects in 1-nitro-9-(alkylamino)acridines (ledakrin or nitracrine analogs): probing structure-activity relationships at the molecular level
John J. Stezowski, Petra Kollat, Maria Bogucka-Ledochowska, and Jenny P. Glusker
pp 2067 - 2077; DOI:
10.1021/ja00293a042
PDF
On the origin of the stereoselectivity of hydrazone alkylations. Investigation of aggregation effects and solution kinetics
Robert A. Wanat and David B. Collum
pp 2078 - 2082; DOI:
10.1021/ja00293a043
PDF
Conformations of saturated six-membered ring phosphorus heterocycles. Chair-chair equilibria for cyclophosphamide, the 5,5-dimethyl derivative, and related 1,3,2-oxazaphosphorinanes. Relative conformational energies of nitrogen mustard and other R2N groups attached to phosphorus
William N. Setzer, Alan E. Sopchik, and Wesley G. Bentrude
pp 2083 - 2091; DOI:
10.1021/ja00293a044
PDF
Ion pairing and reactivity of enolate anions. 6. Kinetics and thermodynamics for reaction of alkali acetylacetonates with alkyl halides in dimethyl sulfoxide
Edward M. Arnett, Stephen G. Maroldo, George W. Schriver, Steven L. Schilling, and E. B. Troughton
pp 2091 - 2099; DOI:
10.1021/ja00293a045
PDF
Theory of stereoselection in conrotatory electrocyclic reactions of substituted cyclobutenes
Nelson G. Rondan and K. N. Houk
pp 2099 - 2111; DOI:
10.1021/ja00293a046
PDF
Mechanisms for interconversions among C3H4 hydrocarbons: deuterium isotope effects and independent generation of vinylmethylene intermediates in photoisomerizations of allenes and cyclopropenes
Mark G. Steinmetz and Richard T. Mayes
pp 2111 - 2121; DOI:
10.1021/ja00293a047
PDF
Mechanism of solvolysis of 2,2-dimethylcyclopentyl p-bromobenzenesulfonate
V. J. Shiner and Michael A. Imhoff
pp 2121 - 2124; DOI:
10.1021/ja00293a048
PDF
Intramolecular carbopalladation of allylic amines and sulfides
Robert A. Holton and Joseph R. Zoeller
pp 2124 - 2131; DOI:
10.1021/ja00293a049
PDF
Alkoxide triggered ligand substitution. Highly stereoselective formation of unsaturated phosphinite ester-molybdenum tetracarbonyl chelates and the x-ray crystal structure of (1-phenylallyl dimethylphosphinite)molybdenum tetracarbonyl
Randall T. DePue, David B. Collum, Joseph W. Ziller, and Melvyn Rowen Churchill
pp 2131 - 2137; DOI:
10.1021/ja00293a050
PDF
Stereocontrolled construction of oxygenated steroidal side chains. Synthesis and stereochemistry of depresosterol
Eiichi Nakamura and Isao Kuwajima
pp 2138 - 2141; DOI:
10.1021/ja00293a051
PDF
Synthesis of 14-membered phosphorus-sulfur P2S2 and P3S macrocycles which contain the 1-thio-2-(phenylphosphino)benzene moiety. Determination of stereochemistries of the free ligands and of a platinum(II) complex
Evan P. Kyba, Clyde N. Clubb, Steven B. Larson, Victor J. Schueler, and Raymond E. Davis
pp 2141 - 2148; DOI:
10.1021/ja00293a052
PDF
Synthesis of polyquinanes. 2. The total synthesis of (.+-.)-silphinene: the intramolecular Diels-Alder approach
Daniel D. Sternbach, Jeffrey W. Hughes, Douglas F. Burdi, and Beverly A. Banks
pp 2149 - 2153; DOI:
10.1021/ja00293a053
PDF
Functional group diversity in enzymic oxygenation reactions catalyzed by bacterial flavin-containing cyclohexanone oxygenase
Bruce P. Branchaud and Christopher T. Walsh
pp 2153 - 2161; DOI:
10.1021/ja00293a054
PDF
Aggregate morphology and intermembrane interaction of synthetic peptide lipids bearing various head groups
Yukito Murakami, Junichi Kikuchi, Toshihiko Takaki, Katsuya Uchimura, and Akio Nakano
pp 2161 - 2167; DOI:
10.1021/ja00293a055
PDF
Absorption and MCD spectral studies of the decaammine(.mu.-dinitrogen-N,N')diosmium(5+) mixed-valence ion
Lucjan Dubicki, James Ferguson, Elmars R. Krausz, Peter A. Lay, Marcel Maeder, Roy H. Magnuson, and Henry Taube
pp 2167 - 2171; DOI:
10.1021/ja00293a056
PDF
Homoleptic carbene complexes. 3. Hexakis(oxazolidin-2-ylidene)cobalt(III) and -rhodium(III)
Ulrike Plaia, Heribert Stolzenberg, and Wolf P. Fehlhammer
pp 2171 - 2172; DOI:
10.1021/ja00293a057
PDF
Anomalously long-wavelength electronic transition in conformationally locked organosilane high polymers
Robert D. Miller, D. Hofer, J. Rabolt, and G. N. Fickes
pp 2172 - 2174; DOI:
10.1021/ja00293a058
PDF
The isolation and x-ray structures of lithium crown ether salts of the free phenyl carbanions [CHPh2]- and [CPh3]-
Marilyn M. Olmstead and Philip P. Power
pp 2174 - 2175; DOI:
10.1021/ja00293a059
PDF
NMR method to detect stereospecific deuterium labeling at diastereotopic methylene hydrogens: selective proton, carbon-13 heteronuclear shift correlation
Laird A. Trimble, Paul B. Reese, and John C. Vederas
pp 2175 - 2177; DOI:
10.1021/ja00293a060
PDF
Cadmium-113 chemical shift tensor in cadmium diethyl phosphate: a step toward understanding divalent cation-phospholipid interactions
V. W. Miner and James H. Prestegard
pp 2177 - 2178; DOI:
10.1021/ja00293a061
PDF
Evidence of the breaking of the copper-imidazolate bridge in copper/cobalt-substituted superoxide dismutase upon reduction of the copper(II) centers
Ivano Bertini, Claudio Luchinat, and Roberto Monnanni
pp 2178 - 2179; DOI:
10.1021/ja00293a062
PDF
Early transition-metal carbene complexes L2M:CH2---equilibrium structures and rotational barriers
Allan R. Gregory and Eric A. Mintz
pp 2179 - 2180; DOI:
10.1021/ja00293a063
PDF
Direct studies of photodissociation of azomethane vapor using transient CARS spectroscopy
P. L. Holt, K. E. McCurdy, J. S. Adams, K. A. Burton, R. B. Weisman, and Paul S. Engel
pp 2180 - 2182; DOI:
10.1021/ja00293a064
PDF
Mechanisms of phenylacetylene polymerization by molybdenum and titanium initiators
Thomas J. Katz, Scott M. Hacker, R. D. Kendrick, and C. S. Yannoni
pp 2182 - 2183; DOI:
10.1021/ja00293a065
PDF
Novel photoinduced carbon-carbon bond formation in purines
Vasu Nair and Stanley D. Chamberlain
pp 2183 - 2185; DOI:
10.1021/ja00293a066
PDF
Extraordinary micellar enantioselectivity coupled to altered aggregate structure
Ryuichi Ueoka, Robert A. Moss, Shanti Swarup, Yoko Matsumoto, George Strauss, and Yukito Murakami
pp 2185 - 2186; DOI:
10.1021/ja00293a067
PDF
Oxidative cleavage of 1-phenyl-1,2-ethanediol by 4-cyano-N,N-dimethylaniline N-oxide and chloro(5,10,15,20-tetraphenylporphinato)chromium(III): a model for cholesterol side-chain cleavage by cytochrome P-450SCC
Ralph I. Murray and Stephen G. Sligar
pp 2186 - 2187; DOI:
10.1021/ja00293a068
PDF
Cumulene photochemistry: evidence for cis and trans cyclopropylidene intermediates in triplet photoreactions of 1,2-cyclodecadiene
John D. Price and Richard P. Johnson
pp 2187 - 2189; DOI:
10.1021/ja00293a069
PDF
Evidence for the hydride abstraction mechanism in the carbon-hydrogen insertion reaction as illustrated in the reaction of secondary alkoxides with alkylidenemethylene carbenoid
Toshiro Harada, Yohko Nozaki, Yasunari Yamaura, and Akira Oku
pp 2189 - 2190; DOI:
10.1021/ja00293a070
PDF
Studies of enzyme stereochemistry. Elucidation of the stereochemistry of the reaction catalyzed by cob(I)alamin adenosyltransferase
Ronald J. Parry, John M. Ostrander, and Isidora Y. Arzu
pp 2190 - 2191; DOI:
10.1021/ja00293a071
PDF
Mechanistic and synthetic studies of the cyclopropyliminium ion rearrangement: an efficient route to enammonium salts and related enamines and dienamines
Robert K. Boeckman, Paul F. Jackson, and Joseph P. Sabatucci
pp 2191 - 2192; DOI:
10.1021/ja00293a072
PDF
Intramolecular [2+2] cycloadditions of ketenes and keteniminium salts to olefins
Istvan Marko, Bruno Ronsmans, Anne Marie Hesbain-Frisque, Stephane Dumas, Leon Ghosez, Beat Ernst, and Hans Greuter
pp 2192 - 2194; DOI:
10.1021/ja00293a073
PDF
Intramolecular [2 + 2] cycloadditions of ketenes
Barry B. Snider, Raymond A. H. F. Hui, and Yashwant S. Kulkarni
pp 2194 - 2196; DOI:
10.1021/ja00293a074
PDF
Novel palladium-catalyzed reactions of propargyl carbonates with carbonucleophiles under neutral conditions
Jiro Tsuji, Hiroyuki Watanabe, Ichiro Minami, and Isao Shimizu
pp 2196 - 2198; DOI:
10.1021/ja00293a075
PDF
Additions and Corrections - Energetic Approach to the Packing of α-Helices. 2. General Treatment of Nonequivalent and Nonregular Helices.
Kuo-Chen Chou, George Nemethy, and Harold A. Scheraga
pp 2199 - 2199; DOI:
10.1021/ja00293a600
PDF
Additions and Corrections - Hapalindoles: New Alkaloids from the Blue-Green Alga Hapalosiphon fontinalis
R. E. Moore, C. Cheuk, and G. M. L. Patterson
pp 2199 - 2199; DOI:
10.1021/ja00293a601
PDF
Additions and Corrections - Siderophore Iron-Release Mechanisms
Robert C. Hider, David Bickar, Ian E. G. Morrison, and Jack Silver
pp 2199 - 2199; DOI:
10.1021/ja00293a602
PDF
Additions and Corrections - Cobalt-Carbon Bond Dissociation Energy of Coenzyme B 12
Jack Halpern, Sook-Hui Kim, and T. W. Leung
pp 2199 - 2199; DOI:
10.1021/ja00293a603
PDF
Additions and Corrections - Stereochemistry of the Wittig Reaction. Effect of Nucleophilic Groups in the Phosphonium Ylide
Bruce E. Maryanoff, Allen B. Reitz, and Barbara A. Duhl-Emswiler
pp 2199 - 2199; DOI:
10.1021/ja00293a604
PDF
Additions and Corrections - Mechanism of the Oxidation of NADH by Quinones. Energetics of One-Electron and Hydride Routes.
Brian W. Carlson, and Larry L. Miller
pp 2199 - 2199; DOI:
10.1021/ja00293a605
PDF
Book Reviews

pp 2199 - 2202; DOI:
10.1021/ja00293a606
PDF

Issue 8


Studies on the photochemistry of chromium hexacarbonyl in the gase phase; primary and secondary processes
T. Rick Fletcher and Robert N. Rosenfeld
pp 2203 - 2212; DOI:
10.1021/ja00294a001
PDF
Molecular mechanical studies of inclusion of alkali cations into anisole spherands
Peter Kollman, Georges Wipff, and U. Chandra Singh
pp 2212 - 2219; DOI:
10.1021/ja00294a002
PDF
Simulation of formamide hydrolysis by hydroxide ion in the gas phase and in aqueous solution
Scott J. Weiner, U. Chandra Singh, and Peter A. Kollman
pp 2219 - 2229; DOI:
10.1021/ja00294a003
PDF
Monte Carlo simulations of the solvation of the dimethyl phosphate anion
Giuliano Alagona, Caterina Ghio, and Peter Kollman
pp 2229 - 2239; DOI:
10.1021/ja00294a004
PDF
Monte Carlo determination of the free energy and internal energy of hydration for the Ala dipeptide at 25.degree.C
M. Mezei, P. K. Mehrotra, and D. L. Beveridge
pp 2239 - 2245; DOI:
10.1021/ja00294a005
PDF
Metal-metal bonding and antibonding molecular orbitals in triangular skeletons of the type L6M3
Carlo Mealli
pp 2245 - 2253; DOI:
10.1021/ja00294a006
PDF
Theoretical studies of the polar effect. 5. The use of the isolated molecule approach
Stephen Marriott and Ronald D. Topsom
pp 2253 - 2255; DOI:
10.1021/ja00294a007
PDF
Experimental and ab initio molecular orbital studies on CH3O2+.cntdot. dications
Wolfram Koch, Francis Maquin, Helmut Schwarz, and Daniel Stahl
pp 2256 - 2260; DOI:
10.1021/ja00294a008
PDF
An MC-SCF study of the thermal cycloaddition of two ethylenes
Fernando Bernardi, Andrea Bottoni, Michael A. Robb, H. Bernhard Schlegel, and Glauco Tonachini
pp 2260 - 2264; DOI:
10.1021/ja00294a009
PDF
Transition-state modeling in acyclic stereoselection. A molecular mechanics model for the kinetic formation of lithium enolates
David W. Moreland and William G. Dauben
pp 2264 - 2273; DOI:
10.1021/ja00294a010
PDF
Energies of non-Kekule molecular states. Calculation by a predictively useful semiempirical method
Paul M. Lahti, Angelo Rossi, and Jerome A. Berson
pp 2273 - 2280; DOI:
10.1021/ja00294a011
PDF
Properties of ions and radicals derived from decacarbonyldimanganese, decacarbonylmanganeserhenium, and decacarbonyldirhenium by electron attachment and protonation in the gas phase
Wilma K. Meckstroth and D. P. Ridge
pp 2281 - 2285; DOI:
10.1021/ja00294a012
PDF
Vibrational circular dichroism of trans-1,2-dideuteriocyclobutane. Experimental and calculational results in the mid-infrared
A. Annamalai, T. A. Keiderling, and J. S. Chickos
pp 2285 - 2291; DOI:
10.1021/ja00294a013
PDF
Relative electron affinities of substituted benzophenones, nitrobenzenes, and quinones
Elaine K. Fukuda and Robert T. McIver
pp 2291 - 2296; DOI:
10.1021/ja00294a014
PDF
Ipso aromatic alkylation in the gas phase. Intermediacy and structure of gaseous heptaalkylbenzenium ions
Marina Attina, Fulvio Cacace, Giulia De Petris, Simonetta Fornarini, and Pierluigi Giacomello
pp 2297 - 2302; DOI:
10.1021/ja00294a015
PDF
Systematic design of chemical oscillators. 26. A new halogen-free chemical oscillator: the reaction between sulfide ion and hydrogen peroxide in a CSTR
Miklos Orban and Irving R. Epstein
pp 2302 - 2305; DOI:
10.1021/ja00294a016
PDF
Geometric structure and pseudorotational potential of pyrrolidine. An ab initio and electron diffraction study
Gregor Pfafferott, Heinz Oberhammer, James E. Boggs, and Walther Caminati
pp 2305 - 2309; DOI:
10.1021/ja00294a017
PDF
Conformations and structures of N-chloro- and N-methylpyrrolidine. An ab initio and gas electron diffraction study
Gregor Pfafferott, Heinz Oberhammer, and James E. Boggs
pp 2309 - 2313; DOI:
10.1021/ja00294a018
PDF
Experimental test for the control intermediate in the Belousov-Zhabotinskii (BZ) reaction
Zoltan Noszticzius, Vilmos Gaspar, and Horst Dieter Foersterling
pp 2314 - 2315; DOI:
10.1021/ja00294a019
PDF
ESR investigation of the photochemical reaction of aroylsilanes with phosphorous compounds
Angelo Alberti, Alessandro Degl'Innocenti, Gian Franco Pedulli, and Alfredo Ricci
pp 2316 - 2319; DOI:
10.1021/ja00294a020
PDF
Geometry of cyclohexaamylose inclusion complexes with some substituted benzenes in aqueous solution based on carbon-13 NMR chemical shifts
Yoshio Inoue, Hajime Hoshi, Minoru Sakurai, and Riichiro Chujo
pp 2319 - 2323; DOI:
10.1021/ja00294a021
PDF
Conformational dependencies of vicinal carbonyl-nitrogen-carbon-carbon (13C(O)-N-C.alpha.-13C) and carbonyl-nitrogen-carbon-hydrogen (13C(O)-N-C.alpha.-1H) coupling constants in compounds which model the peptide backbone
Lung Fa Kao and Michael Barfield
pp 2323 - 2330; DOI:
10.1021/ja00294a022
PDF
Ultrashort nonbonded hydrogen...hydrogen distance in a half-cage pentacyclododecane
Otto Ermer, Sax A. Mason, Frank A. L. Anet, and Steve S. Miura
pp 2330 - 2334; DOI:
10.1021/ja00294a023
PDF
Molecular dynamics of a peptide chain, studied by intramolecular excimer formation
M. Goedeweeck, M. Van der Auweraer, and F. C. De Schryver
pp 2334 - 2341; DOI:
10.1021/ja00294a024
PDF
Molecular structure of 1,4,5,8-tetramethylnaphthalene and in-plane molecular rotation of some methyl-substituted naphthalenes in solids
Fumio Imashiro, Kiyonori Takegoshi, A. Saika, Zenei Taira, and Yutaka Asahi
pp 2341 - 2346; DOI:
10.1021/ja00294a025
PDF
Laser beam-ion beam photodissociation studies of C6H6+ radical cations: the 2,4-hexadiyne system
R. E. Krailler, D. H. Russell, M. F. Jarrold, and M. T. Bowers
pp 2346 - 2354; DOI:
10.1021/ja00294a026
PDF
Nucleophilic activation of coordinated carbon monoxide. 2. Reactions of the mononuclear complexes M(CO)5 [M = Fe, Ru, or Os] with hydroxide and with methoxide
Raymond J. Trautman, David C. Gross, and Peter C. Ford
pp 2355 - 2362; DOI:
10.1021/ja00294a027
PDF
High-resolution solid-state aluminum-27 and silicon-29 nuclear magnetic resonance study of pillared clays
D. Plee, F. Borg, L. Gatineau, and J. J. Fripiat
pp 2362 - 2369; DOI:
10.1021/ja00294a028
PDF
Alternative iron-dioxygen bond lengths in dioxygen adducts of iron porphyrins: implications for hemoglobin cooperativity
Geoffrey L. Woolery, Mark A. Walters, Kenneth S. Suslick, Linda S. Powers, and Thomas G. Spiro
pp 2370 - 2373; DOI:
10.1021/ja00294a029
PDF
Photolysis of hexacarbonylchromium in hydrogen-containing matrixes: evidence of simple adducts of molecular hydrogen
Ray L. Sweany
pp 2374 - 2379; DOI:
10.1021/ja00294a030
PDF
Isolation and characterization of reactive intermediates and active catalysts in homogeneous catalysis
Paul G. Gassman, David W. Macomber, and Stephen M. Willging
pp 2380 - 2388; DOI:
10.1021/ja00294a031
PDF
Synthesis and electrophilic reactivity of dicarbonylnitrosyl(cyclohexadienyl)manganese cations: double nucleophilic addition to coordinated arenes
Young Keun Chung, D. A. Sweigart, Neil G. Connelly, and John B. Sheridan
pp 2388 - 2393; DOI:
10.1021/ja00294a032
PDF
Structure of octaethylporphyrin N-oxide and the characterization of its nickel(II) and copper(II) complexes
Alan L. Balch, Yee Wai Chan, Marilyn Olmstead, and Mark W. Renner
pp 2393 - 2398; DOI:
10.1021/ja00294a033
PDF
Structures of a labile copper redox couple: sterically constrained copper(II) and copper(I) complexes formed with a simple cyclic pentathia ether, 1,4,7,10,13-pentathiacyclopentadecane
Peter W. R. Corfield, Christopher Ceccarelli, Milton D. Glick, Isabel Wei Yu Moy, L. A. Ochrymowycz, and D. B. Rorabacher
pp 2399 - 2404; DOI:
10.1021/ja00294a034
PDF
M3X13 type of equilateral-triangular molybdenum metal atom cluster compound with several unprecedented features: [Mo3(.mu.3-CH3C)(.mu.2-Br)3(.eta.2,.mu.2-CH3CO2)3(H2O)3]ClO4.cntdot.4H2O
Amira Birnbaum, F. Albert Cotton, Zvi Dori, Moshe Kapoh, David Marler, George M. Reisner, and Willi Schwotzer
pp 2405 - 2410; DOI:
10.1021/ja00294a035
PDF
Unique bonding and geometry in .eta.-cyclopentadienyltantalum-diene complexes. Preparation, x-ray structural analyses, and EHMO calculations
Hajime Yasuda, Kazuyuki Tatsumi, Takuji Okamoto, Kazushi Mashima, Keonil Lee, Akira Nakamura, Yasushi Kai, Noriko Kanehisa, and Nobutami Kasai
pp 2410 - 2422; DOI:
10.1021/ja00294a036
PDF
Olefin isomerization catalysis by heterobimetallic hydrides, HFeM(CO)8L- (M = Cr, Mo, W; L = CO, PR3)
Patricia A. Tooley, Larry W. Arndt, and Marcetta Y. Darensbourg
pp 2422 - 2427; DOI:
10.1021/ja00294a037
PDF
Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides
Paul L. Gaus, S. C. Kao, Kay Youngdahl, and Marcetta Y. Darensbourg
pp 2428 - 2434; DOI:
10.1021/ja00294a038
PDF
Stereomutation of methoxycarbenium ions. 1. An investigation of the mechanism in gaseous and solution phases
Dieter Cremer, Juergen Gauss, Ronald F. Childs, and Christopher Blackburn
pp 2435 - 2441; DOI:
10.1021/ja00294a039
PDF
Stereomutation of methoxycarbenium ions. 2. Experimental evidence for an inversion process
Christopher Blackburn, Ronald F. Childs, Dieter Cremer, and Juergen Gauss
pp 2442 - 2448; DOI:
10.1021/ja00294a040
PDF
Anomerization of furanose sugars and sugar phosphates
John Pierce, Anthony S. Serianni, and Robert Barker
pp 2448 - 2456; DOI:
10.1021/ja00294a041
PDF
Conformational enantiomerism in bilirubin. Selection by cyclodextrins
David A. Lightner, Jacek K. Gawronski, and Krystyna Gawronska
pp 2456 - 2461; DOI:
10.1021/ja00294a042
PDF
Structure of hexamethylene triperoxide diamine
William P. Schaefer, John T. Fourkas, and Bruce G. Tiemann
pp 2461 - 2463; DOI:
10.1021/ja00294a043
PDF
Direct evidence for bromine-olefin charge-transfer complexes as essential intermediates of the fast ionic addition of bromine to cyclohexene
Giuseppe Bellucci, Roberto Bianchini, and Roberto Ambrosetti
pp 2464 - 2471; DOI:
10.1021/ja00294a044
PDF
Biosynthesis of macrolide antibiotics. 6. Late steps in brefeldin A biosynthesis
Yoshikuni Yamamoto, Akira Hori, and C. Richard Hutchinson
pp 2471 - 2474; DOI:
10.1021/ja00294a045
PDF
Synthetic studies toward aflavinine: a synthesis of 3-demethylaflavinine via a [2 + 2 + 2] annulation
Samuel Danishefsky, Samuel Chackalamannil, Peter Harrison, and Michael Silvestri
pp 2474 - 2484; DOI:
10.1021/ja00294a046
PDF
Alkylation of nucleosides and nucleotides by dehydroretronecine; characterization of covalent adducts by liquid secondary ion mass spectrometry
Palitha P. Wickramanayake, Brian L. Arbogast, Donald R. Buhler, Max L. Deinzer, and Alma L. Burlingame
pp 2485 - 2488; DOI:
10.1021/ja00294a047
PDF
Reactions of di-, tri-, and hexamethylbenzenes with oxygen(3P) atoms in liquid and on adsorbed phases
Elazar Zadok, Sarah Rubinraut, Felix Frolow, and Yehuda Mazur
pp 2489 - 2494; DOI:
10.1021/ja00294a048
PDF
Asymmetric induction in the intramolecular 1,3-diyl trapping reaction. Use of a stereogenic atom located on the chain linking the diyl and diylophile
Keith J. Stone and R. Daniel Little
pp 2495 - 2505; DOI:
10.1021/ja00294a049
PDF
Electron transfer processes. 34. Reactions of .alpha.-halo ketones with nucleophiles
Glen A. Russell and Francisco Ros
pp 2506 - 2511; DOI:
10.1021/ja00294a050
PDF
Biosynthesis of sulfur compounds. Investigations of the biosynthesis of asparagusic acid
Ronald J. Parry, A. E. Mizusawa, I. C. Chiu, M. V. Naidu, and M. Ricciardone
pp 2512 - 2521; DOI:
10.1021/ja00294a051
PDF
Enzymes in organic synthesis. 34. Preparations of enantiomerically pure exo- and endo-bridged bicyclic [2.2.1] and [2.2.2] chiral lactones via stereospecific horse liver alcohol dehydrogenase catalyzed oxidations of meso diols
Kar P. Lok, Ignac J. Jakovac, and J. Bryan Jones
pp 2521 - 2526; DOI:
10.1021/ja00294a052
PDF
Exact Hueckel molecular orbitals of the finite, square-cut, fcc crystal
L. Salem and C. Leforestier
pp 2526 - 2528; DOI:
10.1021/ja00294a053
PDF
Design, synthesis, and DNA binding properties of bifunctional intercalators. Comparison of polymethylene and diphenyl ether chains connecting phenanthridine
M. Cory, David D. McKee, J. Kagan, D. W. Henry, and J. Allen Miller
pp 2528 - 2536; DOI:
10.1021/ja00294a054
PDF
The molecular structure of allenes and ketenes. 17. Excited states of the allene chromophore: photoelectron, circular dichroism and absorption spectroscopy of alkyl- and halogenoallenes
Cornelis J. Elsevier, Peter Vermeer, Aharon Gedanken, and Wolfgang Runge
pp 2537 - 2547; DOI:
10.1021/ja00294a055
PDF
.beta.-Elimination from a metal acetyl compound to form ketene and a metal hydride
Sven I. Hommeltoft and Michael C. Baird
pp 2548 - 2549; DOI:
10.1021/ja00294a056
PDF
Mechanism of cytochrome P-450 catalysis. Mechanism of N-dealkylation and amine oxide deoxygenation
Leo T. Burka, F. Peter Guengerich, Randolf J. Willard, and Timothy L. Macdonald
pp 2549 - 2551; DOI:
10.1021/ja00294a057
PDF
Decaammine(.mu.-dinitrogen-N,N')diosmium(III): synthesis, characterization, reactivity, and spectral properties
Peter A. Lay, Roy H. Magnuson, Henry Taube, James Ferguson, and Elmars R. Krausz
pp 2551 - 2552; DOI:
10.1021/ja00294a058
PDF
Flow adsorption calorimetry with supercritical fluids on silica gel
Edward M. Arnett, B. Chawla, Elaine A. Dwyer, and Charles H. Lochmuller
pp 2552 - 2553; DOI:
10.1021/ja00294a059
PDF
New modes of ligation for a phosphorus-nitrogen double bond
Atta M. Arif, Alan H. Cowley, and Marek Pakulski
pp 2553 - 2554; DOI:
10.1021/ja00294a060
PDF
Benzene Diol epoxides
Robert A. Aleksejczyk, Glenn A. Berchtold, and Andrew G. Braun
pp 2554 - 2555; DOI:
10.1021/ja00294a061
PDF
New compounds with platinum to silver bonds unsupported by covalent bridges
Rafael Uson, Juan Fornies, Milagros Tomas, Jose M. Casas, F. Albert Cotton, and Larry R. Falvello
pp 2556 - 2557; DOI:
10.1021/ja00294a062
PDF
Selectivity and charge transfer in photoreactions of donor-acceptor systems. 5. Selectivity and charge transfer in photoreactions of .alpha.,.alpha.,.alpha.-trifluorotoluene with olefins
Jochen Mattay, Jan Runsink, Thomas Rumbach, Cuong Ly, and Joachim Gersdorf
pp 2557 - 2558; DOI:
10.1021/ja00294a063
PDF
Evidences for an efficient demethylation of methoxyellipticine derivatives catalyzed by a peroxidase
Gerard Meunier and Bernard Meunier
pp 2558 - 2560; DOI:
10.1021/ja00294a064
PDF
A linear chain with alternating ferromagnetic and antiferromagnetic exchange: Cu(hfac)2.cntdot.TEMPOL
Cristiano Benelli, Dante Gatteschi, David W. Carnegie, and Richard L. Carlin
pp 2560 - 2561; DOI:
10.1021/ja00294a065
PDF
Oxidative decomposition of 1,1'-azoadamantane by thianthrene cation radical. Carbocationic chemistry from a free radical source
Dong Hak Bae, Paul S. Engel, A. K. M. Mansurul Hoque, Dalen E. Keys, Wang Keun Lee, Robert W. Shaw, and Henry J. Shine
pp 2561 - 2562; DOI:
10.1021/ja00294a066
PDF
Novel cycloaddition of dimethylacetylene to the dimethylacetylene radical cation: direct observation by ESR
M. Shiotani, K. Ohta, Y. Nagata, and J. Sohma
pp 2562 - 2564; DOI:
10.1021/ja00294a067
PDF
An asymmetric synthesis of the diastereomeric 1-(2-cyclohexenyl)-1-alkanols in high optical purity via a stereochemically stable allylic borane, B-2-cyclohexen-1-yldiisopinocampheylborane
Herbert C. Brown, Prabhakar K. Jadhav, and Krishna S. Bhat
pp 2564 - 2565; DOI:
10.1021/ja00294a068
PDF
Potential of mean force for the stacking of phenyl rings in aqueous solution
G. Ravishanker and D. L. Beveridge
pp 2565 - 2566; DOI:
10.1021/ja00294a069
PDF
Infrared spectroscopic evidence for silicon-oxygen double bonds: silanone and the silanoic and silicic acid molecules
Robert Withnall and Lester Andrews
pp 2567 - 2568; DOI:
10.1021/ja00294a070
PDF
Metal promoted cyclization. 7. Zirconium-promoted bicyclization of enynes
Eiichi Negishi, Steven J. Holmes, James M. Tour, and Joseph A. Miller
pp 2568 - 2569; DOI:
10.1021/ja00294a071
PDF
Lewis acid assisted condensations between a 5-methoxyisoxazolidine and silicon-based nucleophiles: .gamma.-amino alcohol building block in the synthesis of agroclavine I
Alan P. Kozikowski and Philip D. Stein
pp 2569 - 2571; DOI:
10.1021/ja00294a072
PDF
Phenoxide-directed ortho lithiation
Gary H. Posner and Karen A. Canella
pp 2571 - 2573; DOI:
10.1021/ja00294a073
PDF
Total synthesis of (.+-.)-nemorensic acid
Larry L. Klein
pp 2573 - 2574; DOI:
10.1021/ja00294a074
PDF
Complementary solutes enter nonpolar preorganized cavities in lipophilic noncomplementary media
Donald J. Cram, Kent D. Stewart, Israel Goldberg, and Kenneth N. Trueblood
pp 2574 - 2575; DOI:
10.1021/ja00294a075
PDF
Shell closure of two cavitands forms carcerand complexes with components of the medium as permanent guests
Donald J. Cram, Stefan Karbach, Young Hwan Kim, Lubomir Baczynskyj, and Gregory W. Kallemeyn
pp 2575 - 2576; DOI:
10.1021/ja00294a076
PDF
Book Reviews

pp 2577 - 2580; DOI:
10.1021/ja00294a600
PDF

Issue 9


Charge distribution in diatomic halides from electron spectroscopy
Leif J. Saethre, T. Darrah Thomas, and Odd Gropen
pp 2581 - 2585; DOI:
10.1021/ja00295a001
PDF
The intrinsic reaction coordinate and the rotational barrier in silaethylene
Michael W. Schmidt, Mark S. Gordon, and Michel Dupuis
pp 2585 - 2589; DOI:
10.1021/ja00295a002
PDF
Theoretical study on the dimerization of silanone and the properties of the polymeric products (H2SiO)n (n = 2, 3, and 4). Comparison with dimers (H2SiS)2 and (H2CO)2
Takako Kudo and Shigeru Nagase
pp 2589 - 2595; DOI:
10.1021/ja00295a003
PDF
Ab initio calculations on the diphosphine radical cation (P2H4+.cntdot.)
David Feller, Ernest R. Davidson, and Weston Thatcher Borden
pp 2596 - 2597; DOI:
10.1021/ja00295a004
PDF
The diphosphine radical cation (P2H4+.cntdot.)
Timothy Clark
pp 2597 - 2599; DOI:
10.1021/ja00295a005
PDF
Theoretical electron deformation density studies on chromium benzene tricarbonyl
Randall A. Kok and Michael B. Hall
pp 2599 - 2604; DOI:
10.1021/ja00295a006
PDF
Reactions of the metal carbenes FeCH2+ and CoCH2+ with olefins in the gas phase. Studies involving olefin metathesis
D. B. Jacobson and B. S. Freiser
pp 2605 - 2612; DOI:
10.1021/ja00295a007
PDF
Bridging the gap. A continuous scale of gas-phase basicities from methane to water from pulsed electron beam high pressure mass spectrometric equilibria measurements
T. B. McMahon and P. Kebarle
pp 2612 - 2617; DOI:
10.1021/ja00295a008
PDF
Laser flash photolysis study of the photochemistry of ring-substituted .beta.-phenylpropiophenones
J. C. Netto-Ferreira, W. J. Leigh, and J. C. Scaiano
pp 2617 - 2622; DOI:
10.1021/ja00295a009
PDF
Aqualigand dissociation of nonaaquacerium(3+) ion in the 5d .rarw. 4f excited state
Youkoh Kaizu, Koji Miyakawa, Keiko Okada, Hiroshi Kobayashi, Minoru Sumitani, and Keitaro Yoshihara
pp 2622 - 2626; DOI:
10.1021/ja00295a010
PDF
Detection of hydrogen, hydrogen-deuterium molecule (HD), and deuterium by Raman spectroscopy: a powerful aid for the elucidation of reaction mechanisms
Stephen P. Best, A. J. Bloodworth, Robin J. H. Clark, and Henny J. Eggelte
pp 2626 - 2628; DOI:
10.1021/ja00295a011
PDF
Fusogenic behavior of didodecyldimethylammonium bromide bilayer vesicles
Leo A. M. Rupert, Dick Hoekstra, and Jan B. F. N. Engberts
pp 2628 - 2631; DOI:
10.1021/ja00295a012
PDF
Kinetics of reduction of eight viologens by dithionite ion
K. Tsukahara and R. G. Wilkins
pp 2632 - 2635; DOI:
10.1021/ja00295a013
PDF
Nitrogen-14 and nitrogen-15 ENDOR studies of intrabridgehead three-electron .sigma.-bonded radical cations. Observation of second-order splittings
B. Kirste, R. W. Alder, R. B. Sessions, M. Bock, H. Kurreck, and S. F. Nelsen
pp 2635 - 2640; DOI:
10.1021/ja00295a014
PDF
Anisotropy and asymmetry of the diamagnetic susceptibility of the carbonium ion of anthracene
P. C. M. Van Zijl, G. B. M. Kostermans, and C. MacLean
pp 2641 - 2643; DOI:
10.1021/ja00295a015
PDF
Magnetic properties of manganese in the photosynthetic oxygen-evolving complex
Julio C. De Paula and Gary W. Brudvig
pp 2643 - 2648; DOI:
10.1021/ja00295a016
PDF
A new method for obtaining isotopic fractionation data at multiple sites in rapidly exchanging systems
Ronald M. Jarret and Martin Saunders
pp 2648 - 2654; DOI:
10.1021/ja00295a017
PDF
A study of L-proline, sarcosine, and the cis/trans isomers of N-acetyl-L-proline and N-acetylsarcosine in aqueous and organic solution by oxygen-17 NMR
Roger N. Hunston, Ioannis P. Gerothanassis, and Juergen Lauterwein
pp 2654 - 2661; DOI:
10.1021/ja00295a018
PDF
A heteropolyanion with fivefold molecular symmetry that contains a nonlabile encapsulated sodium ion. The structure and chemistry of [NaP5W30O110]14-
Mohammed H. Alizadeh, Subhash P. Harmalker, Yves Jeannin, Jeanne Martin-Frere, and Michael T. Pope
pp 2662 - 2669; DOI:
10.1021/ja00295a019
PDF
Kinetics and mechanism of the insertion of olefins into transition metal-hydride bonds
Nancy M. Doherty and John E. Bercaw
pp 2670 - 2682; DOI:
10.1021/ja00295a020
PDF
A molecular orbital evaluation of possible factors affecting the homolytic activation of coenzyme B12
David W. Christianson and William N. Lipscomb
pp 2682 - 2686; DOI:
10.1021/ja00295a021
PDF
Ab initio MO study of the coordination modes and bonding nature of rhodium(I)-dinitrogen complexes
Shigeyoshi Sakaki, Keiji Morokuma, and Katsutoshi Ohkubo
pp 2686 - 2693; DOI:
10.1021/ja00295a022
PDF
Relative importance of dissociative loss of carbon monoxide and formation of benzyl radicals from photoexcitation of (.eta.5-C5R5)Fe(CO)2(.eta.1-CH2C6H5) and evidence for reaction of carbon monoxide with 17-electron radicals
Josephine Paw Blaha and Mark S. Wrighton
pp 2694 - 2702; DOI:
10.1021/ja00295a023
PDF
Molecular receptors. Synthesis, x-ray crystal structures, and chemical properties of crown ethers bearing an intraannular phenolic group
Christine M. Browne, George Ferguson, M. Anthony McKervey, D. Lindsay Mulholland, Thomas O'Connor, and Masood Parvez
pp 2703 - 2712; DOI:
10.1021/ja00295a024
PDF
Stereoselective total synthesis of the complement inhibitor K-76
John E. McMurry and Mark D. Erion
pp 2712 - 2720; DOI:
10.1021/ja00295a025
PDF
Ring transformation equilibrium (bond switch) in 5-(2-aminovinyl)isothiazole system via hypervalent sulfurane. Synthesis, structure determination, and kinetic study
Kinya Akiba, Kohichi Kashiwagi, Yoshihiko Ohyama, Yohsuke Yamamoto, and Katsuo Ohkata
pp 2721 - 2730; DOI:
10.1021/ja00295a026
PDF
Acyclic diastereoselection as a synthetic route to quassinoids: a Claisen rearrangement based strategy for bruceantin
Frederick E. Ziegler, Scott I. Klein, Uttam K. Pati, and Tein Fu Wang
pp 2730 - 2737; DOI:
10.1021/ja00295a027
PDF
Polysilane high polymers: mechanism of photodegradation
Peter Trefonas, Robert West, and Robert D. Miller
pp 2737 - 2742; DOI:
10.1021/ja00295a028
PDF
Azide and fluoride exchange reactions of halodiazirines
Robert A. Moss, Jacek Terpinski, D. Phillip Cox, Dorothy Z. Denny, and Karsten Krogh-Jespersen
pp 2743 - 2748; DOI:
10.1021/ja00295a029
PDF
Stereocontrolled functionalization in the cyclohexane ring using organomolybdenum chemistry
Anthony J. Pearson, M. Nazrul I. Khan, Jon C. Clardy, and Cun Heng He
pp 2748 - 2757; DOI:
10.1021/ja00295a030
PDF
Dynamic transduction of energy and internal equilibria in enzymes: a reexamination of pyruvate kinase
Joseph Stackhouse, Krishnan P. Nambiar, Jonathan J. Burbaum, Dora M. Stauffer, and Steven A. Benner
pp 2757 - 2763; DOI:
10.1021/ja00295a031
PDF
Bridgehead adamantyl, diamantyl, and related cations and dications
George A. Olah, G. K. Surya Prakash, Joseph G. Shih, V. V. Krishnamurthy, Gheorge D. Mateescu, Gao Liang, Gyorgy Sipos, Volker Buss, Tamara M. Gund, and Paul v. R. Schleyer
pp 2764 - 2772; DOI:
10.1021/ja00295a032
PDF
Remarkable structures of C2B2H4 isomers
Peter H. M. Budzelaar, Karsten Krogh-Jespersen, Timothy Clark, and Paul v. R. Schleyer
pp 2773 - 2779; DOI:
10.1021/ja00295a033
PDF
Cobalt-59 NMR chemical shifts of cobalt(III) complexes; correlations with parameters calculated from ligand-field spectra
Richard Bramley, Michael Brorson, Alan M. Sargeson, and Claus E. Schaeffer
pp 2780 - 2787; DOI:
10.1021/ja00295a034
PDF
Topochemical double photocyclodimerization of the 1,4-dicinnamoylbenzene crystal
Masaki Hasegawa, Kazuhiko Saigo, Toru Mori, Hirofumi Uno, Masao Nohara, and Hachiro Nakanishi
pp 2788 - 2793; DOI:
10.1021/ja00295a035
PDF
Kinetics of ozonation. 3. Substituent effects on the rates of reaction of alkenes
William A. Pryor, David Giamalva, and Daniel F. Church
pp 2793 - 2797; DOI:
10.1021/ja00295a036
PDF
Acyclic stereoselection. 29. Stereoselection in the Michael addition reaction. 1. The Mukaiyama-Michael reaction
Clayton H. Heathcock, Mark H. Norman, and David E. Uehling
pp 2797 - 2799; DOI:
10.1021/ja00295a037
PDF
Geometrical isomers of a bridgehead imine: (E)- and (Z)-2-azabicyclo[3.2.1]oct-1-ene, and 2-azabicyclo[2.2.2]oct-1-ene
Juliusz G. Radziszewski, John W. Downing, Curt Wentrup, Piotr Kaszynski, Mikolaj Jawdosiuk, Peter Kovacic, and Josef Michl
pp 2799 - 2801; DOI:
10.1021/ja00295a038
PDF
Mixed-valence manganese(II)-manganese(III) complexes: models for the manganese site in the photosynthetic electron transport chain
Bouchra Mabad, Jean Pierre Tuchagues, Yeong Tsyr Hwang, and David N. Hendrickson
pp 2801 - 2802; DOI:
10.1021/ja00295a039
PDF
Photochemistry of ketones in solution. 74. Characterization of transient intermediates on laser flash excitation of cyclohexenones in the presence of amines
D. A. Dunn, D. I. Schuster, and R. Bonneau
pp 2802 - 2804; DOI:
10.1021/ja00295a040
PDF
Spectroscopic determination of .sigma.I and .sigma.R substituent constants for the deuterium atom
H. Kuenzer and S. Berger
pp 2804 - 2805; DOI:
10.1021/ja00295a041
PDF
The role of lithium salts in controlling the regiochemistry of the alkylation of a lithium enolate in a weakly polar aprotic solvent
L. M. Jackman and T. S. Dunne
pp 2805 - 2806; DOI:
10.1021/ja00295a042
PDF
Are carbenium ions stabilized or destabilized by .alpha.-silyl substitution? The solvolysis of 2-(trimethylsilyl)-2-adamantyl p-nitrobenzoate
Yitzhak Apeloig and Amnon Stanger
pp 2806 - 2807; DOI:
10.1021/ja00295a043
PDF
Conformation, configuration, and reactivity of thiosulfonium ions derived from 1,2-dithianes and 1,2-dithiolanes. Stereoelectronic effects
Marjorie C. Caserio, Jhong K. Kim, Scott D. Kahn, and Warren J. Hehre
pp 2807 - 2809; DOI:
10.1021/ja00295a044
PDF
Electron-rich, hydrocarbon-metal complexes: synthesis and reversible one-electron oxidation. X-ray structure of a 17-electron iron cation
Jean Michel Grosselin, Hubert Le Bozec, Claude Moinet, Loic Toupet, and Pierre H. Dixneuf
pp 2809 - 2811; DOI:
10.1021/ja00295a045
PDF
Surprising stereochemical control of Wittig olefination involving reaction of fluorine-containing phosphoranium salt and aldehydes
Daryl G. Cox, Narayanasamy Gurusamy, and Donald J. Burton
pp 2811 - 2812; DOI:
10.1021/ja00295a046
PDF
Nucleophilic displacement vs. proton transfer: the system hydrated hydroxide ion + chloromethane [OH-.cntdot.(H2O)0,1,2 + CH3Cl] in the relative energy range 0.03-5 eV
Michael Henchman, Peter M. Hierl, and John F. Paulson
pp 2812 - 2814; DOI:
10.1021/ja00295a047
PDF
Mechanism of adenylate kinase. 1. Use of oxygen-17 NMR to study the binding properties of substrates
Daniel A. Wisner, Corazon A. Steginsky, Yeun Jund Shyy, and Ming Daw Tsai
pp 2814 - 2815; DOI:
10.1021/ja00295a048
PDF
The octant rule. 13. Axial and equatorial 4-tert-butyladamantan-2-ones. Synthesis, circular dichroism, and mass spectra
David A. Lightner and W. M. Donald Wijekoon
pp 2815 - 2817; DOI:
10.1021/ja00295a049
PDF
High-speed spatially resolved high-resolution NMR spectroscopy
Shigeru Matsui, Kensuke Sekihara, and Hideki Kohno
pp 2817 - 2818; DOI:
10.1021/ja00295a050
PDF
Kinetic isotope effect in gas-phase base-induced elimination reactions
Veronica M. Bierbaum, Jonathan Filley, Charles H. DePuy, Martin F. Jarrold, and Michael T. Bowers
pp 2818 - 2820; DOI:
10.1021/ja00295a051
PDF
Assignment of complex proton NMR spectra via two-dimensional homonuclear Hartmann-Hahn spectroscopy
Donald G. Davis and Ad Bax
pp 2820 - 2821; DOI:
10.1021/ja00295a052
PDF
Transition structures for additions of lithium hydride and methyllithium to ethylene and acetylene
Kendall N. Houk, Nelson G. Rondan, Paul v. R. Schleyer, E. Kaufmann, and Timothy Clark
pp 2821 - 2823; DOI:
10.1021/ja00295a053
PDF
Multiple substitutions in radical-chain chlorinations. A new cage effect
Phillip S. Skell and H. N. Baxter
pp 2823 - 2824; DOI:
10.1021/ja00295a054
PDF
Electrochemistry of polymer films not immersed in solution: electron transfer on an ion budget
Joseph C. Jernigan, Christopher E. D. Chidsey, and Royce W. Murray
pp 2824 - 2826; DOI:
10.1021/ja00295a055
PDF
Book Reviews

pp 2826 - 2830; DOI:
10.1021/ja00295a600
PDF

Issue 10


Relaxation of the second excited singlet states of aromatic thiones: the role of specific solute-solvent interactions
A. Maciejewski, D. R. Demmer, D. R. James, A. Safarzadeh-Amiri, R. E. Verrall, and R. P. Steer
pp 2831 - 2837; DOI:
10.1021/ja00296a001
PDF
The origin of the barriers to thermally allowed, six-electron, pericyclic reactions: the effect of homo-homo interactions on the trimerization of acetylene
Robert D. Bach, Gregory J. Wolber, and H. Bernhard Schlegel
pp 2837 - 2841; DOI:
10.1021/ja00296a002
PDF
Photoinduced intramolecular charge transfer: photodissociation of carbon dioxide ion (1+)-argon (CO2+.Ar) cluster ions
Andreas J. Illies, M. F. Jarrold, W. Wagner-Redeker, and Michael T. Bowers
pp 2842 - 2849; DOI:
10.1021/ja00296a003
PDF
Structure revision of the antibiotic pulvomycin
Richard J. Smith, Dudley H. Williams, Jennifer C. J. Barna, Ian R. McDermott, Klaus Haegele, Francois Piriou, Joseph Wagner, and William Higgins
pp 2849 - 2857; DOI:
10.1021/ja00296a004
PDF
The generation and trapping of the high-temperature oxosilyliumyl cation radicals (28SiO+ and 29SiO+) in neon matrixes at 4 K; an ESR and ab initio CI theoretical investigation
Lon B. Knight, A. Ligon, R. W. Woodward, David Feller, and E. R. Davidson
pp 2857 - 2864; DOI:
10.1021/ja00296a005
PDF
Characterization of partially ligated hemoglobins: NMR, ENDOR, CD, and stopped-flow studies of zinc-containing hemoglobin hybrids
Ken Simolo, Gary Stucky, Shirley Chen, Mark Bailey, Charles Scholes, and George McLendon
pp 2865 - 2872; DOI:
10.1021/ja00296a006
PDF
The stability of alkyl radicals
Wing Tsang
pp 2872 - 2880; DOI:
10.1021/ja00296a007
PDF
Chirality of the electron density distribution in methyl groups with local C3 symmetry
Alberto Gutierrez, James E. Jackson, and Kurt Mislow
pp 2880 - 2885; DOI:
10.1021/ja00296a008
PDF
Molybdenum(VI)-dioxo, molybdenum(V)-oxo, and molybdenum(IV)-oxo complexes with 2,3:8,9-dibenzo-1,4,7,10-tetrathiadecane. Models for the molybdenum binding site of the molybdenum cofactor
Bharat B. Kaul, John H. Enemark, Shannath L. Merbs, and J. T. Spence
pp 2885 - 2891; DOI:
10.1021/ja00296a009
PDF
1,2-Methyl shift between platinum and the coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of platinum(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(MeC6H3(CH2NMe2)2-o,o')]I
Jos Terheijden, Gerard Van Koten, Ico C. Vinke, and Anthony L. Spek
pp 2891 - 2898; DOI:
10.1021/ja00296a010
PDF
Investigations of the mechanism of the rhodium/copper- and rhodium-catalyzed oxidation of terminal olefins with oxygen
Russell S. Drago, Anne Zuzich, and Eric D. Nyberg
pp 2898 - 2903; DOI:
10.1021/ja00296a011
PDF
Steric and electronic effects of ligand variation on cobalt dioxygen catalysts
Barry B. Corden, Russell S. Drago, and Richard P. Perito
pp 2903 - 2907; DOI:
10.1021/ja00296a012
PDF
Mechanistic considerations in the photodisproportionation of .mu.-oxo-bis((tetraphenylporphinato)iron(III))
Mark W. Peterson, David S. Rivers, and Robert M. Richman
pp 2907 - 2915; DOI:
10.1021/ja00296a013
PDF
Structure of the psammaplysins
Deborah M. Roll, Clifford W. J. Chang, Paul J. Scheuer, George A. Gray, James N. Shoolery, Gayle K. Matsumoto, Gregory D. Van Duyne, and Jon Clardy
pp 2916 - 2920; DOI:
10.1021/ja00296a014
PDF
Considered stable carbocations. 262. anti-Tricyclo[5.1.0.03,5]octa-2,6-diyl dications. Novel bis(cyclopropylcarbinyl) dications
G. K. Surya Prakash, Alexander P. Fung, Tarik N. Rawdah, and George A. Olah
pp 2920 - 2923; DOI:
10.1021/ja00296a015
PDF
Synthesis, characterization and reactions of (C5H5)(CO)2Fe:C(CH3)2+ and (C5H5)(CO)2Fe:CH-CH:C(CH3)2+
Charles P. Casey, William H. Miles, and Hideyuki Tukada
pp 2924 - 2931; DOI:
10.1021/ja00296a016
PDF
Stereoselective synthesis of vicinal diamines from alkenes and cyanamide
Sang Hun Jung and Harold Kohn
pp 2931 - 2943; DOI:
10.1021/ja00296a017
PDF
Total syntheses of rivularins D1 and D3
Hubert Maehr and Joanne Smallheer
pp 2943 - 2945; DOI:
10.1021/ja00296a018
PDF
Neighboring group participation by sulfur involving four-membered-ring intermediates (RS-4)
Ernest L. Eliel and David E. Knox
pp 2946 - 2952; DOI:
10.1021/ja00296a019
PDF
Theoretical investigation of acidity and isotope exchange in purine nucleotide cations
Donald W. Boerth and Francis X. Harding
pp 2952 - 2969; DOI:
10.1021/ja00296a020
PDF
Structure of dilithium tetraphenylallenide
Andrzej Rajca and Laren M. Tolbert
pp 2969 - 2971; DOI:
10.1021/ja00296a021
PDF
Model calculations of isotope effects. 10. Temperature-independent isotope effects in hydrogen transfer. Do they signify a bent transition state?
Duncan J. McLennan and Peter M. W. Gill
pp 2971 - 2972; DOI:
10.1021/ja00296a022
PDF
Formation of dinuclear rhodium dialkyl complexes by alkylation of a new dinuclear dianion and by nucleophilic addition of alkyllithium reagents across a metal-metal double bond
Michael J. Krause and Robert G. Bergman
pp 2972 - 2973; DOI:
10.1021/ja00296a023
PDF
Energy profile for a nonconcerted SN2 reaction in solution
Jayaraman Chandrasekhar and William L. Jorgensen
pp 2974 - 2975; DOI:
10.1021/ja00296a024
PDF
Dimer vs. polymer liquid crystals: alkyl chain flexibility via deuterium NMR
Anselm C. Griffin and Edward T. Samulski
pp 2975 - 2976; DOI:
10.1021/ja00296a025
PDF
Punaglandins: halogenated antitumor eicosanoids from the octocoral Telesto riisei
Bill J. Baker, Roy K. Okuda, Patrick T. K. Yu, and Paul J. Scheuer
pp 2976 - 2977; DOI:
10.1021/ja00296a026
PDF
Nucleophilic addition of azide ion to benzene oxide: a reinvestigation
Michael J. McManus, Glenn A. Berchtold, and Donald M. Jerina
pp 2977 - 2978; DOI:
10.1021/ja00296a027
PDF
Crystal structure of meso-tetratolylporphyrin: implications for the solid-state nitrogen-15 CPMAS NMR
Raymond J. Butcher, Geoffrey B. Jameson, and Carlyle B. Storm
pp 2978 - 2980; DOI:
10.1021/ja00296a028
PDF
Iron/copper promoted fragmentation reactions of .alpha.-alkoxy hydroperoxides. The conversion of octalins into fourteen-membered ring macrolides
Stuart L. Schreiber and Waifong Liew
pp 2980 - 2982; DOI:
10.1021/ja00296a029
PDF
Synchrotron light source applied to measuring the vacuum ultraviolet circular dichroism of heparin
E. S. Stevens, E. R. Morris, D. A. Rees, and J. C. Sutherland
pp 2982 - 2983; DOI:
10.1021/ja00296a030
PDF
Oxidation of red ferryl [(FeIVO)2+] porphyrin complexes to green ferryl [(FeIVO)2+] porphyrin radical complexes
Alan L. Balch, Lechoslaw Latos-Grazynski, and Mark W. Renner
pp 2983 - 2985; DOI:
10.1021/ja00296a031
PDF
Carbon dioxide and formaldehyde coordination on molybdenocene to metal and hydrogen bonds of the C1 molecule in the solid state
Sandro Gambarotta, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 2985 - 2986; DOI:
10.1021/ja00296a032
PDF
Dithioether-containing cyclic peptides
Henry I. Mosberg and John R. Omnaas
pp 2986 - 2987; DOI:
10.1021/ja00296a033
PDF
Synthesis of a 1,3-dioxa-2,4-diboretane, an oxoborane precursor
Bernd Pachaly and Robert West
pp 2987 - 2988; DOI:
10.1021/ja00296a034
PDF
Highly efficient sensitization of titanium dioxide
Jean Desilvestro, Michael Graetzel, Ladislav Kavan, Jacques Moser, and Jan Augustynski
pp 2988 - 2990; DOI:
10.1021/ja00296a035
PDF
Photoinduced aggregation changes in photochromic polypeptides
Osvaldo Pieroni, A. Fissi, J. L. Houben, and F. Ciardelli
pp 2990 - 2991; DOI:
10.1021/ja00296a036
PDF
Dielectric relaxation studies demonstrate a peptide librational mode in the polypentapeptide of elastin
R. Henze and Dan W. Urry
pp 2991 - 2993; DOI:
10.1021/ja00296a037
PDF
Stereochemical control of yeast reductions. 5. Characterization of the oxidoreductases involved in the reduction of .beta.-keto esters
Woanru Shieh, Aravamudan S. Gopalan, and Charles J. Sih
pp 2993 - 2994; DOI:
10.1021/ja00296a038
PDF
Synthesis and structural characterization of the nitrosylcobalt complex Co(NO)2[PhP(OCH2CH2)2NH]Cl: a novel carbon dioxide carrier
Michele Aresta, Danielle Ballivet-Tkatchenko, Michel C. Bonnet, Rene Faure, and Henri Loiseleur
pp 2994 - 2995; DOI:
10.1021/ja00296a039
PDF
Synthesis of the putative biosynthetic triene precursor of Monensin A
Frank VanMiddlesworth, Dinesh V. Patel, John Donaubauer, Peter Gannett, and Charles J. Sih
pp 2996 - 2997; DOI:
10.1021/ja00296a040
PDF
Enzymic synthesis of unusual sugars: galactose oxidase-catalyzed stereospecific oxidation of polyols
Robert L. Root, J. Robert Durrwachter, and Chi Huey Wong
pp 2997 - 2999; DOI:
10.1021/ja00296a041
PDF
Book Reviews

pp 2999 - 3002; DOI:
10.1021/ja00296a600
PDF

Issue 11


Nuclear magnetic resonance studies of axial amine coordination in synthetic ferryl, (FeIVO)2+, porphyrin complexes and in ferryl myoglobin
Alan L. Balch, Gerd N. La Mar, Lechoslaw Latos-Grazynski, Mark W. Renner, and V. Thanabal
pp 3003 - 3007; DOI:
10.1021/ja00297a001
PDF
Gas-phase thermolysis of 1,5-hexadiene: the continuous wave carbon dioxide laser-induced reaction and studies of the cyclization pathway
J. K. McDonald, J. A. Merritt, B. J. Alley, and S. P. McManus
pp 3008 - 3012; DOI:
10.1021/ja00297a002
PDF
Natural abundance carbon-13 and silicon-29 ENDOR studies of cyclopolysilane radical anions
B. Kirste, R. West, and H. Kurreck
pp 3013 - 3016; DOI:
10.1021/ja00297a003
PDF
Role of weak hydrogen bonding in the coordination of dioxygen to hemoproteins and their models
Geoffrey B. Jameson and Russell S. Drago
pp 3017 - 3020; DOI:
10.1021/ja00297a004
PDF
Flavin analog-metal ion complexes acting as efficient photocatalysts in the oxidation of p-methylbenzyl alcohol by oxygen under irradiation with visible light
Shunichi Fukuzumi, Sadaki Kuroda, and Toshio Tanaka
pp 3020 - 3027; DOI:
10.1021/ja00297a005
PDF
Polymer films on electrodes. 17. The application of simultaneous electrochemical and electron spin resonance techniques for the study of two viologen-based chemically modified electrodes
John G. Gaudiello, Pushpito K. Ghosh, and Allen J. Bard
pp 3027 - 3032; DOI:
10.1021/ja00297a006
PDF
Frequency and intensity considerations in the far-IR spectroscopy of faujasite zeolites: experiment and theory. Metal cation vibrational assignments, site locations, and populations
Mark D. Baker, John Godber, and Geoffrey A. Ozin
pp 3033 - 3043; DOI:
10.1021/ja00297a007
PDF
Identification of proton NMR signals from the metal ligands in cadmium-substituted plastocyanin via two-dimensional multiple-quantum detection in the absence of explicitly resolved proton-cadmium-113 coupling
David H. Live, Christopher L. Kojiro, David Cowburn, and John L. Markley
pp 3043 - 3045; DOI:
10.1021/ja00297a008
PDF
Evidence for a strong .sigma.,.pi. interaction in 3,4,7,8-tetrasilacycloocta-1,5-diyne and 3,4,7,8,11,12-hexasilacyclododeca-1,5,9-triyne
Rolf Gleiter, Wolfgang Schaefer, and Hideki Sakurai
pp 3046 - 3050; DOI:
10.1021/ja00297a009
PDF
Moments and the energies of solids
Jeremy K. Burdett and Stephen Lee
pp 3050 - 3063; DOI:
10.1021/ja00297a010
PDF
Moments method and elemental structures
Jeremy K. Burdett and Stephen Lee
pp 3063 - 3082; DOI:
10.1021/ja00297a011
PDF
Coloring problem
Jeremy K. Burdett, Stephen Lee, and Timothy J. McLarnan
pp 3083 - 3089; DOI:
10.1021/ja00297a012
PDF
When does electronic delocalization become a driving force of molecular shape and stability? 1. The aromatic sextet
Sason S. Shaik and Philippe C. Hiberty
pp 3089 - 3095; DOI:
10.1021/ja00297a013
PDF
The valence-bond description of conjugated molecules. 40. Theoretical study of the Mills-Nixon effect, a phenomenon of .pi.-bond localization in small ring annelated aromatics
Philippe C. Hiberty, Gilles Ohanessian, and Francoise Delbecq
pp 3095 - 3100; DOI:
10.1021/ja00297a014
PDF
A simple relation between nuclear charges and potential surfaces
Paul G. Mezey
pp 3100 - 3105; DOI:
10.1021/ja00297a015
PDF
Linear solvation energy relationships. 29. Solution properties of some tetraalkylammonium halide ion pairs and dissociated ions
Robert W. Taft, Michael H. Abraham, Ruth M. Doherty, and Mortimer J. Kamlet
pp 3105 - 3110; DOI:
10.1021/ja00297a016
PDF
Crystal morphology engineering by "tailor-made" inhibitors; a new probe to fine intermolecular interactions
Ziva Berkovitch-Yellin, J. Van Mil, L. Addadi, M. Idelson, M. Lahav, and L. Leiserowitz
pp 3111 - 3122; DOI:
10.1021/ja00297a017
PDF
Kinetics and mechanism of substitution reactions of some (.eta.3-allyl)manganese tetracarbonyl compounds
G. Todd Palmer and Fred Basolo
pp 3122 - 3129; DOI:
10.1021/ja00297a018
PDF
The carbalkoxymethyl ligand on (.eta.-C5H5)(CO)[P(OCH3)3]FeCH2CO2CH3 as a carbon monoxide-derived C2 template for generating C2 organic ligands and molecules
Edward J. Crawford, Carol Lambert, Kevin P. Menard, and Alan R. Cutler
pp 3130 - 3139; DOI:
10.1021/ja00297a019
PDF
Structure of rhodium in an ultradispersed rhodium/alumina catalyst as studied by EXAFS and other techniques
H. F. J. Van't Blik, J. B. A. D. Van Zon, T. Huizinga, J. C. Vis, D. C. Koningsberger, and R. Prins
pp 3139 - 3147; DOI:
10.1021/ja00297a020
PDF
Stereoselective oxidative addition of hydrogen to iridium(I) complexes. Kinetic control based on ligand electronic effects
Curtis E. Johnson and Richard Eisenberg
pp 3148 - 3160; DOI:
10.1021/ja00297a021
PDF
Study of the reactions of substituted allenes with tris(triphenylphosphine)nickel(0). An analysis of the factors affecting the regio- and stereochemistry of .pi.-complex formation and coupling to form nickelacyclopentane complexes
Daniel J. Pasto, Naizhong Huang, and Charles W. Eigenbrot
pp 3160 - 3172; DOI:
10.1021/ja00297a022
PDF
Synthesis and reactions of a cyclopentadienylidene ketene complex
Charles P. Casey, Joseph M. O'Connor, and Kenneth J. Haller
pp 3172 - 3177; DOI:
10.1021/ja00297a023
PDF
Synthesis and geometry determination of cofacial diporphyrins. EPR spectroscopy of dicopper diporphyrins in frozen solution
Sandra S. Eaton, Gareth R. Eaton, and C. K. Chang
pp 3177 - 3184; DOI:
10.1021/ja00297a024
PDF
Structural studies of syn-1,6:8,13-diimino[14]annulenes. 1. Molecules without bridge connection
Riccardo Destro, Tullio Pilati, Massimo Simonetta, and Emanuel Vogel
pp 3185 - 3191; DOI:
10.1021/ja00297a025
PDF
Structural studies of syn-1,6:8,13-diimino[14]annulenes. 2. Molecules with connected bridges
Riccardo Destro, Tullio Pilati, Massimo Simonetta, and Emanuel Vogel
pp 3192 - 3196; DOI:
10.1021/ja00297a026
PDF
Chemical and spectroscopic studies on copper iodide derived organocuprates: new insight into the composition of Gilman's reagent
Bruce H. Lipshutz, Joseph A. Kozlowski, and Curt M. Breneman
pp 3197 - 3204; DOI:
10.1021/ja00297a027
PDF
Interlocked macrocyclic ligands: a kinetic catenand effect in copper(I) complexes
Anne Marie Albrecht-Gary, Zeinab Saad, Christiane O. Dietrich-Buchecker, and Jean Pierre Sauvage
pp 3205 - 3209; DOI:
10.1021/ja00297a028
PDF
Ground-state analogs of transition states for attack at sulfonyl, sulfinyl, and sulfenyl sulfur: a sulfuranide dioxide (10-S-5) salt, a sulfuranide oxide (10-S-4) salt, and a sulfuranide (10-S-3) salt
C. W. Perkins, S. R. Wilson, and J. C. Martin
pp 3209 - 3218; DOI:
10.1021/ja00297a029
PDF
Heavy-atom kinetic isotope effects in the acid-catalyzed and thermal rearrangements of 2,2'-hydrazonaphthalene. Transition-state differences in their concerted rearrangements
Henry J. Shine, Ewa Gruszecka, Witold Subotkowski, Marilyn Brownawell, and Joseph San Filippo
pp 3218 - 3223; DOI:
10.1021/ja00297a030
PDF
Nucleophilic substitution factors. 1. Coplanar vs. orthogonal bimolecular substitution at a benzylic carbon. X-ray structure of 2-isobutyl-1,3-dihydrobenzo[c]thiophenium perchlorate
J. F. King, G. T. Y. Tsang, M. M. Abdel-Malik, and N. C. Payne
pp 3224 - 3232; DOI:
10.1021/ja00297a031
PDF
Regiospecific sulfonation of secondary hydroxyl groups of .alpha.-cyclodextrin. Its application to preparation of 2A2B, 2A2C-, and 2A2D-disulfonates
Kahee Fujita, Satoru Nagamura, Taiji Imoto, Tsutomu Tahara, and Toshitaka Koga
pp 3233 - 3235; DOI:
10.1021/ja00297a032
PDF
Palladium-catalyzed double carbonylation of aryl halides to give .alpha.-keto amides. Mechanistic studies
Fumiyuki Ozawa, Hidehiko Soyama, Hisayoshi Yanagihara, Issei Aoyama, Hiroaki Takino, Kunisuke Izawa, Takakazu Yamamoto, and Akio Yamamoto
pp 3235 - 3245; DOI:
10.1021/ja00297a033
PDF
Divergent, generalized synthesis of unsymmetrically substituted 2,5-piperazinediones
Robert M. Williams, Robert W. Armstrong, Lynn K. Maruyama, Jen Sen Dung, and Oren P. Anderson
pp 3246 - 3253; DOI:
10.1021/ja00297a034
PDF
Stereocontrolled total synthesis of (.+-.)- and (+)-bicyclomycin
Robert M. Williams, Robert W. Armstrong, and Jen Sen Dung
pp 3253 - 3266; DOI:
10.1021/ja00297a035
PDF
Synthesis of skeletally labeled 3-methylhexaborane(12) and 2-methylpentaborane(9): boron-10 and boron-11 NMR spectral studies of base-catalyzed intramolecular rearrangements in 2-methylpentaborane(9)
Donald F. Gaines and Darrell E. Coons
pp 3266 - 3271; DOI:
10.1021/ja00297a036
PDF
Convergent synthesis of polyether ionophore antibiotics: the synthesis of the monensin spiroketal
Robert E. Ireland, Dieter Haebich, and Daniel W. Norbeck
pp 3271 - 3278; DOI:
10.1021/ja00297a037
PDF
Convergent synthesis of polyether ionophore antibiotics: the synthesis of the monensin bis(tetrahydrofuran) via the Claisen rearrangement of an ester enolate with a .beta.-leaving group
Robert E. Ireland and Daniel W. Norbeck
pp 3279 - 3285; DOI:
10.1021/ja00297a038
PDF
Convergent synthesis of polyether ionophore antibiotics: an approach to the synthesis of the monensin tetrahydropyran-bis(tetrahydrofuran) via the ester enolate Claisen rearrangement and reductive decarboxylation
Robert E. Ireland, Daniel W. Norbeck, Gretchen S. Mandel, and Neil S. Mandel
pp 3285 - 3294; DOI:
10.1021/ja00297a039
PDF
Steady-state kinetic studies of superoxide dismutases: properties of the iron containing protein from Escherichia coli
Christopher Bull and James A. Fee
pp 3295 - 3304; DOI:
10.1021/ja00297a040
PDF
Structural studies of the interaction between indole derivatives and biologically important aromatic compounds. XIII. Ring stacking interaction on the thiamin-tryptophan systems
Toshimasa Ishida, Miyuki Matsui, Masatoshi Inoue, Hiroshi Hirano, Mayumi Yamashita, Kazuaki Sugiyama, Makiko Sugiura, and Kenichi Tomita
pp 3305 - 3314; DOI:
10.1021/ja00297a041
PDF
Hydrolysis of nucleoside phosphates. 9. Comparison of the effectiveness of various metal ions on the promoted dephosphorylation of adenosine 5'-triphosphate (ATP) and uridine 5'-triphosphate (UTP)
Ronald M. Milburn, Mamta Gautam-Basak, Roger Tribolet, and Helmut Sigel
pp 3315 - 3321; DOI:
10.1021/ja00297a042
PDF
Crystal and solution structures of cyclo(Ala-Pro-Gly-D-Phe-Pro): a new type of cyclic pentapeptide which undergoes cis-trans isomerization of the Ala-Pro bond
Lila M. Gierasch, Isabella L. Karle, Arlene L. Rockwell, and Kemal Yenal
pp 3321 - 3327; DOI:
10.1021/ja00297a043
PDF
Synthesis of 7,9-didecarboxymethoxatin (4,5-dihydro-4,5-dioxo-1H-pyrrolo[2,3-f]quinoline-2-carboxylic acid) and comparison of its chemical properties with those of methoxatin and analogous o-quinones. Model studies directed toward the action of PQQ requiring bacterial oxidoreductases and mammalian plasma amine oxidase
Paul R. Sleath, J. Barry Noar, Gert A. Eberlein, and Thomas C. Bruice
pp 3328 - 3338; DOI:
10.1021/ja00297a044
PDF
Photonitrosation promoted by enhanced acidity of singlet-state phenols
Yuan L. Chow and Zheng Zhi Wu
pp 3338 - 3340; DOI:
10.1021/ja00297a045
PDF
syn-[2.2]Metacyclophane: synthesis and facile isomerization to anti-[2.2]metacyclophane. The use of (arene)chromium carbonyl complexes to control the stereochemistry of cyclophanes
Reginald H. Mitchell, Thottumkara K. Vinod, and Gordon W. Bushnell
pp 3340 - 3341; DOI:
10.1021/ja00297a046
PDF
Characterization of 10-hydroxybacteriochlorophyll a by ENDOR and TRIPLE resonance spectroscopy
Wolfgang Lubitz, F. Lendzian, and H. Scheer
pp 3341 - 3343; DOI:
10.1021/ja00297a047
PDF
Simple asymmetric construction of a carbocyclic framework. Direct coupling of dimenthyl succinate and 1,.omega.-dihalides
Akihiro Misumi, Kiyoshi Iwanaga, Kyoji Furuta, and Hisashi Yamamoto
pp 3343 - 3345; DOI:
10.1021/ja00297a048
PDF
X-ray crystal structure of an unsolvated lithium enolate anion
Paul G. Williard and Gene B. Carpenter
pp 3345 - 3346; DOI:
10.1021/ja00297a049
PDF
Synthesis, conformation, and reactivity of the rhenium phosphide complex (diphenylphosphido)(triphenylphosphine)nitrosyl(.eta.5-cyclopentadienyl)rhenium. The "Gauche effect" in transition metal chemistry
William E. Buhro, Savas Georgiou, John P. Hutchinson, and John A. Gladysz
pp 3346 - 3348; DOI:
10.1021/ja00297a050
PDF
Prostaglandin synthesis. 10. An extremely short way to prostaglandins
M. Suzuki, A. Yanagisawa, and R. Noyori
pp 3348 - 3349; DOI:
10.1021/ja00297a051
PDF
Dehydrophenylalanine as the i + 2th residue of a .beta. turn: synthesis and conformational analysis of cyclo(Gly-Pro-.DELTA.z-Phe-D-Ala-Pro) and cyclo(Gly-Pro-D-Phe-D-Ala-Pro)
Alvin C. Bach and Lila M. Gierasch
pp 3349 - 3350; DOI:
10.1021/ja00297a052
PDF
Crystallization-induced changes in protein structure observed by infrared spectroscopy of carbon monoxide liganded to human hemoglobins A and Zurich
William T. Potter, Robert A. Houtchens, and Winslow S. Caughey
pp 3350 - 3352; DOI:
10.1021/ja00297a053
PDF
Catalysis of N-alkyl-1,4-dihydronicotinamide oxidation by a flavopapain: rapid reaction in all catalytic steps
C. Radziejewski, D. P. Ballou, and Emil Thomas Kaiser
pp 3352 - 3354; DOI:
10.1021/ja00297a054
PDF
Trichothecene metabolism studies: isolation and structure determination of 15-acetyl-3.alpha.-(1'.beta.-D-glucopyranosiduronyl)scirpen-3,4.beta.,15-triol
William R. Roush, Michael A. Marletta, Sandra Russo-Rodriguez, and Joanne Recchia
pp 3354 - 3355; DOI:
10.1021/ja00297a055
PDF
Picosecond time-resolved Raman studies of photodissociated carboxymyoglobin
Eric W. Findsen, Thomas W. Scott, Mark R. Chance, Joel M. Friedman, and Mark R. Ondrias
pp 3355 - 3357; DOI:
10.1021/ja00297a056
PDF
Acylation of dienyliron anions. Selective formation of exo or endo acyl substituted iron diene complexes
Gregory M. Williams and Duane E. Rudisill
pp 3357 - 3358; DOI:
10.1021/ja00297a057
PDF
A new iron/sulfur cluster with the (Fe6S6)3+ prismatic core and p-methylphenolate terminal ligands. The synthesis, structure, and properties of (Et4N)3Fe6S6(OC6H4-p-CH3)6
M. G. Kanatzidis, A. Salifoglou, and D. Coucouvanis
pp 3358 - 3360; DOI:
10.1021/ja00297a058
PDF
Independent generation of arene meta photoaddition biradicals
Douglas E. Reedich and Robert S. Sheridan
pp 3360 - 3361; DOI:
10.1021/ja00297a059
PDF
Tetrahydroborate complexes of tantalum: synthesis, characterization, and reactivity of Ta(BH4)H2(PMe3)4
M. L. Luetkens, J. C. Huffman, and A. P. Sattelberger
pp 3361 - 3363; DOI:
10.1021/ja00297a060
PDF
Thermocontrol of ion permeation through ternary composite membranes composed of polymer/liquid crystal/amphiphilic crown ethers
Seiji Shinkai, Shinichiro Nakamura, Shinji Tachiki, Osamu Manabe, and Tisato Kajiyama
pp 3363 - 3365; DOI:
10.1021/ja00297a061
PDF
Organomercurial reagents for the simultaneous introduction of mercury and pH-sensitive reporter functional group into a protein containing no thiol group
Eric Wohlfeil, Cecil H. McMurry, David R. Evans, and Richard A. Hudson
pp 3365 - 3366; DOI:
10.1021/ja00297a062
PDF
The planar C...C ring-opened form of the ethylene oxide radical cation. ESR evidence from anisotropic carbon-13 studies
Xue Zhi Qin, Larry D. Snow, and Ffrancon Williams
pp 3366 - 3368; DOI:
10.1021/ja00297a063
PDF
Determination of adsorption conformation from surface resolution analysis
Dina Farin, Anna Volpert, and David Avnir
pp 3368 - 3370; DOI:
10.1021/ja00297a064
PDF
Ultraviolet resonance Raman spectra of hemoglobin excited at 200 and 218 nm: tertiary and quaternary structure differences
Robert A. Copeland, Siddharth Dasgupta, and Thomas G. Spiro
pp 3370 - 3371; DOI:
10.1021/ja00297a065
PDF
Functionalized crown ethers as an approach to the enzyme model for the synthesis of peptides
Shigeki Sasaki, Mitsuhiko Shionoya, and Kenji Koga
pp 3371 - 3372; DOI:
10.1021/ja00297a066
PDF
Novel globular aggregates composed of synthetic peptide lipids
Yukito Murakami, Junichi Kikuchi, Toshihiko Takaki, and Katsuya Uchimura
pp 3373 - 3374; DOI:
10.1021/ja00297a067
PDF
Regioselective nucleophilic C-alkylation of the pyrrole ring in an (.eta.-pyrrolyl)iodohydridorhenium complex
Hugh Felkin and Janusz Zakrzewski
pp 3374 - 3375; DOI:
10.1021/ja00297a068
PDF
Design of stereoselective etchants for organic crystals. Application for the sorting of enantiomorphs and direct assignment of absolute configuration of chiral molecules
L. J. W. Shimon, M. Lahav, and L. Leiserowitz
pp 3375 - 3377; DOI:
10.1021/ja00297a069
PDF
Olefin insertion in a metal alkyl in a Ziegler polymerization system
Leigh Clawson, Jorge Soto, Stephen L. Buchwald, Michael L. Steigerwald, and Robert H. Grubbs
pp 3377 - 3378; DOI:
10.1021/ja00297a070
PDF
2,2-Dimesityl-1-(2,4,6-tri-tert-butylphenyl)germaphosphene: the first stable compound with a germanium-phosphorus double bond
Jean Escudie, Claude Couret, Jacques Satge, Mbolatiana Andrianarison, and Jean Dominique Andriamizaka
pp 3378 - 3379; DOI:
10.1021/ja00297a071
PDF
Resonance Raman studies of the photoreduction of horseradish peroxidase compounds I and II
Harold E. Van Wart and John Zimmer
pp 3379 - 3381; DOI:
10.1021/ja00297a072
PDF
Observation of the ultraviolet absorption spectrum of phenyl radical in the gas phase
Noriaki Ikeda, Nobuaki Nakashima, and Keitaro Yoshihara
pp 3381 - 3382; DOI:
10.1021/ja00297a073
PDF
Nitric oxide adduct of the binuclear iron center in deoxyhemerythrin from Phascolopsis gouldii. Analog of a putative intermediate in the oxygenation reaction
Judith M. Nocek, Donald M. Kurtz, J. Timothy Sage, Peter G. Debrunner, Michael J. Maroney, and Lawrence Que
pp 3382 - 3384; DOI:
10.1021/ja00297a074
PDF
Electronic structure of a metalated doubly bonded Group 15 complex
Kimberly A. Schugart and Richard F. Fenske
pp 3384 - 3385; DOI:
10.1021/ja00297a075
PDF
Gas-phase reactions of the acetyl anion
Charles H. DePuy, Veronica M. Bierbaum, Robert Damrauer, and John A. Soderquist
pp 3385 - 3386; DOI:
10.1021/ja00297a076
PDF
Energetics of a homogeneous gas-phase photocatalytic system: the hydrogenation of ethylene by Fe(CO)4(C2H4)
Michael E. Miller and Edward R. Grant
pp 3386 - 3387; DOI:
10.1021/ja00297a077
PDF
Synthesis and reactions of hydrido(.eta.1-allyl)- and hydrido(.eta.3-allyl)iridium complexes
William D. McGhee and Robert G. Bergman
pp 3388 - 3389; DOI:
10.1021/ja00297a078
PDF
Metaphosphate and metaphosphonic anhydride formation by thermolysis of 5,6-oxaphosphabicyclo[2.2.2]octenes; electrophilic .alpha.-substitution on a pyrrole
Louis D. Quin and Brian G. Marsi
pp 3389 - 3390; DOI:
10.1021/ja00297a079
PDF
The structure of the C4H6CH3+-cation. 13C- and 1H-NMR-spectroscopic investigation of equilibrium isotope effects in deuterated methylbicyclobutonium ions
Hans Ullrich Siehl
pp 3390 - 3392; DOI:
10.1021/ja00297a080
PDF
(2-Alkynylethenyl)ketenes. A new quinone synthesis
J. Olle Karlsson, Nghi V. Nguyen, Lafayette D. Foland, and Harold W. Moore
pp 3392 - 3393; DOI:
10.1021/ja00297a081
PDF
Hydrolysis of mustard derivatives. Failure of the Raber-Harris probe in predicting nucleophilic assistance
Samuel P. McManus, N. Neamati-Mazraeh, B. A. Hovanes, S. M. Paley, and J. M. Harris
pp 3393 - 3395; DOI:
10.1021/ja00297a082
PDF
Liquid crystals and plastic solids. A carbon-13 NMR study
Bing Man Fung and Mahinda Gangoda
pp 3395 - 3396; DOI:
10.1021/ja00297a083
PDF
Synthesis and structure of the first 20-Bi-9 system: a discrete nine-coordinate 20-electron bismuth
Constantine A. Stewart, Joseph C. Calabrese, and Anthony J. Arduengo
pp 3397 - 3398; DOI:
10.1021/ja00297a084
PDF
Book Reviews

pp 3399 - 3400; DOI:
10.1021/ja00297a600
PDF

Issue 12


The electron spin resonance spectrum of the tyrosyl radical
Roger C. Sealy, Laura Harman, Paul R. West, and Ronald P. Mason
pp 3401 - 3406; DOI:
10.1021/ja00298a001
PDF
Extended scope of chiral recognition applying hydrogen bond associations in nonaqueous media: (R,R)-N,N'-diisopropyltartramide (DIPTA) as a widely applicable resolving agent
Yasuo Dobashi and Shoji Hara
pp 3406 - 3411; DOI:
10.1021/ja00298a002
PDF
Electron-transfer reactions associated with host-guest complexation. Oxidation of ferrocenecarboxylic acid in the presence of .beta.-cyclodextrin
Tomokazu Matsue, Dennis H. Evans, Tetsuo Osa, and Nagao Kobayashi
pp 3411 - 3417; DOI:
10.1021/ja00298a003
PDF
Models for ferredoxins: electronic structures of iron-sulfur clusters with one, two, and four iron atoms
Louis Noodleman, Joe G. Norman, Joseph H. Osborne, Arie Aizman, and David A. Case
pp 3418 - 3426; DOI:
10.1021/ja00298a004
PDF
Properties of some protein denaturants in N,N-dimethylformamide. Enthalpic interaction coefficients of urea and substituted urea compounds
M. Bloemendal and G. Somsen
pp 3426 - 3431; DOI:
10.1021/ja00298a005
PDF
Stable composite polyelectrolyte electrode coatings with morphologies that yield large ion-exchange capacities and high cross-coating charge propagation rates
Donald D. Montgomery and Fred C. Anson
pp 3431 - 3436; DOI:
10.1021/ja00298a006
PDF
Quenching and possible Coulombic complexation of the pyrene-N,N-dimethylaniline exciplex by tetraalkylammonium salts
Rolfe J. Hartley and Larry R. Faulkner
pp 3436 - 3442; DOI:
10.1021/ja00298a007
PDF
Electrocatalysis at redox polymer electrodes with separation of the catalytic and charge propagation roles. Reduction of dioxygen to hydrogen peroxide as catalyzed by cobalt(II) tetrakis(4-N-methylpyridyl)porphyrin
Fred C. Anson, Ching Long Ni, and Jean Michel Saveant
pp 3442 - 3450; DOI:
10.1021/ja00298a008
PDF
Nucleophile and aryl radical reactivity in SRN1 aromatic nucleophilic substitution reactions. Absolute and relative electrochemical determination
Christian Amatore, Mehmet A. Oturan, Jean Pinson, Jean Michel Saveant, and Andre Thiebault
pp 3451 - 3459; DOI:
10.1021/ja00298a009
PDF
Spectroscopic assignment of d-d transitions of achiral metal complexes using circular dichroism: DICD of cobalt(III) complexes in sugar solutions
Pieter E. Schipper and Alison Rodger
pp 3459 - 3465; DOI:
10.1021/ja00298a010
PDF
Dimerization paths of CH2 and SiH2 fragments to ethylene, disilene, and silaethylene: MCSCF and MRCI study of least- and non-least-motion paths
Katsuhisa Ohta, Ernest R. Davidson, and Keiji Morokuma
pp 3466 - 3471; DOI:
10.1021/ja00298a011
PDF
Coordination chemistry and geometries of some 4,4'-bipyridyl-capped porphyrins. Proton- and ligand-induced switching of conformations
Raymond J. Abraham, Philip Leighton, and Jeremy K. M. Sanders
pp 3472 - 3478; DOI:
10.1021/ja00298a012
PDF
Metal-nucleotide interactions. 3. Oxygen-17, phosphorus-31, and proton NMR studies on the interaction of scandium(III), lanthanum(III), and lutetium(III) with adenosine 5'-triphosphate
Yuen Jund Shyy, Tsun Chung Tsai, and Ming Daw Tsai
pp 3478 - 3484; DOI:
10.1021/ja00298a013
PDF
Uncovering remote nuclear-spin connectivities by relayed zero and double quantum coherence
Luciano Muller and Arthur Pardi
pp 3484 - 3487; DOI:
10.1021/ja00298a014
PDF
Application of linear free energy relationships to calculated stabilization energies of strained and unsaturated molecules
Arthur Greenberg and Tyler A. Stevenson
pp 3488 - 3494; DOI:
10.1021/ja00298a015
PDF
Lyomesophases of the diethylammonium flufenamate-water system studied by deuterium NMR spectroscopy
I. Kustanovich, R. Poupko, H. Zimmermann, Z. Luz, and M. M. Labes
pp 3494 - 3501; DOI:
10.1021/ja00298a016
PDF
Synthesis of trimethylphosphine-substituted (pentamethylcyclopentadienyl)iridium hydride complexes; protonation and deprotonation of (pentamethylcyclopentadienyl)(trimethylphosphine)iridium dihydride
Thomas M. Gilbert and Robert G. Bergman
pp 3502 - 3507; DOI:
10.1021/ja00298a017
PDF
(Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compounds
Thomas M. Gilbert, Frederick J. Hollander, and Robert G. Bergman
pp 3508 - 3516; DOI:
10.1021/ja00298a018
PDF
The photochemistry of palladium and platinum homo- and heteronuclear metal-metal .sigma.-bonds: efficient photogeneration of 15-electron radicals
Mark K. Reinking, Marc L. Kullberg, Ann R. Cutler, and Clifford P. Kubiak
pp 3517 - 3524; DOI:
10.1021/ja00298a019
PDF
Reactions of Re2Cl4(dppm)2 with carbon monoxide that proceed with retention of the metal-metal bond: synthesis of Re2Cl4(dppm)2(CO)n (n = 1, 2) and the structural characterization of Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CO)
F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Larry R. Falvello, Stephen M. Tetrick, and Richard A. Walton
pp 3524 - 3530; DOI:
10.1021/ja00298a020
PDF
Homolysis and electron-transfer reactions of benzylcobalamin
Reed J. Blau and James H. Espenson
pp 3530 - 3533; DOI:
10.1021/ja00298a021
PDF
Cobalt(III) alkylperoxy complexes. Synthesis, x-ray structure, and role in the catalytic decomposition of alkyl hydroperoxides and in the hydroxylation of hydrocarbons
Lucien Saussine, Eric Brazi, Alain Robine, Hubert Mimoun, Jean Fischer, and Raymond Weiss
pp 3534 - 3540; DOI:
10.1021/ja00298a022
PDF
Halide-promoted insertion of carbon monoxide into osmium-.mu.-methylene bonds in triosmium clusters
Eric D. Morrison and Gregory L. Geoffroy
pp 3541 - 3545; DOI:
10.1021/ja00298a023
PDF
Formation of glycol monoacetates in the oxidation of olefins catalyzed by metal nitro complexes: mono- vs. bimetallic system
Frank Mares, Steven E. Diamond, Francis J. Regina, and Jeffrey P. Solar
pp 3545 - 3552; DOI:
10.1021/ja00298a024
PDF
Metal-promoted fusion and linkage of B5H8-, 1-XB5H7- (X = D, CH3), B10H13-, and (.eta.5-C5H5)CoB4H7-. Facile routes to B10H14 and (.eta.5-C5H5)2Co2B8H10 isomers
Cynthia T. Brewer and Russell N. Grimes
pp 3552 - 3557; DOI:
10.1021/ja00298a025
PDF
Metal-promoted fusion of B6H9-. Directed synthesis and structural characterization of dodecaborane(16), B12H16
Cynthia T. Brewer, Robert G. Swisher, Ekk Sinn, and Russell N. Grimes
pp 3558 - 3564; DOI:
10.1021/ja00298a026
PDF
The rhodium-catalyzed carbonylation of linear primary alcohols
Thomas W. Dekleva and Denis Forster
pp 3565 - 3567; DOI:
10.1021/ja00298a027
PDF
Studies into the mechanism of the rhodium-catalyzed carbonylation of isopropyl alcohol
Thomas W. Dekleva and Denis Forster
pp 3568 - 3572; DOI:
10.1021/ja00298a028
PDF
Dinuclear aryloxide chemistry. 4. Effect of aryloxide ancillary ligands on the chemistry of molybdenum-molybdenum and tungsten-tungsten multiple metal-metal bonds
Timothy W. Coffindaffer, Gerald P. Niccolai, Douglas Powell, and Ian P. Rothwell
pp 3572 - 3583; DOI:
10.1021/ja00298a029
PDF
Tungsten as a weak backscatter: an example of information loss in extended x-ray absorption fine structure (EXAFS) spectroscopy. Tungsten and iron EXAFS studies of tungsten-iron-sulfur clusters containing the WS2Fe unit
Mark R. Antonio, Boon K. Teo, and Bruce A. Averill
pp 3583 - 3590; DOI:
10.1021/ja00298a030
PDF
Simultaneous binding of platinum(II) to three different sites (N7, N1, N3) of a guanine nucleobase
Gabriele Raudaschl-Sieber, Helmut Schoellhorn, Ulf Thewalt, and Bernhard Lippert
pp 3591 - 3595; DOI:
10.1021/ja00298a031
PDF
Ammoniation, acid dissociation, and hydrogen exchange of chloropentaamminecobalt(2+) ion and cis- and trans-dichlorotetraamminecobalt(1+) ion in liquid ammonia
Sijbe Balt and Hendrikus J. Gamelkoorn
pp 3596 - 3600; DOI:
10.1021/ja00298a032
PDF
l-2-Nitro-1,3-alkanediols by stereoselective addition of nitroethanol to aldehydes. On the asymmetric electrophilic addition to double bonds
Martin Eyer and Dieter Seebach
pp 3601 - 3606; DOI:
10.1021/ja00298a033
PDF
Direct observation and chemistry of biradicals from photochemical decarbonylation of .alpha.-perphenylated cycloalkanones
D. H. R. Barton, B. Charpiot, Keith U. Ingold, L. J. Johnston, W. B. Motherwell, J. C. Scaiano, and S. Stanforth
pp 3607 - 3611; DOI:
10.1021/ja00298a034
PDF
Nucleophilic addition to olefins. 12. Solvent-induced change in the rate-limiting step of the hydrolysis of benzylidenemalononitrile in acidic dimethyl sulfoxide-water solution
Claude F. Bernasconi, Anastassia Kanavarioti, and Robert B. Killion
pp 3612 - 3620; DOI:
10.1021/ja00298a035
PDF
Photochemical reactions in organized assemblies. Part 41. Bromination of surfactant and hydrophobic trans-stilbenes in aqueous micelles and vesicles. Evidence for wide variation of solubilization/reaction sites in microheterogeneous media
Tadashi Mizutani and David G. Whitten
pp 3621 - 3625; DOI:
10.1021/ja00298a036
PDF
Reactivity and stereochemical studies of the [2 + 2] cycloaddition of 1,1-difluoroallene and styrene
William R. Dolbier and Gene E. Wicks
pp 3626 - 3631; DOI:
10.1021/ja00298a037
PDF
Stereodynamics of intramolecular triplet energy transfer in carotenoporphyrins
Devens Gust, Thomas A. Moore, Rene V. Bensasson, Paul Mathis, Edward J. Land, Claude Chachaty, Ana L. Moore, Paul A. Liddell, and Gregory A. Nemeth
pp 3631 - 3640; DOI:
10.1021/ja00298a038
PDF
Acid-catalyzed enolization and aldol condensation of acetaldehyde
Lynn M. Baigrie, Robin A. Cox, Henryka Slebocka-Tilk, Michal Tencer, and Thomas T. Tidwell
pp 3640 - 3645; DOI:
10.1021/ja00298a039
PDF
Host-guest complexation. 35. Spherands, the first completely preorganized ligand systems
Donald J. Cram, Takahiro Kaneda, Roger C. Helgeson, S. Bruce Brown, Carolyn B. Knobler, Emily Maverick, and Kenneth N. Trueblood
pp 3645 - 3657; DOI:
10.1021/ja00298a040
PDF
Host-guest complexation. 36. Spherand and lithium and sodium ion complexation rates and equilibria
Donald J. Cram and George M. Lein
pp 3657 - 3668; DOI:
10.1021/ja00298a041
PDF
Stable simple enols. 11. Equilibrium constants for the 1-alkyl-2,2-dimesitylethenol/1-alkyl-2,2-dimesitylethanone systems in hexane. The predominance of steric effects on Kenol values
David A. Nugiel and Zvi Rappoport
pp 3669 - 3676; DOI:
10.1021/ja00298a042
PDF
Stereo- and regioselective palladium-catalyzed 1,4-acetoxychlorination of 1,3-dienes. 1-Acetoxy-4-chloro-2-alkenes as versatile synthons in organic transformations
Jan E. Baeckvall, Jan E. Nystroem, and Ruth E. Nordberg
pp 3676 - 3686; DOI:
10.1021/ja00298a043
PDF
Synthesis, thermolysis, and photolysis of the azoalkane 4,5-diazatricyclo[4.3.03,7]nona-4,8-diene: denitrogenation vs. azirane formation
Waldemar Adam and Karlheinz Hill
pp 3686 - 3689; DOI:
10.1021/ja00298a044
PDF
Conant-Swan fragmentation reaction: stereochemistry of phosphate ester formation
Kim C. Calvo
pp 3690 - 3694; DOI:
10.1021/ja00298a045
PDF
Biosynthesis of the hypocholesterolemic agent mevinolin by Aspergillus terreus. Determination of the origin of carbon, hydrogen, and oxygen atoms by carbon-13 NMR and mass spectrometry
Richard N. Moore, Glen Bigam, Jean K. Chan, Alan M. Hogg, Thomas T. Nakashima, and John C. Vederas
pp 3694 - 3701; DOI:
10.1021/ja00298a046
PDF
Distal and proximal control of ligand reactivity: a transient Raman comparison of COHbA and COHb (Zurich)
Thomas W. Scott, Joel M. Friedman, and Victor W. Macdonald
pp 3702 - 3705; DOI:
10.1021/ja00298a047
PDF
Tautomeric nature of quinonoid 6,7-dimethyl-7,8-dihydro-6H-pterin in aqueous solution: a nitrogen-15 NMR study
Stephen J. Benkovic, Douglas Sammons, Wilfred L. F. Armarego, Paul Waring, and Ruth Inners
pp 3706 - 3712; DOI:
10.1021/ja00298a048
PDF
Chiral discrimination and solid-state carbon-13 NMR. Application to tri-o-thymotide clathrates
J. A. Ripmeester and N. E. Burlinson
pp 3713 - 3714; DOI:
10.1021/ja00298a049
PDF
Ruthenium(IV) and osmium(IV) chalcogen complexes of carbon monoxide
Michelle Millar, Timothy O'Sullivan, Nadine De Vries, and Stephen A. Koch
pp 3714 - 3715; DOI:
10.1021/ja00298a050
PDF
[5]Paracyclophane
Leonardus W. Jenneskens, Franciscus J. J. De Kanter, Paulus A. Kraakman, Lucas A. M. Turkenburg, Willem E. Koolhaas, Willem H. De Wolf, Friedrich Bickelhaupt, Yoshito Tobe, Kiyomi Kakiuchi, and Yoshinobu Odaira
pp 3716 - 3717; DOI:
10.1021/ja00298a051
PDF
Acetylene derivatives of titanocene
Helmut G. Alt, Heidi E. Engelhardt, Marvin D. Rausch, and Lawrence B. Kool
pp 3717 - 3718; DOI:
10.1021/ja00298a052
PDF
Threshold resonances in electron photodetachment spectra. Structural evidence for dipole-supported states
Jeffrey Marks, Paul B. Comita, and John I. Brauman
pp 3718 - 3719; DOI:
10.1021/ja00298a053
PDF
Dependence of rate constants of heterogeneous electron transfer reactions on viscosity
X. Zhang, Johna Leddy, and Allen J. Bard
pp 3719 - 3721; DOI:
10.1021/ja00298a054
PDF
Evidence for hydrogen atom abstraction and loss of diylophile stereochemistry in an intramolecular 1,3-diyl trapping reaction
Onorato Campopiano, R. Daniel Little, and Jeffrey L. Petersen
pp 3721 - 3722; DOI:
10.1021/ja00298a055
PDF
Tetranuclear carbidotungsten and nitridomolybdenum clusters supported by alkoxide ligands: W4(C)(OCHMe2)12(NMe) and Mo4(N)2(OCHMe2)12
Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, Joseph Leonelli, Nancy S. Marchant, Crystal A. Smith, and Lester C. E. Taylor
pp 3722 - 3724; DOI:
10.1021/ja00298a056
PDF
Synthesis, structure, and carbon-carbon bond-forming reactions of carbon-bound molybdenum, tungsten, and rhenium enolates. Detection of an .eta.3-oxaallyl intermediate
Jeffrey J. Doney, Robert G. Bergman, and Clayton H. Heathcock
pp 3724 - 3726; DOI:
10.1021/ja00298a057
PDF
Selective catalytic oxidation of organic compounds by nitrogen dioxide
Stefan A. Nyarady and Robert E. Sievers
pp 3726 - 3727; DOI:
10.1021/ja00298a058
PDF
Identification of rubidium(1-) ion and complexed rubidium(1+) ion in alkalides and electrides by x-ray absorption spectroscopy (XANES and EXAFS)
Odette Fussa, Susan Kauzlarich, James L. Dye, and Boon K. Teo
pp 3727 - 3728; DOI:
10.1021/ja00298a059
PDF
Reductive homologation of carbon monoxide to a ketenecarboxylate by a low-valent organolanthanide complex: synthesis and x-ray crystal structure of [(C5Me5)4Sm2(O2CCCO)(THF)]2
William J. Evans, Jay W. Grate, Laura A. Hughes, Hongming Zhang, and Jerry L. Atwood
pp 3728 - 3730; DOI:
10.1021/ja00298a060
PDF
Carboxylate bridge exchange reactions in the {Fe2O(O2CR)2}2+ core. Synthesis, structure, and properties of phosphodiester-bridged complexes
William H. Armstrong and Stephen J. Lippard
pp 3730 - 3731; DOI:
10.1021/ja00298a061
PDF
Synthetic and biological studies of compactin and related compounds. 4. Total synthesis of (+)-compactin
Terry Rosen and Clayton H. Heathcock
pp 3731 - 3733; DOI:
10.1021/ja00298a062
PDF
High-resolution nuclear magnetic resonance spectroscopy of quadrupolar nuclei: nitrogen-14 and oxygen-17 examples
Jan M. Robert and Ronald F. Evilia
pp 3733 - 3735; DOI:
10.1021/ja00298a063
PDF
N-Alkylporphyrin formation during the reactions of cytochrome P-450 model systems
Toshio Mashiko, David Dolphin, Taku Nakano, and T. G. Traylor
pp 3735 - 3736; DOI:
10.1021/ja00298a064
PDF
Formation of an iron(IV)-oxo "picket-fence" porphyrin derivative via reduction of the ferrous dioxygen adduct and reaction with carbon dioxide
M. Schappacher, R. Weiss, R. Montiel-Montoya, A. Trautwein, and A. Tabard
pp 3736 - 3738; DOI:
10.1021/ja00298a065
PDF
The gold/GaPc-Cl/ferri, ferrocyanide/GaPc-Cl/platinum photoelectrochemical cell
William J. Buttner, Peter C. Rieket, and Neal R. Armstrong
pp 3738 - 3739; DOI:
10.1021/ja00298a066
PDF
Size and selectivity of zeolite chemistry. A remarkable effect of additive on the products produced in the photolyses of ketones
Nicholas J. Turro, Chen Chih Cheng, Xue Gong Lei, and Edith M. Flanigen
pp 3739 - 3741; DOI:
10.1021/ja00298a067
PDF
Additions and Corrections - Zoanthamine: A Novel Alkaloid from a Marine Zoanthid
C. Beemasankara Rao, A. S. R. Anjaneyulu, N. S. Sarma, Y. Venkateswarlu, Richard M. Rosser, D. John Faulkner, Marine H. M. Chen, and Jon Clardy
pp 3741 - 3741; DOI:
10.1021/ja00298a601
PDF
Additions and Corrections - Treatment of Electrostatic Effects within the Molecular Mechanics Method
Ljiljana Dosen-Micovic, Dragoslav Jeremic, and Norman L. Allinger
pp 3741 - 3741; DOI:
10.1021/ja00298a602
PDF
Book Reviews

pp 3742 - 3746; DOI:
10.1021/ja00298a600
PDF

Issue 13


Kinetics and equilibria of chloride transfer reactions. Stabilities of carbocations based on chloride and hydride transfer equilibria measurements
R. B. Sharma, D. K. Sen Sharma, K. Hiraoka, and P. Kebarle
pp 3747 - 3757; DOI:
10.1021/ja00299a001
PDF
Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+
Dilip K. Sen Sharma, Sarah Meza de Hoejer, and Paul Kebarle
pp 3757 - 3762; DOI:
10.1021/ja00299a002
PDF
Formation of ionic transition-metal carbonyl cluster fragments by ion-molecule reactions. 1. The chromium hexacarbonyl and iron pentacarbonyl systems
DonnaJean Anderson Fredeen and David H. Russell
pp 3762 - 3768; DOI:
10.1021/ja00299a003
PDF
Conversions over low barriers. 4. Dimer/monomer dissociation in formic acid
K. I. Lazaar and S. H. Bauer
pp 3769 - 3772; DOI:
10.1021/ja00299a004
PDF
Resonance Raman studies of the excited electronic states of imidazolepentacyanoferrate(III)(2-) and imidazolepentaammineruthenium(III)(3+) ions
Colleen M. Jones, Craig R. Johnson, Sanford A. Asher, and Rex E. Shepherd
pp 3772 - 3780; DOI:
10.1021/ja00299a005
PDF
Isomerization of cyclopropylidene to allene
Arvi Rauk, Willem J. Bouma, and Leo Radom
pp 3780 - 3786; DOI:
10.1021/ja00299a006
PDF
Generalization of the Born equation to nonspherical solvent cavities
Joel I. Gersten and Anne Marie Sapse
pp 3786 - 3788; DOI:
10.1021/ja00299a007
PDF
Rearrangement and fragmentation processes on the potential energy surfaces of thioformaldehyde molecule and cation
Susan A. Pope, Ian H. Hillier, and Martyn F. Guest
pp 3789 - 3800; DOI:
10.1021/ja00299a008
PDF
Theoretical determination of molecular structure and conformation. 15. Three-membered rings: bent bonds, ring strain, and surface delocalization
Dieter Cremer and Elfi Kraka
pp 3800 - 3810; DOI:
10.1021/ja00299a009
PDF
Theoretical determination of molecular structure and conformation. 16. Substituted cyclopropanes - an electron density model of substituent-ring interactions
Dieter Cremer and Elfi Kraka
pp 3811 - 3819; DOI:
10.1021/ja00299a010
PDF
Picosecond dynamics of the Paterno-Buechi reaction
Steven C. Freilich and Kevin S. Peters
pp 3819 - 3822; DOI:
10.1021/ja00299a011
PDF
Preparation and electrical response of solid polymer electrolytes with only one mobile species
L. Charles Hardy and Duward F. Shriver
pp 3823 - 3828; DOI:
10.1021/ja00299a012
PDF
8,8'-Bi(8-azabicyclo[3.2.1]octane) and its oxidized forms
Stephen F. Nelsen, Glen T. Cunkle, Dennis H. Evans, Kenneth J. Haller, Menahem Kaftory, Burkhard Kirste, Harry Kurreck, and Timothy Clark
pp 3829 - 3839; DOI:
10.1021/ja00299a013
PDF
Photoinduced electron-transfer reactions: rearrangement of a bicyclopropenyl radical cation
Christopher J. Abelt and Heinz D. Roth
pp 3840 - 3843; DOI:
10.1021/ja00299a014
PDF
Synthesis and structures of the tellurium-bridged molybdenum iron carbonyl cluster (C5H5)2Mo2FexTe2(CO)7 (x = 1, 2). Cluster assembly mechanisms and the role of the tellurium
Leonard E. Bogan, Thomas B. Rauchfuss, and Arnold L. Rheingold
pp 3843 - 3850; DOI:
10.1021/ja00299a015
PDF
Mononuclear and binuclear cationic complexes of vanadium(II)
F. Albert Cotton, Stan A. Duraj, Leo E. Manzer, and Wieslaw J. Roth
pp 3850 - 3855; DOI:
10.1021/ja00299a016
PDF
Structure and redox properties of the water-oxidation catalyst [(bpy)2(OH2)RuORu(OH2)(bpy)2]4+
John A. Gilbert, Drake S. Eggleston, Wyatt R. Murphy, Daniel A. Geselowitz, Susan W. Gersten, Derek J. Hodgson, and Thomas J. Meyer
pp 3855 - 3864; DOI:
10.1021/ja00299a017
PDF
Stereochemical and electronic spin state tuning of the metal center in the nickel(II) tropocoronands
William M. Davis, Michael M. Roberts, Arie Zask, Koji Nakanishi, Tetsuo Nozoe, and Stephen J. Lippard
pp 3864 - 3870; DOI:
10.1021/ja00299a018
PDF
Synthesis, structure, and properties of pentathiepins
B. L. Chenard, R. L. Harlow, A. L. Johnson, and S. A. Vladuchick
pp 3871 - 3879; DOI:
10.1021/ja00299a019
PDF
Expeditious synthesis of resistomycin
T. Ross Kelly and Mitali Ghoshal
pp 3879 - 3884; DOI:
10.1021/ja00299a020
PDF
Synthesis and valence orbital structures of azacycl[3.3.3]azines in a systematic series
Mitchell A. Rossman, Nelson J. Leonard, Shigeyuki Urano, and Pierre R. LeBreton
pp 3884 - 3890; DOI:
10.1021/ja00299a021
PDF
A stereospecific route to aziridinomitosanes: the synthesis of novel mitomycin congeners
Samuel Danishefsky, Ellen M. Berman, Marco Ciufolini, Sarah Jane Etheredge, and Brigitte E. Segmuller
pp 3891 - 3898; DOI:
10.1021/ja00299a022
PDF
Development and use of quantum molecular models. 75. Comparative tests of theoretical procedures for studying chemical reactions
Michael J. S. Dewar and Donn M. Storch
pp 3898 - 3902; DOI:
10.1021/ja00299a023
PDF
Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model
Michael J. S. Dewar, Eve G. Zoebisch, Eamonn F. Healy, and James J. P. Stewart
pp 3902 - 3909; DOI:
10.1021/ja00299a024
PDF
Synthesis and structure of some 3-aza[5]- and 3-aza[6](1,7)naphthalenophanes
John B. Bremner, Lutz M. Engelhardt, Allan H. White, and Kevin N. Winzenberg
pp 3910 - 3915; DOI:
10.1021/ja00299a025
PDF
Application of [2,3] sigmatropic (Wittig) rearrangements in synthesis. The synthesis of (+)-Prelog-Djerassi lactone
David J. S. Tsai and M. Mark Midland
pp 3915 - 3918; DOI:
10.1021/ja00299a026
PDF
Ionization of the phosphorus-hydrogen bond in diethyl phosphonate
Edward S. Lewis and L. Gene Spears
pp 3918 - 3921; DOI:
10.1021/ja00299a027
PDF
The 185-nm photochemistry of cyclobutene and bicyclo[1.1.0]butane
Waldemar Adam, Thomas Oppenlaender, and Gerald Zang
pp 3921 - 3924; DOI:
10.1021/ja00299a028
PDF
The 185-nm photochemistry of bicyclo[2.1.0]pentane and cyclopentene
Waldemar Adam and Thomas Oppenlaender
pp 3924 - 3928; DOI:
10.1021/ja00299a029
PDF
Considered stable cations. 259. Application of the Gassman-Fentiman tool of increasing electron demand to the carbon-13 NMR spectroscopic study of 1-aryl-3-methylbut-2-enyl (allylic) and 2-arylpent-3-yn-2-yl (propargylic) cations
G. K. Surya Prakash, V. V. Krishnamurthy, George A. Olah, and D. G. Farnum
pp 3928 - 3935; DOI:
10.1021/ja00299a030
PDF
Silacyclopropylcarbinyl and cyclopropylsilylenium cations in the aluminum chloride-induced rearrangements of (chloromethyl)vinylsilanes
Larry R. Robinson, Gary T. Burns, and Thomas J. Barton
pp 3935 - 3941; DOI:
10.1021/ja00299a031
PDF
Kinetic study of the photoisomerization of a protonated Schiff base of 11-cis-retinal over the picosecond-to-second time regimes
Ralph S. Becker, Kenn Freedman, J. A. Hutchinson, and Lewis J. Noe
pp 3942 - 3944; DOI:
10.1021/ja00299a032
PDF
Versatile photochemical behavior of phosphorus azides: Curtius-type rearrangement and diverse fates of .alpha.-phosphorus nitrenes
Antoine Baceiredo, Guy Bertrand, Jean Pierre Majoral, Fatiha El Anba, and George Manuel
pp 3945 - 3949; DOI:
10.1021/ja00299a033
PDF
Redox-switched crown ethers. 3. Cyclic-acyclic interconversion coupled with redox between dithiol and disulfide and its application to membrane transport
Seiji Shinkai, Kenichi Inuzuka, Osamu Miyazaki, and Osamu Manabe
pp 3950 - 3955; DOI:
10.1021/ja00299a034
PDF
Excited-state proton-transfer reactions of naphthylammonium ion-18-crown-6 complexes
Haruo Shizuka, Kosei Kameta, and Tsutomu Shinozaki
pp 3956 - 3963; DOI:
10.1021/ja00299a035
PDF
Cumulene photochemistry: photorearrangments of tetraphenyl and triphenyl C3 isomers
Michael W. Klett and Richard P. Johnson
pp 3963 - 3971; DOI:
10.1021/ja00299a036
PDF
Cumulene photochemistry: singlet and triplet photorearrangements of 1,2-cyclononadiene
Thomas J. Stierman and Richard P. Johnson
pp 3971 - 3980; DOI:
10.1021/ja00299a037
PDF
Reductions of activated carbonyl compounds with chiral-bridged 1,4-dihydropyridines. An investigation of scope and structural effects
Auke G. Talma, Patrick Jouin, Johannes G. De Vries, C. B. Troostwijk, Gerard H. Werumeus Buning, Jan K. Waninge, Johnny Visscher, and Richard M. Kellogg
pp 3981 - 3997; DOI:
10.1021/ja00299a038
PDF
Substituent and conformational effects on the ring current in 9-arylmethylenecyclooctatrienyl anions
Stuart W. Staley, Charles K. Dustman, and Gerard E. Linkowski
pp 3997 - 4003; DOI:
10.1021/ja00299a039
PDF
Electron-transfer valence tautomerism. The bicyclooctatetraenyl and 1,2-dicyclooctatetraenylethylene dianions
Stuart W. Staley, Charles K. Dustman, Kevin L. Facchine, and Gerard E. Linkowski
pp 4003 - 4007; DOI:
10.1021/ja00299a040
PDF
Conformational analysis of a cyclic enkephalin analog by proton NMR and computer simulations
Nancy J. Mammi, Moises Hassan, and Murray Goodman
pp 4008 - 4013; DOI:
10.1021/ja00299a041
PDF
Electronic structures of active site models for compounds I and II of peroxidase
Stephen F. Sontum and David A. Case
pp 4013 - 4015; DOI:
10.1021/ja00299a042
PDF
Substrate analog binding to the coupled binuclear copper active site in tyrosinase
Dean E. Wilcox, Arturo G. Porras, Yeong T. Hwang, Konrad Lerch, Marjorie E. Winkler, and Edward I. Solomon
pp 4015 - 4027; DOI:
10.1021/ja00299a043
PDF
Enzymatic vs. fermentative synthesis: thermostable glucose dehydrogenase catalyzed regeneration of NAD(P)H for use in enzymatic synthesis
Chihuey Wong, Dale G. Drueckhammer, and Henri M. Sweers
pp 4028 - 4031; DOI:
10.1021/ja00299a044
PDF
Conformational transmission in four- and five-coordinated phosphorus compounds. Solvent effects on the conformation in 5'-phosphorylated model nucleosides
Leo H. Koole, J. L. Van Kooyk, and Henk M. Buck
pp 4032 - 4037; DOI:
10.1021/ja00299a045
PDF
Stereochemistry of the carbon-skeleton rearrangements dependent on coenzyme B12. MNDO quantum chemical calculations
Ingrid I. Merkelbach, Hanneke G. M. Becht, and Henk M. Buck
pp 4037 - 4042; DOI:
10.1021/ja00299a046
PDF
Solid-state photochemistry of guest aliphatic ketones inside the channels of host deoxycholic and apocholic acids
R. Popovitz-Biro, C. P. Tang, H. C. Chang, M. Lahav, and L. Leiserowitz
pp 4043 - 4058; DOI:
10.1021/ja00299a047
PDF
Reaction pathways in crystalline host-guest inclusion complexes: rotation by a net 180.degree. of the acetyl group on photoaddition of guest acetophenone and m-chloroacetophenone to the atom C5 of host deoxycholic acid
C. P. Tang, H. C. Chang, R. Popovitz-Biro, F. Frolow, M. Lahav, L. Leiserowitz, and R. K. McMullan
pp 4058 - 4070; DOI:
10.1021/ja00299a048
PDF
Biomimetic models for cysteine proteases. 2. Nucleophilic thiolate-containing zwitterions produced from imidazole-thiol pairs. A model for the acylation step in papain
K. I. Skorey and R. S. Brown
pp 4070 - 4072; DOI:
10.1021/ja00299a049
PDF
Total synthesis of (.+-.)-reserpine
Stephen F. Martin, Slawomir Grzejszczak, Heinrich Rueeger, and Sidney A. Williamson
pp 4072 - 4074; DOI:
10.1021/ja00299a050
PDF
Resolution, circular dichroism spectrum, molecular structure, and absolute configuration of cis,trans-1,3-cyclooctadiene
Roland Isaksson, Jan Roschester, Jan Sandstroem, and Lars Goeran Wistrand
pp 4074 - 4075; DOI:
10.1021/ja00299a051
PDF
Alkyl group migration in photoinduced cation radical reactions
Paul G. Gassman and Bruce A. Hay
pp 4075 - 4076; DOI:
10.1021/ja00299a052
PDF
Prooxidant effects of glutathione in aerobic hemoglobin solutions. Superoxide generation from uncoordinated dioxygen
Vijaya Sampath and Winslow S. Caughey
pp 4076 - 4078; DOI:
10.1021/ja00299a053
PDF
Time-dependent inhibition of isopentenyl pyrophosphate isomerase by 2-(dimethylamino)ethyl pyrophosphate
John E. Reardon and Robert H. Abeles
pp 4078 - 4079; DOI:
10.1021/ja00299a054
PDF
Molecular mechanics calculations on cis-[Pt(NH3)2{d(GpG)}] adducts in two oligonucleotide duplexes
Jiri Kozelka, Gregory A. Petsko, Stephen J. Lippard, and Gary J. Quigley
pp 4079 - 4081; DOI:
10.1021/ja00299a055
PDF
Cytochrome P-450 catalyzed oxidation of quadricyclane. Evidence for a radical cation intermediate
Ralph A. Stearns and Paul R. Ortiz de Montellano
pp 4081 - 4082; DOI:
10.1021/ja00299a056
PDF
Electron paramagnetic relaxation as a probe for structural characterization of paramagnetic oxyanions
S. R. Maple and N. S. Dalal
pp 4082 - 4083; DOI:
10.1021/ja00299a057
PDF
Insertion of carbon monoxide into a transition metal-silicon bond. X-ray structure of the silaacyl chloro(trimethylsilyl-.eta.2-carbonyl)bis(.eta.5-cyclopentadienyl)zirconium
T. Don Tilley
pp 4084 - 4085; DOI:
10.1021/ja00299a058
PDF
Fluoride ion catalyzed aldehyde addition of labile .alpha.- or .beta.-halo carbanion species generated from the corresponding .alpha.- or .beta.-halo organosilanes
Makoto Fujita and Tamejiro Hiyama
pp 4085 - 4087; DOI:
10.1021/ja00299a059
PDF
Iron-57 nuclear magnetic resonance spectroscopic study of carbonmonoxymyoglobin
Hee Cheon Lee, Janice Koles Gard, Theodore L. Brown, and Eric Oldfield
pp 4087 - 4088; DOI:
10.1021/ja00299a060
PDF
Asymmetric synthesis via chiral sulfinylallyl anion. Total synthesis of (+)-hirsutene: facile ring closure involving enol thioether and enol acetate moieties
Duy H. Hua, Gurudas Sinai-Zingde, and S. Venkataraman
pp 4088 - 4090; DOI:
10.1021/ja00299a061
PDF
Electronic and structural requirements for ring opening of azacyclopentadiene carbenes
Daniel J. Pasto and Jeremiah P. Freeman
pp 4090 - 4091; DOI:
10.1021/ja00299a062
PDF
Stereospecific reaction of 3-methoxy-4-chloro-7-aminoisocoumarin with crystalline porcine pancreatic elastase
Edgar F. Meyer, Leonard G. Presta, and R. Radhakrishnan
pp 4091 - 4093; DOI:
10.1021/ja00299a063
PDF
Mimics of tryptophan synthetase and of biochemical dehydroalanine formation
Wayne Weiner, Jeffrey Winkler, Steven C. Zimmerman, Anthony W. Czarnik, and Ronald Breslow
pp 4093 - 4094; DOI:
10.1021/ja00299a064
PDF
High-dilution synthesis of macrocyclic polycatecholates
Steven J. Rodgers, Chiu Yuen Ng, and Kenneth N. Raymond
pp 4094 - 4095; DOI:
10.1021/ja00299a065
PDF
Synthesis and study of an analog for the [Fe4S4]3+ center of oxidized high potential iron-sulfur proteins
Timothy O'Sullivan and Michelle M. Millar
pp 4096 - 4097; DOI:
10.1021/ja00299a066
PDF
Dimethylsilylene: trisilane and a geminal diazide as new photochemical precursors. Evidence for an absorption maximum near 450 nm
Hrvoj Vancik, Gerhard Raabe, Michael J. Michalczyk, Robert West, and Josef Michl
pp 4097 - 4098; DOI:
10.1021/ja00299a067
PDF
Selective alkali metal and hydrogen reduction of benzene to cyclohexene
Guido P. Pez, Irving L. Mador, James E. Galle, Richard K. Crissey, and Charles E. Forbes
pp 4098 - 4100; DOI:
10.1021/ja00299a068
PDF
o-Hydroperoxynaphthoquinols. Chemical transducers for coupling oxidation with acylation: a vitamin K model
R. Marshall Wilson and Gregg Tharp
pp 4100 - 4101; DOI:
10.1021/ja00299a069
PDF
Lithium-metalloid exchange reactions. Kinetic evidence for an intermediate in the lithium-iodine exchange
Hans J. Reich, Nancy H. Phillips, and Ieva L. Reich
pp 4101 - 4103; DOI:
10.1021/ja00299a070
PDF
Reaction of the cyanomethyl rhenium complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) with n-BuLi/TMEDA; generation, stereospecific alkylation, and basicity of a transition-metal substituted carbanion
Guy L. Crocco and J. A. Gladysz
pp 4103 - 4104; DOI:
10.1021/ja00299a071
PDF
Structure of the alkali-labile product formed during iron(II)-bleomycin-mediated DNA strand scission
Hiroshi Sugiyama, Cheng Xu, Natesan Murugesan, and Sidney M. Hecht
pp 4104 - 4105; DOI:
10.1021/ja00299a072
PDF
Book Reviews

pp 4106 - 4108; DOI:
10.1021/ja00299a600
PDF

Issue 14


The structure of propadienone
Ronald D. Brown, Robert Champion, Patricia S. Elmes, and Peter D. Godfrey
pp 4109 - 4112; DOI:
10.1021/ja00300a001
PDF
The microwave spectrum and structure of tricarbon monoxide
Ronald D. Brown, Peter D. Godfrey, Patricia S. Elmes, Martin Rodler, and Leslie M. Tack
pp 4112 - 4115; DOI:
10.1021/ja00300a002
PDF
On the quencher concentration dependence of fluorescence quenching: the role of solution dielectric constant and ionic strength
R. I. Cukier
pp 4115 - 4117; DOI:
10.1021/ja00300a003
PDF
Electronic energy levels in long polyenes: S2 .fwdarw. S0 emission in all-trans-1,3,5,7,9,11,13-tetradecaheptaene
Richard Snyder, Eric Arvidson, Caroline Foote, Lynne Harrigan, and Ronald L. Christensen
pp 4117 - 4122; DOI:
10.1021/ja00300a004
PDF
Gas-phase ion-molecule reactions of dioxygen anion radical (O2-.bul.)
Richard N. McDonald and A. Kasem Chowdhury
pp 4123 - 4128; DOI:
10.1021/ja00300a005
PDF
Formation of hypervalent ammoniated radicals by neutralized ion beam techniques
Seung Joon Jeon, Asit B. Raksit, Gregory I. Gellene, and Richard F. Porter
pp 4129 - 4133; DOI:
10.1021/ja00300a006
PDF
Hydrophilic spacer groups in polymerizable lipids: formation of biomembrane models from bulk polymerized lipids
R. Elbert, A. Laschewsky, and H. Ringsdorf
pp 4134 - 4141; DOI:
10.1021/ja00300a007
PDF
Stereoelectronic effect in anionic 1,1-addition to isocyanides. An ab initio study of the hydride ion + isocyanic acid system
Michel Sana and Georges Leroy
pp 4141 - 4145; DOI:
10.1021/ja00300a008
PDF
Conformational properties of oxidation-reduction cofactors
Douglas J. Raber and Walter Rodriguez
pp 4146 - 4147; DOI:
10.1021/ja00300a009
PDF
Electron-transfer-induced rearrangements: radical cations of bridged bicyclobutanes
Christopher J. Abelt, Heinz D. Roth, and Marcia L. M. Schilling
pp 4148 - 4152; DOI:
10.1021/ja00300a010
PDF
Molecular orbital effects on the structure of cyclopropane radical cations
Heinz D. Roth, Marcia L. M. Schilling, and Frederic C. Schilling
pp 4152 - 4158; DOI:
10.1021/ja00300a011
PDF
Applications of the reduced isotope shift to general estimation of one-bond isotope shifts in NMR
Cynthia J. Jameson and H. Joerg Osten
pp 4158 - 4161; DOI:
10.1021/ja00300a012
PDF
Additivity of carbon-13 spin-lattice relaxation times
Kenneth L. Williamson, Nicholas V. Reo, and Thomas R. Stengle
pp 4162 - 4167; DOI:
10.1021/ja00300a013
PDF
Sodium cation complexation by large crown ethers: sodium-23 NMR chemical shifts and longitudinal and transverse relaxation rate studies of sodium tetraphenylborate-dibenzo-24-crown-8 complexes in nitromethane
Harald D. H. Stoever, Alfred Delville, and Christian Detellier
pp 4167 - 4171; DOI:
10.1021/ja00300a014
PDF
Exchange kinetics of the sodium cation with dibenzo-24-crown-8 in nitromethane solution: competition between unimolecular decomplexation and bimolecular cation interchange mechanisms
Alfred Delville, Harald D. H. Stoever, and Christian Detellier
pp 4172 - 4175; DOI:
10.1021/ja00300a015
PDF
Aliphatic semidiones. 44. Spin probes derived from dithiols
Glen A. Russell, W. C. Law, and Mary Zaleta
pp 4175 - 4182; DOI:
10.1021/ja00300a016
PDF
Spontaneous resolution and polymorphism of potassium tris(oxalato)cobaltate(III). X-ray crystallographic and thermal studies
Hiroshi Okazaki, Yoshihiko Kushi, and Hayami Yoneda
pp 4183 - 4189; DOI:
10.1021/ja00300a017
PDF
An ESR study of the addition of metal atoms to allene: metal-substituted allyl radicals
J. H. B. Chenier, J. A. Howard, and B. Mile
pp 4190 - 4191; DOI:
10.1021/ja00300a018
PDF
Artificial allosteric system. 2. Cooperative 1-methylimidazole binding to an artificial allosteric system, zinc-gable porphyrin-dipyridylmethane complex
Iwao Tabushi, Shinichi Kugimiya, Michael G. Kinnaird, and Tomikazu Sasaki
pp 4192 - 4199; DOI:
10.1021/ja00300a019
PDF
Synthesis and characterization of phenolate-bridge copper dimers with a copper-copper separation of >3.5 .ANG.. Models for the active site of oxidized hemocyanin derivatives
Thomas N. Sorrell, Charles O'Connor, Oren P. Anderson, and Joseph H. Reibenspies
pp 4199 - 4206; DOI:
10.1021/ja00300a020
PDF
Comparison of the molecular and electronic structures of (2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(II) and (trans-7,8-dihydro-2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(II)
Steven H. Strauss, Michael E. Silver, Kim M. Long, Ronald G. Thompson, Robert A. Hudgens, K. Spartalian, and James A. Ibers
pp 4207 - 4215; DOI:
10.1021/ja00300a021
PDF
Vanadium(V) oxyanions: the esterification of ethanol with vanadate
Michael J. Gresser and Alan S. Tracey
pp 4215 - 4220; DOI:
10.1021/ja00300a022
PDF
Kinetics and mechanism of the permanganate ion oxidation of sulfite in alkaline solutions. The nature of short-lived intermediates
Laszlo I. Simandi, Miklos Jaky, C. R. Savage, and Z. A. Schelly
pp 4220 - 4224; DOI:
10.1021/ja00300a023
PDF
Mechanism of hydrolysis of 2-tert-butyl-2-methoxy-1,3-dithiolane. Rate-determining deprotonation in the breakdown of tetrahedral intermediate
Tadashi Okuyama and Takayuki Fueno
pp 4224 - 4229; DOI:
10.1021/ja00300a024
PDF
Stereochemistry of the lead(IV) acetate fragmentation of 1-(trimethylsiloxy)bicyclo[n.1.0]alkanes
George M. Rubottom, Ellen C. Beedle, Chong Wan Kim, and Robert C. Mott
pp 4230 - 4233; DOI:
10.1021/ja00300a025
PDF
The reality of polar transition states of photobromination of toluenes by N-bromosuccinimide (NBS)
Sung Soo Kim, Seung Yong Choi, and Chul Hyun Kang
pp 4234 - 4237; DOI:
10.1021/ja00300a026
PDF
Chemical and physical properties of 3,6-dimethoxyfluorenylidene: substituent effects making the ground state a singlet carbene
Carl Chuang, Stephen C. Lapin, Alan K. Schrock, and Gary B. Schuster
pp 4238 - 4243; DOI:
10.1021/ja00300a027
PDF
Chemical and physical properties of 9-xanthylidene: a ground-state singlet aromatic carbene
Stephen C. Lapin and Gary B. Schuster
pp 4243 - 4248; DOI:
10.1021/ja00300a028
PDF
"Mediator methodology" for the synthesis of peptides in a two-polymeric system
Yechiel Shai, Kenneth A. Jacobson, and Abraham Patchornik
pp 4249 - 4252; DOI:
10.1021/ja00300a029
PDF
General method of diastereo- and enantioselective synthesis of β-hydroxy-α-amino acids by condensation of aldehydes and ketones with glycine
Yu. N. Belokon, A. G. Bulychev, S. V. Vitt, Yu. T. Struchkov, A. S. Batsanov, T. V. Timofeeva, V. A. Tsyryapkin, M. G. Ryzhov, L. A. Lysova, and et al.
pp 4252 - 4259; DOI:
10.1021/ja00300a030
PDF
Elimination reactions of .alpha.,.beta.-dihydroxysilanes: stereospecific synthesis of silyl enol ethers from vinylsilanes
Paul F. Hudrlik, Anne M. Hudrlik, and Ashok K. Kulkarni
pp 4260 - 4264; DOI:
10.1021/ja00300a031
PDF
Quantum chemical studies of model cytochrome P450 oxidations of amines. 1. MNDO pathways for alkylamine reactions with singlet and triplet oxygen
Amiram Goldblum and Gilda H. Loew
pp 4265 - 4272; DOI:
10.1021/ja00300a032
PDF
Cytochrome P450 mediated aromatic oxidation: a theoretical study
Kenneth Korzekwa, William Trager, Martin Gouterman, Dale Spangler, and Gilda Loew
pp 4273 - 4279; DOI:
10.1021/ja00300a033
PDF
Crystal structure of aspartame, a peptide sweetener
Marcos Hatada, Jarmila Jancarik, Bradford Graves, and Sung Hou Kim
pp 4279 - 4282; DOI:
10.1021/ja00300a034
PDF
In vitro reaction of the carcinogen chromate with cellular thiols and carboxylic acids
P. H. Connett and K. E. Wetterhahn
pp 4282 - 4288; DOI:
10.1021/ja00300a035
PDF
C-Glycosidation of pyridyl thioglycosides
Andrew O. Stewart and Robert M. Williams
pp 4289 - 4296; DOI:
10.1021/ja00300a036
PDF
Sodium ion-proton exchange reactions of the carboxylic acid ionophore monensin
B. G. Cox, P. Firman, and H. Schneider
pp 4297 - 4300; DOI:
10.1021/ja00300a037
PDF
Deuterium isotope effects for the nonenzymic and glutamate dehydrogenase catalyzed reduction of an .alpha.-imino acid by NADH
R. Srinivasan and Harvey F. Fisher
pp 4301 - 4305; DOI:
10.1021/ja00300a038
PDF
Specific cleavage of peptides containing an aspartic acid (.beta.-hydroxamic acid) residue
James K. Blodgett, G. Marc Loudon, and Kim D. Collins
pp 4305 - 4313; DOI:
10.1021/ja00300a039
PDF
Steric course of the reactions catalyzed by 5-enolpyruvylshikimate-3-phosphate synthase, chorismate mutase, and anthranilate synthase
Y. Asano, J. J. Lee, T. L. Shieh, F. Spreafico, C. Kowal, and Heinz G. Floss
pp 4314 - 4320; DOI:
10.1021/ja00300a040
PDF
Complex isomerization of ketoses: a carbon-13 NMR study of the base-catalyzed ring-opening and ring-closing rates of D-fructose isomers in aqueous solution
Warren J. Goux
pp 4320 - 4327; DOI:
10.1021/ja00300a041
PDF
Single transition state for sulfonato group (SO3) transfer between pyridine nucleophiles
Nicholas Bourne, Andrew Hopkins, and Andrew Williams
pp 4327 - 4331; DOI:
10.1021/ja00300a042
PDF
Electron transfer from trialkyltin radicals to nitrosugars: the synthesis of C-glycosides with tertiary anomeric carbon atoms
Jacques Dupuis, Bernd Giese, Jens Hartung, Michael Leising, Hans Gert Korth, and Reiner Sustmann
pp 4332 - 4333; DOI:
10.1021/ja00300a043
PDF
Insertion and oxidative addition reactions of rhodium porphyrin complexes. Novel free radical chain mechanisms
Ralph S. Paonessa, Nicholas C. Thomas, and Jack Halpern
pp 4333 - 4335; DOI:
10.1021/ja00300a044
PDF
On the reported high barrier to nitrogen inversion in azetidine (trimethylenimine)
Frank A. L. Anet
pp 4335 - 4335; DOI:
10.1021/ja00300a045
PDF
A diacridine derivative that binds by bisintercalation at two contiguous sites on DNA
Graham J. Atwell, Georgina M. Stewart, Werner Leupin, and William A. Denny
pp 4335 - 4337; DOI:
10.1021/ja00300a046
PDF
Isolation and x-ray crystal structures of the mononuclear cuprates [CuMe2]-, [CuPh2]-, and [Cu(Br)CH(SiMe3)2]-
Hakon Hope, Marilyn M. Olmstead, Philip P. Power, Janet Sandell, and Xiaojie Xu
pp 4337 - 4338; DOI:
10.1021/ja00300a047
PDF
Photoisomerization of a highly substituted silene
A. G. Brook, K. D. Safa, Paul D. Lickiss, and Kim M. Baines
pp 4338 - 4339; DOI:
10.1021/ja00300a048
PDF
Total synthesis of (.+-.)-retigeranic acid
E. J. Corey, Manoj C. Desai, and Thomas A. Engler
pp 4339 - 4341; DOI:
10.1021/ja00300a049
PDF
Bridgehead intermediates in organic synthesis: two direct syntheses of (.+-.)-lycopodine
George A. Kraus and Yung Son Hon
pp 4341 - 4342; DOI:
10.1021/ja00300a050
PDF
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride (1) as a coupling reagent for N-alkyl amino acids
Roger D. Tung and Daniel H. Rich
pp 4342 - 4343; DOI:
10.1021/ja00300a051
PDF
Mechanism of oxygen atom transfer from high valent iron porphyrins to olefins: implications to the biological epoxidation of olefins by cytochrome P-450
Thomas Kodadek, Scott A. Raybuck, James P. Collman, John I. Brauman, and Lisa M. Papazian
pp 4343 - 4345; DOI:
10.1021/ja00300a052
PDF
Solvent water and the biological group-transfer potential of phosphoric and carboxylic anhydrides
Richard Wolfenden and Richard Williams
pp 4345 - 4346; DOI:
10.1021/ja00300a053
PDF
Asymmetric oxygenation of chiral imide enolates. A general approach to the synthesis of enantiomerically pure .alpha.-hydroxy carboxylic acid synthons
D. A. Evans, M. M. Morrissey, and R. L. Dorow
pp 4346 - 4348; DOI:
10.1021/ja00300a054
PDF
X-ray absorption spectroscopic studies of the copper(II) sites in bovine plasma amine oxidase
Robert A. Scott and David M. Dooley
pp 4348 - 4350; DOI:
10.1021/ja00300a055
PDF
Does carbon-protonated hydrogen cyanide, H2CN+, exist?
Doug J. DeFrees and A. D. McLean
pp 4350 - 4351; DOI:
10.1021/ja00300a056
PDF
Unprecedented carbon-nitrogen bond formation. Crystal and molecular structure of N-(2-aminoethyl)-N-(4-aza-6-aminohexyl)-(.alpha.,.alpha.-diaminomalonato)cobalt(III) perchlorate
Morio Yashiro, Akira Shimada, Takeshi Usui, Shigenobu Yano, Kimiko Kobayashi, Tosio Sakurai, and Sadao Yoshikawa
pp 4351 - 4353; DOI:
10.1021/ja00300a057
PDF
Hexakis(.mu.3-thio)pentakis[(.eta.5-cyclopentadienyl)titanium], [((.eta.5-C5H5)Ti)5(.mu.3-S)6]: preparation and molecular and electronic structure
Frank Bottomley, Gabriel O. Egharevba, and Peter S. White
pp 4353 - 4354; DOI:
10.1021/ja00300a058
PDF
Excited-state chemistry of tetrakis(.mu.-pyrophosphito)diplatinum(II). Photoinduced addition of aryl bromides and iodides to the binuclear complex and the photoinduced catalytic conversion of isopropyl alcohol into acetone and hydrogen
D. Max Roundhill
pp 4354 - 4356; DOI:
10.1021/ja00300a059
PDF
Dynamics of transient ion pairs and radical pairs. Solvent and salt effects by time-resolved spectroscopy
J. M. Masnovi, A. Levine, and J. K. Kochi
pp 4356 - 4358; DOI:
10.1021/ja00300a060
PDF
Inter- and intramolecular oxidative addition of phosphine, methane, alkane, and alkene carbon-hydrogen bonds to rhenium
Robert G. Bergman, Paul F. Seidler, and Timothy T. Wenzel
pp 4358 - 4359; DOI:
10.1021/ja00300a061
PDF
Synthetic and mechanistic studies of the retro-Claisen rearrangement: an example of cation acceleration of a [3,3]-sigmatropic rearrangement
Robert K. Boeckman, Christopher J. Flann, and Kathleen M. Poss
pp 4359 - 4362; DOI:
10.1021/ja00300a062
PDF
Ab initio study of 1,2,4,5-tetramethylenebenzene: a disjoint non-Kekule molecule with a possible singlet ground state
Paul M. Lahti, Angelo Rossi, and Jerome A. Berson
pp 4362 - 4363; DOI:
10.1021/ja00300a063
PDF
Observation of an unusually low carbon monoxide stretching frequency on iron(100)
D. W. Moon, S. L. Bernasek, D. J. Dwyer, and J. L. Gland
pp 4363 - 4364; DOI:
10.1021/ja00300a064
PDF
Book Reviews

pp 4365 - 4372; DOI:
10.1021/ja00300a600
PDF

Issue 15


Reactions of the iron and cobalt carbenes FeCH2+ and CoCH2+ with aliphatic alkanes in the gas phase. Activation of carbon-hydrogen and carbon-carbon bonds by naked transition-metal carbene ions
D. B. Jacobson and Ben S. Freiser
pp 4373 - 4379; DOI:
10.1021/ja00301a001
PDF
Generation and reaction of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies for the vanadium, chromium, iron, cobalt, and molybdenum hydrides VH, CrH, FeH, CoH, and MoH
Larry Sallans, Kelley R. Lane, Robert R. Squires, and Ben S. Freiser
pp 4379 - 4385; DOI:
10.1021/ja00301a002
PDF
Correlation of electron and hydrogen atom binding energies for transition-metal atoms
Robert R. Squires
pp 4385 - 4390; DOI:
10.1021/ja00301a003
PDF
Investigation of Cu2Co2SOD and its anion derivatives. Proton NMR and electronic spectra
I. Bertini, G. Lanini, C. Luchinat, L. Messori, R. Monnanni, and A. Scozzafava
pp 4391 - 4396; DOI:
10.1021/ja00301a004
PDF
Exploratory study of the intermolecular reactivity of excited diphenylmethyl radicals
J. C. Scaiano, M. Tanner, and D. Weir
pp 4396 - 4403; DOI:
10.1021/ja00301a005
PDF
Pulse radiolysis study of the cycloheptatriene triplet state: lifetime, relaxation and nonvertical excitation
A. A. Gorman, I. Hamblett, M. Irvine, P. Raby, M. C. Standen, and S. Yeates
pp 4404 - 4411; DOI:
10.1021/ja00301a006
PDF
Upper excited state(s) in the methylenecyclopropane/trimethylenemethane system. Photolysis of (E)- and (Z)-2,3-diethyl-2-methylmethylenecyclopropane at 185 nm
Thomas Baum, Angelo Rossi, and R. Srinivasan
pp 4411 - 4415; DOI:
10.1021/ja00301a007
PDF
A theoretical study of fluorine atom and fluoride ion attack on methane and silane
Larry P. Davis, Larry W. Burggraf, Mark S. Gordon, and Kim K. Baldridge
pp 4415 - 4419; DOI:
10.1021/ja00301a008
PDF
The structure corresponding to the reference polynomial of [N]annulene in the topological resonance energy theory
Noriyuki Mizoguchi
pp 4419 - 4421; DOI:
10.1021/ja00301a009
PDF
Comparison of semiempirical and ab initio transition states
Stefan Schroeder and Walter Thiel
pp 4422 - 4430; DOI:
10.1021/ja00301a010
PDF
Photoinduced disproportionation of Ru(bpy)32+ on porous Vycor glass
Theresa Kennelly, Harry D. Gafney, and Martin Braun
pp 4431 - 4440; DOI:
10.1021/ja00301a011
PDF
Carbon monoxide activation by biscyclopentadienyl complexes of Group 4 metals and actinides: .eta.2-acyl complexes
Kazuyuki Tatsumi, Akira Nakamura, Peter Hofmann, Peter Stauffert, and Roald Hoffmann
pp 4440 - 4451; DOI:
10.1021/ja00301a012
PDF
Why the energetic minimum aluminum vinylidene is not observed in low-temperature aluminum + acetylene reactions
Andrew C. Scheiner and Henry F. Schaefer
pp 4451 - 4453; DOI:
10.1021/ja00301a013
PDF
Theoretical study on the quadruple metal bond in d4-d4 binuclear tetracarboxylate complexes of chromium, molybdenum, and tungsten by the Hartree-Fock-Slater transition-state method
Tom Ziegler
pp 4453 - 4459; DOI:
10.1021/ja00301a014
PDF
Comparative studies on the electronic structures of tetraformatoditungsten and dimethyltetraformatoditungsten by the relativistic X.alpha.-SW method: a d3-d3 metal dimer with a quadruple metal-metal bond
M. D. Braydich, B. E. Bursten, M. H. Chisholm, and D. L. Clark
pp 4459 - 4465; DOI:
10.1021/ja00301a015
PDF
Kinetics and mechanism of reductive dioxygen activation catalyzed by P-450 model system. Iron picket fence as a catalytic center
Iwao Tabushi, Masahito Kodera, and Masataka Yokoyama
pp 4466 - 4473; DOI:
10.1021/ja00301a016
PDF
Transformation of a tungsten(0) alkyne to a tungsten(II) alkyne via vinylidene, carbyne, and ketenyl ligands
K. R. Birdwhistell, T. L. Tonker, J. L. Templeton, and W. R. Kenan
pp 4474 - 4483; DOI:
10.1021/ja00301a017
PDF
Transformation of the bis(diphenylphosphino)methane ligand on the triruthenium nonacarbonyl framework. Synthesis and characterization of the ruthenium complexes Ru3(CO)9(.mu.3-.eta.3-P(C6H5)CH2P(C6H5)(C6H4)), Ru3(CO)9(.mu.-H)(.mu.3-.eta.2-P(C6H5)CH2P(C6H5)2), and Ru3(CO)10(.mu.-.eta.2-P(C6H5)CH2P(C6H5)(C6H4))
Noel Lugan, Jean Jacques Bonnet, and James A. Ibers
pp 4484 - 4491; DOI:
10.1021/ja00301a018
PDF
Cyclopropeniumyldiazonium systems: first generation of a C-sp-attached diazonium function
Robert Weiss, Klaus Georg Wagner, Claus Priesner, and Juergen Macheleid
pp 4491 - 4499; DOI:
10.1021/ja00301a019
PDF
Oxidation-reduction reactions of N-sulfonoxyacetanilides: mechanisms of the halide-induced reduction of models for the carcinogenic metabolites of aromatic amides
Maria Pelecanou and Michael Novak
pp 4499 - 4503; DOI:
10.1021/ja00301a020
PDF
The question of reversible formation of bromonium ions during the course of electrophilic bromination of olefins. 2. The crystal and molecular structure of the bromonium ion of adamantylideneadamantane
H. Slebocka-Tilk, R. G. Ball, and R. Stan Brown
pp 4504 - 4508; DOI:
10.1021/ja00301a021
PDF
Oligomerization of vinyl monomers. 17. Stereoselective methylation of 1-lithio-1,3-bis(phenylsulfinyl)butane. Kinetic vs. thermodynamic control in the formation of diastereomeric ion pairs
Mark A. Buese and Thieo E. Hogen-Esch
pp 4509 - 4513; DOI:
10.1021/ja00301a022
PDF
Solvolysis of 1-arylethyl tosylates. Kinetic and stereochemical tests for solvent participation
Annette D. Allen, V. M. Kanagasabapathy, and Thomas T. Tidwell
pp 4513 - 4519; DOI:
10.1021/ja00301a023
PDF
Electronic structure and bonding of the blue copper site in plastocyanin
Kevin W. Penfield, Andrew A. Gewirth, and Edward I. Solomon
pp 4519 - 4529; DOI:
10.1021/ja00301a024
PDF
Carboxypeptidase A-catalyzed hydrolysis of .alpha.-(acylamino)cinnamoyl derivatives of L-.beta.-phenyllactate and L-phenylalaninate: evidence for acyl-enzyme intermediates
Junghun Suh, Wonhwa Cho, and Shin Chung
pp 4530 - 4535; DOI:
10.1021/ja00301a025
PDF
Studies of silicon-phosphorus bonding
Kenneth J. Dykema, Thanh N. Truong, and Mark S. Gordon
pp 4535 - 4541; DOI:
10.1021/ja00301a026
PDF
Marine alkaloids. 10. Chartelline A: a pentahalogenated alkaloid from the marine bryozoan Chartella papyracea
Lionel Chevolot, Anne Marie Chevolot, Michael Gajhede, Charles Larsen, Uffe Anthoni, and Carsten Christophersen
pp 4542 - 4543; DOI:
10.1021/ja00301a027
PDF
Cyclization and disproportionation kinetics of triplet generated, medium chain length, localized biradicals measured by time-resolved CIDNP
Gerhard L. Closs and O. David Redwine
pp 4543 - 4544; DOI:
10.1021/ja00301a028
PDF
Direct intermolecular transfer of dihydrogen between two transition metal complexes
William D. Jones and John A. Maguire
pp 4544 - 4546; DOI:
10.1021/ja00301a029
PDF
Structural investigations by solid-state carbon-13 NMR. Dependence of |1J(119Sn,13C)| on the methyl-tin-methyl angle in methyltin(IV)s
Thomas P. Lockhart, William F. Manders, and J. J. Zuckerman
pp 4546 - 4547; DOI:
10.1021/ja00301a030
PDF
Formation of interstitial palladium-carbon phase by interaction of ethylene, acetylene, and carbon monoxide with palladium
S. B. Ziemecki, G. A. Jones, D. G. Swartzfager, R. L. Harlow, and J. Faber
pp 4547 - 4548; DOI:
10.1021/ja00301a031
PDF
Organoboron compounds in organic synthesis. 1. Asymmetric hydroboration
Satoru Masamune, Byeong Moon Kim, John S. Petersen, Tsuneo Sato, Siem J. Veenstra, and Toshiro Imai
pp 4549 - 4551; DOI:
10.1021/ja00301a032
PDF
Direct nucleophilic 1,4-acylation of .alpha.,.beta.-unsaturated ketones and aldehydes via acylcuprate reagents
Dietmar Seyferth and Richard C. Hui
pp 4551 - 4553; DOI:
10.1021/ja00301a033
PDF
Norborna-2,5-dien-7-one: a covalent benzene-carbon monoxide adduct. A new point on the cycloreversion structure-reactivity correlation curve
David M. Birney and Jerome A. Berson
pp 4553 - 4554; DOI:
10.1021/ja00301a034
PDF
Photochemical generation and direct observation of 7-norbornadienone
Brian F. LeBlanc and Robert S. Sheridan
pp 4554 - 4556; DOI:
10.1021/ja00301a035
PDF
One-electron reduction of anthraquinone by hydroxide ion in aprotic media
Julian L. Roberts, Hiroshi Sugimoto, William C. Barrette, and Donald T. Sawyer
pp 4556 - 4557; DOI:
10.1021/ja00301a036
PDF
Preparation of an unsubstituted hydrazido(1-) complex and an authentic high oxidation state ditungsten dinitrogen complex
Robert C. Murray and Richard R. Schrock
pp 4557 - 4558; DOI:
10.1021/ja00301a037
PDF
Bimetallic-mediated reaction of carbon monoxide and dioxygen
Mitsuru Kubota, Frank S. Rosenberg, and Michael J. Sailor
pp 4558 - 4559; DOI:
10.1021/ja00301a038
PDF
Specific side-chain cleavage of tryptophan, tryptophanyl derivatives, and tryptophanyl dipeptides using hypervalent iodine
Robert M. Moriarty and Mumtaz Sultana
pp 4559 - 4561; DOI:
10.1021/ja00301a039
PDF
Dinuclear, 18-electron species having a triplet ground state: isolation, characterization, and crystal structure of photogenerated (.eta.5-C5Me5)2Fe2(.mu.-CO)3
Josephine Paw Blaha, Bruce E. Bursten, John C. Dewan, Richard B. Frankel, Claudia Lewis Randolph, Beth A. Wilson, and Mark S. Wrighton
pp 4561 - 4562; DOI:
10.1021/ja00301a040
PDF
Reactions of cyclic cation radicals with nucleophiles: a new route to distonic ions
Thomas M. Sack, Ronald L. Cerny, and Michael L. Gross
pp 4562 - 4564; DOI:
10.1021/ja00301a041
PDF
Proton-transfer spectroscopy of bis[2,5-(2-benzoxazolyl)]hydroquinone in supersonic jets: effect of van der Waals complexation with noble gas atoms
N. P. Ernsting
pp 4564 - 4565; DOI:
10.1021/ja00301a042
PDF
Crystal and molecular structure of tris(dimethylamino)sulfonium trifluoromethoxide. Evidence for negative fluorine hyperconjugation
W. B. Farnham, B. E. Smart, W. J. Middleton, J. C. Calabrese, and D. A. Dixon
pp 4565 - 4567; DOI:
10.1021/ja00301a043
PDF
Changes in the electronic structure of Ni/TiOx composites as a function of reduction temperature
Hans Conrad Zur Loye and Angelica M. Stacy
pp 4567 - 4568; DOI:
10.1021/ja00301a044
PDF
Synthesis, structure, and magnetic properties of an asymmetric .mu.3-oxotriiron(III) complex: a new type of {Fe3O}7+ core
Sergiu M. Gorun and Stephen J. Lippard
pp 4568 - 4570; DOI:
10.1021/ja00301a045
PDF
Cleavage of ruthenium and osmium porphyrin dimers: formation of organometallic ruthenium porphyrin complexes and highly reduced metalloporphyrin species
James P. Collman, P. J. Brothers, L. McElwee-White, E. Rose, and L. J. Wright
pp 4570 - 4571; DOI:
10.1021/ja00301a046
PDF
Zirconium cluster compounds stabilized by interstitial atoms
Robin P. Ziebarth and John D. Corbett
pp 4571 - 4573; DOI:
10.1021/ja00301a047
PDF
Methylaluminum bis(2,6-di-tert-butyl-4-alkylphenoxide). A new reagent for obtaining unusual equatorial and anti-Cram selectivity in carbonyl alkylation
Keiji Maruoka, Takayuki Itoh, and Hisashi Yamamoto
pp 4573 - 4576; DOI:
10.1021/ja00301a048
PDF
Cyano complexes of trivalent nickel in aqueous solution
Thomas L. Pappenhagen and Dale W. Margerum
pp 4576 - 4577; DOI:
10.1021/ja00301a049
PDF
Stereospecific synthesis of the bicyclo[2.2.2] portion of granaticin; synthesis of sarubicin A
M. F. Semmelhack, Yohini Appapillai, and Tadahisa Sato
pp 4577 - 4579; DOI:
10.1021/ja00301a050
PDF
Carbanion-accelerated vinylcyclopropane rearrangement. Application in a general, stereocontrolled annulation approach to cyclopentene derivatives
Rick L. Danheiser, Joanne J. Bronson, and Kazuo Okano
pp 4579 - 4581; DOI:
10.1021/ja00301a051
PDF
Insertion of iridium into the carbon-hydrogen bonds of alkenes: the .pi.-complex cannot be an intermediate
Page O. Stoutland and Robert G. Bergman
pp 4581 - 4582; DOI:
10.1021/ja00301a052
PDF
Formation of novel, dimeric epidioxides from the Lewis acid catalyzed oxygenation of 1-tert-butylcyclohexa-1,3-diene
Munawar F. Arain, Richard K. Hayenes, Simone C. Vonwiller, and Trevor W. Hambley
pp 4582 - 4584; DOI:
10.1021/ja00301a053
PDF
Surface conversion of benzene to acetylene
W. L. Parker, R. M. Hexter, and A. R. Siedle
pp 4584 - 4585; DOI:
10.1021/ja00301a054
PDF
Kinetic molecular design of uranophile. Linear tris(dithiocarbamate) as a strong and rapid extracting reagent for uranyl ion from dilute carbonate solution
Iwao Tabushi, Atsushi Yoshizawa, and Hodaka Mizuno
pp 4585 - 4586; DOI:
10.1021/ja00301a055
PDF
Unusual substituent effect on a palladium-mediated cyclization: a total synthesis of (.+-.)-sterepolide
Barry M. Trost and John Y. L. Chung
pp 4586 - 4588; DOI:
10.1021/ja00301a056
PDF
Stereochemistry of the carbon to carbon bond formation in the biosynthesis of polyprepenyl chains with Z double bonds. Studies with undecaprenyl-pyrophosphate synthetase
Masaki Kobayashi, Michio Ito, Tanetoshi Koyama, and Kyozo Ogura
pp 4588 - 4589; DOI:
10.1021/ja00301a057
PDF
Asymmetric induction in diarylcarbene cyclopropanations
Laren M. Tolbert and Mahfuza B. Ali
pp 4589 - 4590; DOI:
10.1021/ja00301a058
PDF
Large tunneling effects in the migration of chemisorbed hydrogen on a metal
Jack G. Lauderdale and Donald G. Truhlar
pp 4590 - 4591; DOI:
10.1021/ja00301a059
PDF
Facile oxidation of methoxide to formaldehyde by a heterocyclic quinone
Edward B. Skibo and Chang Hee Lee
pp 4591 - 4593; DOI:
10.1021/ja00301a060
PDF
6-Hydroxyanthranilic acid, a new shikimate pathway product found in the biosynthesis of sarubicin A
Larry R. Hillis and Steven J. Gould
pp 4593 - 4594; DOI:
10.1021/ja00301a061
PDF
Absolute rate constants for reaction of phenyl, 2,2-dimethylvinyl, cyclopropyl, and neopentyl radicals with tri-n-butylstannane. Comparison of the radical trapping abilities of tri-n-butylstannane and -germane
L. J. Johnston, J. Lusztyk, D. D. M. Wayner, A. N. Abeywickreyma, A. L. J. Beckwith, J. C. Scaiano, and Keith U. Ingold
pp 4594 - 4596; DOI:
10.1021/ja00301a062
PDF
Nature of the cadmium sites in rat liver metallothionein 1 from cadmium K-edge EXAFS
Ian L. Abrahams, C. David Garner, Ian Bremner, Gregory P. Diakun, and S. Samar Hasnain
pp 4596 - 4597; DOI:
10.1021/ja00301a063
PDF
Ligand-induced reactions of a directly bonded early-late transition metal complex involving reversible cleavage of a zirconium-ruthenium bond with expulsion of a ruthenium hydride
Charles P. Casey, Robert E. Palermo, Richard F. Jordan, and Arnold L. Rheingold
pp 4597 - 4599; DOI:
10.1021/ja00301a064
PDF
Coordination of a "noncoordinating" anion: x-ray crystal structure and phosphorus-31 NMR characterization of a tungsten nitrosyl cation ligated to hexafluoroantimonate(1-) ion
William H. Hersh
pp 4599 - 4601; DOI:
10.1021/ja00301a065
PDF
Additions and Corrections - Mechanism of the Reaction of Gas-Phase Iron Ions with Neutral Olefins
D. A. Peake, M. L. Gross, and D. P. Ridge
pp 4601 - 4601; DOI:
10.1021/ja00301a601
PDF
Additions and Corrections - Nucleophilic Reactions in Solutions of Nonmicellized Hydrophobic Ammonium Ions
Girma Biresaw, Clifford A. Bunton, Clifford Quan, and Zhong-Yun Yang
pp 4601 - 4601; DOI:
10.1021/ja00301a602
PDF
Additions and Corrections - Gas Phase 1H NMR Spectra and Nitrogen Inversion of Trimethylene Imine
B. Ri. Friedman, J. Paul Chauvel, Jr., and Nancy S. True
pp 4601 - 4601; DOI:
10.1021/ja00301a603
PDF
Book Reviews

pp 4602 - 4606; DOI:
10.1021/ja00301a600
PDF

Issue 16


Dynamics of radical pair reactions in micelles
I. R. Gould, M. B. Zimmt, Nicholas J. Turro, B. H. Baretz, and G. F. Lehr
pp 4607 - 4612; DOI:
10.1021/ja00302a001
PDF
Reaction of diphenylcarbene with amines and the question of triplet-singlet equilibration
A. S. Nazran and David Griller
pp 4613 - 4615; DOI:
10.1021/ja00302a002
PDF
Fluorenone oxide: transient spectroscopy and kinetics of its formation and reactions
H. L. Casal, M. Tanner, N. H. Werstiuk, and J. C. Scaiano
pp 4616 - 4620; DOI:
10.1021/ja00302a003
PDF
Theoretical studies on gas-phase reactions of fluoride ion with fluoroethane: E2 and SN2 reactions
Tsutomu Minato and Shinichi Yamabe
pp 4621 - 4626; DOI:
10.1021/ja00302a004
PDF
Electron affinities from electron-transfer equilibria: A- + B = A + B-
Eric P. Grimsrud, Gary Caldwell, Swapan Chowdhury, and Paul Kebarle
pp 4627 - 4634; DOI:
10.1021/ja00302a005
PDF
Electrohydrodynamic mass spectrometric studies of some polyether-cation complexes
Victor F. Man, J. Dale Lin, and Kelsey D. Cook
pp 4635 - 4640; DOI:
10.1021/ja00302a006
PDF
Rotation of methyl groups in hexamethylbenzene
V. Melissas, K. Faegri, and J. Almloef
pp 4640 - 4642; DOI:
10.1021/ja00302a007
PDF
Role of magnesium(2+) ion in modifying the environment of radiolytically produced silver atoms in A zeolites: electron spin resonance and electron spin echo modulation spectroscopy studies
M. Narayana and Larry Kevan
pp 4643 - 4647; DOI:
10.1021/ja00302a008
PDF
Electrochemistry, spectroelectrochemistry, and photochemistry of a series of new covalently linked tris(2,2-bipyridine)ruthenium(II)/diquat complexes
C. Michael Elliott, Ruth A. Freitag, and David D. Blaney
pp 4647 - 4655; DOI:
10.1021/ja00302a009
PDF
Fluorescence study of pyrene and naphthalene in cyclodextrin-amphiphile complex systems
S. Hashimoto and J. K. Thomas
pp 4655 - 4662; DOI:
10.1021/ja00302a010
PDF
Mechanistic insight into the reaction of phenyl isocyanate with ditungsten hexa-tert-butoxide: isolation and characterization of early intermediates
F. Albert Cotton and Edwar S. Shamshoum
pp 4662 - 4667; DOI:
10.1021/ja00302a011
PDF
Unusual configuration and low iron-uptake ability of isomugineic acid produced from chlorotic gramineous plants
Yukio Sugiura, Yoshiki Mino, Takashi Iwashita, and Kyosuke Nomoto
pp 4667 - 4669; DOI:
10.1021/ja00302a012
PDF
Synthesis and reactivity of cyclopentadienylhafnium phosphido complexes. Hydrogenolysis and carbon monoxide insertion for Hf-PR2 bonds
Dean M. Roddick, Bernard D. Santarsiero, and John E. Bercaw
pp 4670 - 4678; DOI:
10.1021/ja00302a013
PDF
Control of chemo- and stereoselectivity in the reactions of organocuprates with .alpha.-oxoketene dithioacetals
R. Karl Dieter, Louis A. Silks, Jeffrey A. Fishpaugh, and M. E. Kastner
pp 4679 - 4692; DOI:
10.1021/ja00302a014
PDF
Carbon-oxygen bond cleavage reactions by electron transfer. 2. Electrochemical formation and dimerization reaction pathways of cyanodiphenyl ether radical anions
Miles D. Koppang, Neil F. Woolsey, and Duane E. Bartak
pp 4692 - 4700; DOI:
10.1021/ja00302a015
PDF
The chemistry of free and complexed phosphirenes: reactivity toward electrophiles, nucleophiles, and conjugated dienes
Angela Marinetti and Francois Mathey
pp 4700 - 4706; DOI:
10.1021/ja00302a016
PDF
Proximity as a component of organic reactivity
F. M. Menger and U. V. Venkataram
pp 4706 - 4709; DOI:
10.1021/ja00302a017
PDF
Reaction mechanism from structure-energy relations. 1. Base-catalyzed addition of alcohols to formaldehyde
Ernest Grunwald
pp 4710 - 4715; DOI:
10.1021/ja00302a018
PDF
Reaction mechanism from structure-energy relations. 2. Acid-catalyzed addition of alcohols to formaldehyde
Ernest Grunwald
pp 4715 - 4720; DOI:
10.1021/ja00302a019
PDF
The free radical reaction between alkanes and carbon tetrachloride
J. A. Hawari, S. Davis, P. S. Engel, B. C. Gilbert, and David Griller
pp 4721 - 4724; DOI:
10.1021/ja00302a020
PDF
Effect of bending on the reactivity of alkynes: a semiempirical study
Wilhelm F. Maier, Gene C. Lau, and Alan B. McEwen
pp 4724 - 4731; DOI:
10.1021/ja00302a021
PDF
Ionization of N-arylsulfonyloxy amines: the nitrenium ion question
Robert V. Hoffman, Anil Kumar, and Gregory A. Buntain
pp 4731 - 4736; DOI:
10.1021/ja00302a022
PDF
Base-catalyzed isomerization of 3-butenenitrile. Relative nucleophilicities of carbanions, nitranions, oxanions, and thianions toward hydrogen
Frederick G. Bordwell and David L. Hughes
pp 4737 - 4744; DOI:
10.1021/ja00302a023
PDF
The .beta.' lithiation of .alpha.,.beta.-unsaturated amides
Peter Beak, Dale J. Kempf, and Kenneth D. Wilson
pp 4745 - 4756; DOI:
10.1021/ja00302a024
PDF
Synthesis, characterization, and properties of hexadecyl silica: a novel hydrophobic matrix for protein immobilization
Mohsen Nemat-Gorgani, Khashayar Karimian, and Farajolah Mohanazadeh
pp 4756 - 4759; DOI:
10.1021/ja00302a025
PDF
Stereochemical fate of chiral methyl of valine in the ring expansion of penicillin N to deacetoxycephalosporin C
Craig A. Townsend, Alan B. Theis, A. Scott Neese, Ellen B. Barrabee, and Douglas Poland
pp 4760 - 4767; DOI:
10.1021/ja00302a026
PDF
Antileprosy dihydrophenazines. Structural characterization of two crystal forms of clofazimine and of isoclofazimine, B.3857
Urszula Rychlewska, M. Beth Humphrey Broom, Drake S. Eggleston, and Derek J. Hodgson
pp 4768 - 4772; DOI:
10.1021/ja00302a027
PDF
Solvent isotope effects on formation of protease complexes with inhibitory aldehydes
Roger Bone and Richard Wolfenden
pp 4772 - 4777; DOI:
10.1021/ja00302a028
PDF
Valence delocalization in mixed-valence 1,6'-diiodobi ferrocenium triiodide
Teng Yuan Dong, Michelle J. Cohn, David N. Hendrickson, and Cortlandt G. Pierpont
pp 4777 - 4778; DOI:
10.1021/ja00302a029
PDF
Metal carbonyl fragments as a new class of markers in molecular biology
Gerard Jaouen, Anne Vessieres, Siden Top, Ashraf A. Ismail, and Ian S. Butler
pp 4778 - 4780; DOI:
10.1021/ja00302a030
PDF
Bromate oscillators: elucidation of the source of bromide ion and modification of the chemical mechanism
Margit Varga, Laszlo Gyorgyi, and Endre Koros
pp 4780 - 4781; DOI:
10.1021/ja00302a031
PDF
Synthesis of the first .alpha.-diazophosphines. Phosphorous-carbon multiple-bond character of phosphinocarbenes
Antoine Baceiredo, Guy Bertrand, and Ghislaine Sicard
pp 4781 - 4783; DOI:
10.1021/ja00302a032
PDF
New chromia pillared clay catalysts
Thomas J. Pinnavaia, Ming Shin Tzou, and Steven D. Landau
pp 4783 - 4785; DOI:
10.1021/ja00302a033
PDF
Dynamic NMR study of phenyl thiolformate. Non-aromaticity of the Z conformation
Eric A. Noe, Thomas Sanders, Masood Garahi, Hasan Hosseini, and Rose Young
pp 4785 - 4786; DOI:
10.1021/ja00302a034
PDF
General approach for the synthesis of polyquinenes. 2. Synthesis of tetracyclo[5.5.1.04,13.010,13]tridecane-2,5,8,11-tetraene
M. N. Deshpande, M. Jawdosiuk, G. Kubiak, M. Venkatachalam, U. Weiss, and James M. Cook
pp 4786 - 4788; DOI:
10.1021/ja00302a035
PDF
syn-Sesquinorbornatriene and its quadricyclane valence isomer
Leo A. Paquette, Hermann Kuenzer, and Kenneth E. Green
pp 4788 - 4790; DOI:
10.1021/ja00302a036
PDF
Arene synthesis by extrusion reaction. Part 8. Synthesis of 1,2:7,8-dibenzo[2.2]paracyclophane and 1,2-benzo-7,8-naphtho[2.2]paracyclophane
Chin Wing Chan and Henry N. C. Wong
pp 4790 - 4791; DOI:
10.1021/ja00302a037
PDF
Transition state conformations of a Lewis acid catalyzed Diels-Alder reaction. The low temperature cycloaddition of 1-(1-oxoallyl)-2-(3-isopropenyl-4-methyl-3-pentenyl) benzene
K. J. Shea and J. W. Gilman
pp 4791 - 4792; DOI:
10.1021/ja00302a038
PDF
Concurrent catalytic reduction/stoichiometric oxidation using oligomerically ligated catalysts and polymer-bound reagents
David E. Bergbreiter and Rama Chandran
pp 4792 - 4793; DOI:
10.1021/ja00302a039
PDF
On the structure of the allyl anion
Paul v. R. Schleyer
pp 4793 - 4794; DOI:
10.1021/ja00302a040
PDF
A novel disproportionation reaction that occurs at a multiply bonded dimetal center. The isolation of dirhenium(IV,II) alkoxide complexes of the type (RO)2Cl2ReReCl2(PPh3)2 (R = Me, Et, or n-Pr)
Akhil R. Chakravarty, F. Albert Cotton, Ann R. Cutler, Stephen M. Tetrick, and Richard A. Walton
pp 4795 - 4796; DOI:
10.1021/ja00302a041
PDF
Norhalichondrin A: an antitumor polyether macrolide from a marine sponge
Daisuke Uemura, Kanji Takahashi, Toshihiro Yamamoto, Chuji Katayama, Jiro Tanaka, Yasuaki Okumura, and Yoshimasa Hirata
pp 4796 - 4798; DOI:
10.1021/ja00302a042
PDF
Simple phosphorus-31 NMR method for the determination of enantiomeric purity of alcohols not requiring any chiral auxiliary compounds
Ben L. Feringa, Ab Smaardijk, and Hans Wynberg
pp 4798 - 4799; DOI:
10.1021/ja00302a043
PDF
Excited-state nitrosyl bending and metal oxidation in K2[Fe(CN)5NO] determined by excited-state Raman spectroscopy
Y. Y. Yang and Jeffrey I. Zink
pp 4799 - 4800; DOI:
10.1021/ja00302a044
PDF
Chemical transformations in the quassinoid series: novel copper(II) mediated ring contraction of .delta.-lactones to .gamma.-lactones. A synthetic entry into the samanderins
Junji Inanaga, Shigeki Sasaki, Paul A. Grieco, and Hongbum Kim
pp 4800 - 4802; DOI:
10.1021/ja00302a045
PDF
A spherand azophenol dye: lithium ion specific coloration with "perfect" selectivity
Takahiro Kaneda, Shinichi Umeda, Hisako Tanigawa, Soichi Misumi, Yasushi Kai, Hisashi Morii, Kunio Miki, and Nobutami Kasai
pp 4802 - 4803; DOI:
10.1021/ja00302a046
PDF
Additions and Corrections - Transition-State Modeling in Acyclic Stereoselection. A Molecular Mechanics Model for the Kinetic Formation of Lithium Enolates
David W. Moreland, and William G. Dauben
pp 4804 - 4804; DOI:
10.1021/ja00302a600
PDF
Book Reviews

pp 4805 - 4808; DOI:
10.1021/ja00302a601
PDF

Issue 17


High-resolution carbon-13 NMR of retinal derivatives in the solid state
G. S. Harbison, P. P. J. Mulder, H. Pardoen, J. Lugtenburg, J. Herzfeld, and R. G. Griffin
pp 4809 - 4816; DOI:
10.1021/ja00303a001
PDF
Nuclear spin-spin coupling via nonbonded interactions. 5. Nitrogen-fluorine coupling
Frank B. Mallory and Clelia W. Mallory
pp 4816 - 4819; DOI:
10.1021/ja00303a002
PDF
Transient absorption and two step laser-excitation fluorescence studies on the proton transfer in the ground and excited states of 3-hydroxyxanthone in alcohols
Michiya Itoh, Yoshinori Yoshida, and Masanobu Takashima
pp 4819 - 4824; DOI:
10.1021/ja00303a003
PDF
Free cyclohexyl cations from the decay of tritiated cyclohexane
Marina Attina, Fulvio Cacace, Romano Cipollini, and Maurizio Speranza
pp 4824 - 4828; DOI:
10.1021/ja00303a004
PDF
Optical activity of monoolefins: RPA calculations and extraction of the mechanisms in Kirkwood's theory. Application to (-)-trans-cyclooctene and 3(3R)-3-methylcyclopentene
Aage E. Hansen and Thomas D. Bouman
pp 4828 - 4839; DOI:
10.1021/ja00303a005
PDF
Stable hydrogen-bonded isomers of covalent ions. Association of carbonium ions with n-donors
Michael Mautner, Mark M. Ross, and Joseph E. Campana
pp 4839 - 4845; DOI:
10.1021/ja00303a006
PDF
Electrochemically induced SRN1 aromatic nucleophilic substitution. Absolute reactivities of phenyl derivatives in liquid ammonia
Christian Amatore, Catherine Combellas, Jean Pinson, Mehmet A. Oturan, Sabine Robvieille, Jean Michel Saveant, and Andre Thiebault
pp 4846 - 4853; DOI:
10.1021/ja00303a007
PDF
Mixed-ligand poly(pyridine) complexes of ruthenium(II). Resonance Raman spectroscopic evidence for selective population of ligand-localized 3MLCT excited states
Stephen F. McClanahan, Richard F. Dallinger, F. James Holler, and James R. Kincaid
pp 4853 - 4860; DOI:
10.1021/ja00303a008
PDF
Infrared intensities: cyclohexane. A molecular force field and dipole moment derivatives
Kenneth B. Wiberg, Valerie A. Walters, and William P. Dailey
pp 4860 - 4867; DOI:
10.1021/ja00303a009
PDF
An ab initio study of the insertion reaction silylene (SiH2(1Aa)) + hydrogen .fwdarw. silane
Alexander Sax and Gottfried Olbrich
pp 4868 - 4874; DOI:
10.1021/ja00303a010
PDF
Spontaneous and induced homolysis of bis(triphenylphosphine)octacarbonyldimanganese(Mn-Mn)
Anthony Poe and Chandra V. Sekhar
pp 4874 - 4883; DOI:
10.1021/ja00303a011
PDF
Fundamental study of the oxidation of butane over vanadyl pyrophosphate
Marc A. Pepera, James L. Callahan, Michael J. Desmond, Ernest C. Milberger, Patricia R. Blum, and Noel J. Bremer
pp 4883 - 4892; DOI:
10.1021/ja00303a012
PDF
Conformations of cyclic octapeptides. 2. Crystal structure of cyclo(D-Ala-Gly-Pro-D-Phe)2. Solvent exposure of backbone protons in crystal and solution conformations
Kenneth D. Kopple, Gopinath Kartha, Krishna K. Bhandary, and Krystyna Romanowska
pp 4893 - 4897; DOI:
10.1021/ja00303a013
PDF
CPMAS (cross-polarization magic angle spinning) carbon-13 NMR spectra of quinones, hydroquinones, and their complexes. Use of CMR to follow a reaction in the solid state
J. Scheffer, Y. F. Wong, A. O. Patil, D. Y. Curtin, and I. C. Paul
pp 4898 - 4904; DOI:
10.1021/ja00303a014
PDF
Spectral, electrochemical and base-binding studies of heterodinuclear ruthenium-cobalt complexes of meso-.alpha.,.alpha.,.alpha.,.alpha.-tetra(nicotinamidophenyl)porphine
C. Michael Elliott, J. Kenneth Arnette, and R. R. Krebs
pp 4904 - 4911; DOI:
10.1021/ja00303a015
PDF
The characterization of a new heteropolytungstoarsonate anion, [CH3AsW7O27H]7-. Topological relationships among ions related to the Lindqvist structure
Geoffrey B. Jameson, Michael T. Pope, and Sadiq H. Wasfi
pp 4911 - 4915; DOI:
10.1021/ja00303a016
PDF
Phosphorus-31 and proton NMR spectroscopic studies of platinum adducts of poly(I).poly(C). The antitumor agent cis-dichlorodiammineplatinum forms an N7,N7 bis-adduct
Michael D. Reily and Luigi G. Marzilli
pp 4916 - 4924; DOI:
10.1021/ja00303a017
PDF
Synthesis, structural characterization, and electronic properties of the tetraphenylphosphonium salts of the mixed terminal ligand cubanes Fe4S4(Et2Dtc)n(X)4-n2- (X = Cl-, PhS-) (n = 1, 2). Two different modes of ligation on the [Fe4S4]2+ core
M. G. Kanatzidis, D. Coucouvanis, A. Simopoulos, A. Kostikas, and V. Papaefthymiou
pp 4925 - 4935; DOI:
10.1021/ja00303a018
PDF
Three-dimensional orthogonal protection scheme for solid-phase peptide synthesis under mild conditions
George Barany and Fernando Albericio
pp 4936 - 4942; DOI:
10.1021/ja00303a019
PDF
Disilathiiranes: synthesis and crystal structure
Robert West, Douglas J. De Young, and Kenneth J. Haller
pp 4942 - 4946; DOI:
10.1021/ja00303a020
PDF
The meso substitution of chlorophyll derivatives: direct route for transformation of bacteriopheophorbides d into bacteriopheophorbides c.
Kevin M. Smith, Dane A. Goff, and Daniel J. Simpson
pp 4946 - 4954; DOI:
10.1021/ja00303a021
PDF
Synthesis of nickel(II) isobacteriochlorins from nickel(II) complexes of chlorophyll derivatives
Kevin M. Smith and Dane A. Goff
pp 4954 - 4964; DOI:
10.1021/ja00303a022
PDF
Spring-loaded biradicals. The radical and electron-transfer photochemistry of bridgehead cyclopropyl-substituted 2,3-diazabicyclo[2.2.2]oct-2-enes (DBO's)
Paul S. Engel, Dalen E. Keys, and Akihide Kitamura
pp 4964 - 4975; DOI:
10.1021/ja00303a023
PDF
Onium ylide chemistry. 4. Alkylhalonium methylides
George A. Olah, Hans Doggweiler, and Jeff D. Felberg
pp 4975 - 4978; DOI:
10.1021/ja00303a024
PDF
Long bonds in cation radicals of vicinally difunctional molecules
Dennis J. Bellvile, Raul A. Pabon, and Nathan L. Bauld
pp 4978 - 4979; DOI:
10.1021/ja00303a025
PDF
Chiral synthesis via organoboranes. 3. Conversion of boronic esters of essentially 100% optical purity to aldehydes, acids, and homologated alcohols of very high enantiomeric purities
Herbert C. Brown, Toshiro Imai, Manoj C. Desai, and Bakthan Singaram
pp 4980 - 4983; DOI:
10.1021/ja00303a026
PDF
Synthesis of the antileukemic agent (.+-.)-steganone using a stereoconvergent biaryl coupling reaction
Philip Magnus, James Schultz, and Timothy Gallagher
pp 4984 - 4988; DOI:
10.1021/ja00303a027
PDF
Binding strength and specificity in DNA interactions: the design of A.cntdot.T specific intercalators
W. David Wilson, Yueh Hwa Wang, S. Kusuma, S. Chandrasekaran, N. C. Yang, and David W. Boykin
pp 4989 - 4995; DOI:
10.1021/ja00303a028
PDF
Formation of anthracenes in the flash vacuum pyrolysis of benzocyclobutenes and dimers of o-quinodimethanes
Walter S. Trahanovsky and Bruce W. Surber
pp 4995 - 4997; DOI:
10.1021/ja00303a029
PDF
High lithium selectivity in competitive alkali metal solvent extraction by lipophilic crown carboxylic acids
Richard A. Bartsch, Bronislaw P. Czech, San Ihn Kang, Louis E. Stewart, Wladyslaw Walkowiak, Witold A. Charewicz, Gwi Suk Heo, and Byungki Son
pp 4997 - 4998; DOI:
10.1021/ja00303a030
PDF
A new pyridine synthesis
T. Ross Kelly and Hshiouting Liu
pp 4998 - 4999; DOI:
10.1021/ja00303a031
PDF
Synthesis of sec-alkylacetylenes. Reduction of cobalt carbonyl complexes of acetylenic alcohols
Kenneth M. Nicholas and Jay Siegel
pp 4999 - 5001; DOI:
10.1021/ja00303a032
PDF
Carbonylation of a strained phosphorus-carbon bond. Conversion of phosphirene into 2-keto-1,2-dihydrophosphete complexes: an entry into the chemistry of the phosphorus analogs of unsaturated .beta.-lactams
Angela Marinetti, Jean Fischer, and Francois Mathey
pp 5001 - 5002; DOI:
10.1021/ja00303a033
PDF
Long-distance electron transfer in pentaammineruthenium (histidine-48)-myoglobin. Reorganizational energetics of a high-spin heme
Robert J. Crutchley, Walther R. Ellis, and Harry B. Gray
pp 5002 - 5004; DOI:
10.1021/ja00303a034
PDF
Protonation of molybdenum(II) and tungsten(II) bis(alkyne) complexes: formation of .eta.4-C4R4H ligands
J. R. Morrow, T. L. Tonker, J. L. Templeton, and W. R. Kenan
pp 5004 - 5005; DOI:
10.1021/ja00303a035
PDF
Synthesis and characterization of a new iron/molybdenum/sulfur cluster containing the [Fe6Mo2S6]3+ core. A precursor to a possible structural analog for the iron/molybdenum site of nitrogenase
D. Coucouvanis and M. G. Kanatzidis
pp 5005 - 5006; DOI:
10.1021/ja00303a036
PDF
Topographical mimicry of the enzyme binding domain of cytochrome c
Kimberly K. Clark-Ferris and Jed Fisher
pp 5007 - 5008; DOI:
10.1021/ja00303a037
PDF
Total synthesis of (.+-.)-4-amino-4-deoxychorismic acid: a key intermediate in the biosynthesis of p-aminobenzoic acid and L-p-aminophenylalanine
Chia Yu P. Teng, Bruce Ganem, Stella Z. Doktor, Brian P. Nichols, Raj K. Bhatnagar, and Leo C. Vining
pp 5008 - 5009; DOI:
10.1021/ja00303a038
PDF
Multiply bonded octachlorodiosmate(III) anion [Os2Cl8]2-. The first example of a homoleptic halide complex of this type for the platinum metals
Phillip E. Fanwick, M. Kathleen King, Stephen M. Tetrick, and Richard A. Walton
pp 5009 - 5011; DOI:
10.1021/ja00303a039
PDF
An example of cyclometalation by oxidative addition: a platinum(IV)-tetramethylthiourea complex containing a carbon-metal .sigma. bond. Crystal structure
Paule Castan, Joel Jaud, Neil P. Johnson, and Regis Soules
pp 5011 - 5012; DOI:
10.1021/ja00303a040
PDF
One- and two-electron reduction of a chromium(0) alkyne complex and isolation of the chromium(1-) product
Donald J. Wink, James R. Fox, and N. John Cooper
pp 5012 - 5014; DOI:
10.1021/ja00303a041
PDF
A remarkably simple preparation of (trifluoromethyl)cadmium and -zinc reagents directly from difluorodihalomethanes
Donald J. Burton and Denise M. Wiemers
pp 5014 - 5015; DOI:
10.1021/ja00303a042
PDF
Stable carbocations. 264. Observation of secondary carbon-13 equilibrium isotope effect in the degenerate rearrangement of 2,3-dimethyl-2-butyl cation using natural abundance carbon-13 NMR spectroscopy
V. V. Krishnamurthy, G. K. Surya Prakash, Pradeep S. Iyer, and George A. Olah
pp 5015 - 5016; DOI:
10.1021/ja00303a043
PDF
Pentadienyl compounds of zirconium, niobium, and molybdenum: "U" vs "S" .eta.5-2,4-dimethylpentadienyl coordination
Lothar Stahl, John P. Hutchinson, David R. Wilson, and Richard D. Ernst
pp 5016 - 5018; DOI:
10.1021/ja00303a044
PDF
Control of heme protein redox potential and reduction rate: linear free energy relation between potential and ferric spin state equilibrium
Mark T. Fisher and Stephen G. Sligar
pp 5018 - 5019; DOI:
10.1021/ja00303a045
PDF
2-(9,10-Dimethoxyanthracenyl)-tert-butylnitroxide. An ESR spectroscopic indicator for singlet oxygen
John F. W. Keana, Vaikunth S. Prabhu, Shigeru Ohmiya, and Charles E. Klopfenstein
pp 5020 - 5021; DOI:
10.1021/ja00303a046
PDF
Direct observation of benzoyloxyl radicals in photodecomposition of dibenzoyl peroxides with a time-resolved ESR technique
Seigo Yamauchi, Noboru Hirota, Shigeru Takahara, Hirochika Sakuragi, and Katsumi Tokumaru
pp 5021 - 5022; DOI:
10.1021/ja00303a047
PDF
Mechanism-based inhibitors of dopamine .beta.-hydroxylase containing acetylenic or cyclopropyl groups
Paul F. Fitzpatrick and Joseph J. Villafranca
pp 5022 - 5023; DOI:
10.1021/ja00303a048
PDF
EXAFS and WAXS structure determination for an antiarthritic drug, sodium gold(I) thiomalate
R. C. Elder, K. Ludwig, J. N. Cooper, and M. K. Eidsness
pp 5024 - 5025; DOI:
10.1021/ja00303a049
PDF
Additions and Corrections - Molecular Mechanical Studies of Inclusion of Alkali Cations into Anisole Spherands
Peter A. Kollman, Georges Wipff, and U. Chandra Singh
pp 5025 - 5025; DOI:
10.1021/ja00303a601
PDF
Additions and Corrections - Stereoselective Synthesis and Biological Activity of β -and α-D-Arabinose 1,5-Diphosphate: Analogues of a Potent Metabolic Regulator
Bruce E. Maryanoff, Allen B. Reitz, Gene F. Tutwiler, Stephen J. Benkovic, Patricia A. Benkovic, and Simon J. Pilkis
pp 5025 - 5025; DOI:
10.1021/ja00303a602
PDF
Additions and Corrections - Optimized Intermolecular Potential Functions for Amides and Peptides. Hydration of Amides.
William L. Jorgensen, and Carol J. Swenson
pp 5025 - 5025; DOI:
10.1021/ja00303a603
PDF
Book Reviews

pp 5026 - 5026; DOI:
10.1021/ja00303a600
PDF

Issue 18


2s + 2s Reactions at transition metals. Part 3. Dichlorotitanacyclopropane. The structure and reactivity of a metallacyclopropane
Michael L. Steigerwald and William A. Goddard
pp 5027 - 5035; DOI:
10.1021/ja00304a001
PDF
Barriers to rotation adjacent to double bonds
Kenneth B. Wiberg and Eric Martin
pp 5035 - 5041; DOI:
10.1021/ja00304a002
PDF
MNDO calculations of ions in chloroaluminate molten salts
Larry P. Davis, Chester J. Dymek, James J. P. Stewart, Henry P. Clark, and Walter J. Lauderdale
pp 5041 - 5046; DOI:
10.1021/ja00304a003
PDF
An ab initio molecular orbital study on rearrangement/fragmentation processes of isomeric CH3N+.bul. ions
Einar Uggerud and Helmut Schwarz
pp 5046 - 5048; DOI:
10.1021/ja00304a004
PDF
Experimental and ab initio molecular orbital studies on collisions of methane radical ion(1+) (CH4+.cntdot.) and monoprotonated methane (CH5+) with molecular oxygen: on the formation of methane (CH42+) and methonium (CH52+) dications and stable CHn- species (n = 0-3)
Daniel Stahl, Francis Maquin, Tino Gaumann, Helmut Schwarz, Pierre Alain Carrupt, and Pierre Vogel
pp 5049 - 5053; DOI:
10.1021/ja00304a005
PDF
Some aspects of the triplet di-.pi.-methane rearrangement: comparison of the ring opening of cyclopropyldicarbinyl and cyclopropylcarbinyl
Kris Quenemoen, Weston Thatcher Borden, Ernest R. Davidson, and David Feller
pp 5054 - 5059; DOI:
10.1021/ja00304a006
PDF
Ab initio heats of formation of medium-sized hydrocarbons. 3. The valence isomers of benzene
Jerome M. Schulman and Raymond L. Disch
pp 5059 - 5061; DOI:
10.1021/ja00304a007
PDF
Oxidative dimerization of methane over a lithium-promoted magnesium oxide catalyst
Tomoyasu Ito, Jixiang Wang, Chiu Hsun Lin, and Jack H. Lunsford
pp 5062 - 5068; DOI:
10.1021/ja00304a008
PDF
Infrared photochemistry of tetramethyldioxetane. 2. The nature of electronically excited products
Y. Haas, S. Ruhman, G. D. Greenblatt, and O. Anner
pp 5068 - 5074; DOI:
10.1021/ja00304a009
PDF
Multiphoton infrared laser activation of organometallic species: a novel probe of the potential energy surfaces for reactions of cobalt ions with C5H10 isomers
Maureen A. Hanratty, Carlotta M. Paulsen, and J. L. Beauchamp
pp 5074 - 5080; DOI:
10.1021/ja00304a010
PDF
Contribution from microwave absorption to the abnormally large differences between the radio-frequency and visible-frequency polarizations of several metal trisacetylacetonates
E. N. DiCarlo, E. P. Zurbach, and C. V. Gallacher
pp 5081 - 5085; DOI:
10.1021/ja00304a011
PDF
Gas-phase organometallic chemistry: chain-length effects
A. Tsarbopoulos and J. Allison
pp 5085 - 5093; DOI:
10.1021/ja00304a012
PDF
Surface photochemistry: cadmium sulfide-mediated dimerization of phenyl vinyl ether. The dark reaction
Mohammad Ilyas and Paul De Mayo
pp 5093 - 5099; DOI:
10.1021/ja00304a013
PDF
Stereochemical study of 1,2,3,4,5,6-(hexamethoxycarbonyl)cyclohexanes
Mario Farina, Maria Grassi, and Giuseppe Di Silvestro
pp 5100 - 5104; DOI:
10.1021/ja00304a014
PDF
Long range photoinduced electron transfer in a rigid polymer
Tom Guarr, Mark E. McGuire, and George McLendon
pp 5104 - 5111; DOI:
10.1021/ja00304a015
PDF
A lipophilic salt of a transition-metal polyhydride: KOsH3(PMe2Ph)3
John C. Huffman, Mark A. Green, Susan L. Kaiser, and Kenneth G. Caulton
pp 5111 - 5115; DOI:
10.1021/ja00304a016
PDF
1,3-Ditungstacyclobutadienes. 1. Reactions with alkynes. Alkyne adducts and 1,3-dimetallaallyl derivatives
Malcolm H. Chisholm, John C. Huffman, and Joseph A. Heppert
pp 5116 - 5136; DOI:
10.1021/ja00304a017
PDF
Ternary complexes of solution. 48. Influence of organic solvents on intramolecular aromatic-ring stacks in aqueous mixed-ligand metal ion complexes. Opposing solvent effects
Helmut Sigel, Raman Malini-Balakrishnan, and Ulrich K. Haering
pp 5137 - 5148; DOI:
10.1021/ja00304a018
PDF
Catalytic photochemical dehydrogenation of organic substrates by polyoxometalates
Craig L. Hill and Donald A. Bouchard
pp 5148 - 5157; DOI:
10.1021/ja00304a019
PDF
Reactions of coordinated dinitrogen. 16. New mono-dinitrogen complexes of molybdenum that produce ammonia and hydrazine
T. Adrian George and Robert C. Tisdale
pp 5157 - 5159; DOI:
10.1021/ja00304a020
PDF
Artificial allosteric systems. 3. Cooperative carbon monoxide binding to diiron(II)-gable porphyrin-diimidazolylmethane complexes
Iwao Tabushi, Shinichi Kugimiya, and Tomikazu Sasaki
pp 5159 - 5163; DOI:
10.1021/ja00304a021
PDF
pH dependence of the lifetime of a Norrish II biradical
Richard A. Caldwell, S. N. Dhawan, and D. E. Moore
pp 5163 - 5166; DOI:
10.1021/ja00304a022
PDF
Conformation, bonding, and flexibility in short-chain linear phosphazenes
Harry R. Allcock, Norris M. Tollefson, Robert A. Arcus, and Robert R. Whittle
pp 5166 - 5177; DOI:
10.1021/ja00304a023
PDF
The unusual reactions of singlet oxygen with isomeric 1,4-di-tert-butoxy-1,3-butadienes. A 2S + 2a cycloaddition
Edward L. Clennan and Robert P. L'Esperance
pp 5178 - 5182; DOI:
10.1021/ja00304a024
PDF
Kinetics and mechanism of the acid hydrolysis of mitomycins
Robert A. McClelland and Kenneth Lam
pp 5182 - 5186; DOI:
10.1021/ja00304a025
PDF
Ultrasound-promoted selective perfluoroalkylation on the desired position of organic molecules
Tomoya Kitazume and Nobuo Ishikawa
pp 5186 - 5191; DOI:
10.1021/ja00304a026
PDF
A theoretical evaluation of the mechanism of acetylene formation in the reactions of atomic carbon with hydrocarbons
Michael L. McKee and Philip B. Shevlin
pp 5191 - 5198; DOI:
10.1021/ja00304a027
PDF
Oxyphosphorane hydrolysis. Reversible ring opening of spirophosphoranes containing six-atom rings
Glenn H. McGall and Robert A. McClelland
pp 5198 - 5203; DOI:
10.1021/ja00304a028
PDF
Kinetics and mechanism of the hydrolysis of acyclic oxyphosphonium salts
Robert A. McClelland, Glenn H. McGall, and Geeta Patel
pp 5204 - 5209; DOI:
10.1021/ja00304a029
PDF
Diethoxytriphenylphosphorane: a mild, regioselective cyclodehydrating reagent for conversion of diols to cyclic ethers: stereochemistry, synthetic utility, and scope
Philip L. Robinson, Carey N. Barry, Jeffery W. Kelly, and Slayton A. Evans
pp 5210 - 5219; DOI:
10.1021/ja00304a030
PDF
Total synthesis of (.+-.)-tirandamycin A
Philip DeShong, Subban Ramesh, Varadaraj Elango, and Joseph J. Perez
pp 5219 - 5224; DOI:
10.1021/ja00304a031
PDF
Organic synthesis using haloboration reaction. Part 7. A stereospecific synthesis of (Z)-.delta.-halo-.gamma.,.delta.-unsaturated ketones via haloboration reaction of terminal alkynes
Yoshitaka Satoh, Hirokazu Serizawa, Shoji Hara, and Akira Suzuki
pp 5225 - 5228; DOI:
10.1021/ja00304a032
PDF
A logic-based program for synthesis design
James B. Hendrickson, David L. Grier, and A. Glenn Toczko
pp 5228 - 5238; DOI:
10.1021/ja00304a033
PDF
Vinyl cations. 42. Synthesis and solvolysis of substituted 1-cyclobutenyl nonaflates
Michael Hanack and Gerhard Auchter
pp 5238 - 5245; DOI:
10.1021/ja00304a034
PDF
Ground term splitting of high-spin cobalt(2+) ion as a probe of coordination structure. 1. Dependence of the splitting on coordination geometry
Marvin W. Makinen, Lawrence C. Kuo, Moon B. Yim, Gregg B. Wells, James M. Fukuyama, and Judy E. Kim
pp 5245 - 5255; DOI:
10.1021/ja00304a035
PDF
Ground term splitting of high-spin cobalt(2+) ion as a probe of coordination structure. 2. The ligand environment of the active site metal ion of carboxypeptidase A in ester hydrolysis
Lawrence C. Kuo and Marvin W. Makinen
pp 5255 - 5261; DOI:
10.1021/ja00304a036
PDF
Analysis of the interaction of haloenol lactone suicide substrates with .alpha.-chymotrypsin using computer graphics and molecular mechanics
Shunji Naruto, Ioan Motoc, Garland R. Marshall, Scott B. Daniels, Michael J. Sofia, and John A. Katzenellenbogen
pp 5262 - 5270; DOI:
10.1021/ja00304a037
PDF
Supermonomolecular structure in the Langmuir-Blodgett films of a surface-active dye-fatty acid mixed system
Yasujiro Kawabata, Tatsuo Sekiguchi, Motoo Tanaka, Takayoshi Nakamura, Hideo Komizu, Koichi Honda, Eiichiro Manda, Mitsuyoshi Saito, Michio Sugi, and Sigeru Iizima
pp 5270 - 5271; DOI:
10.1021/ja00304a038
PDF
Duality of mechanism, radical and nonradical, in the dehalogenation of aryl halides by lithium 2,6-dimethylpiperidide
Jerzy Winiarski and Joseph F. Bunnett
pp 5271 - 5272; DOI:
10.1021/ja00304a039
PDF
Metal ion complexation by rhodium and iridium metallomacrocycles. The preparation and x-ray crystal structures of Rh2(CO)2Cl2(.mu.-Ph2PCH2As(Ph)CH2PPh2)2 and [Rh2Pd(CO)2Cl3(.mu.-Ph2PCH2As(Ph)CH2PPh2)2][BPh4]
Alan L. Balch, L. Alan Fossett, Marilyn M. Olmstead, Douglas E. Oram, and Philip E. Reedy
pp 5272 - 5274; DOI:
10.1021/ja00304a040
PDF
Sensitized photooxygenation. 1. Reaction of singlet oxygen with 3,4-dihydro-6-methyl-2H-pyran-5-carboxylic acid ethyl ester. Isolation of hydroperoxides and evidence of their transformation to dioxetane
Yukyee Chan, Chen Zhu, and Hiukwong Leung
pp 5274 - 5275; DOI:
10.1021/ja00304a041
PDF
Model copolymerization reactions. Direct observation of a "penultimate effect" in a model styrene-acrylonitrile copolymerization
Sharon A. Jones, Glenn S. Prementine, and David A. Tirrell
pp 5275 - 5276; DOI:
10.1021/ja00304a042
PDF
Flash vacuum pyrolysis of organomanganese pentacarbonyl compounds
Hsing Yeh Parker, C. E. Klopfenstein, R. A. Wielesek, and T. Koenig
pp 5276 - 5277; DOI:
10.1021/ja00304a043
PDF
Farnesylpyrophosphate synthetase. A case for common electrophilic mechanisms for prenyltransferases and terpene cyclases
V. Jo Davisson, Timothy R. Neal, and C. Dale Poulter
pp 5277 - 5279; DOI:
10.1021/ja00304a044
PDF
Photoinduced reactions. 163. Trimethylsilyl cyanide as a trapping agent for dipolar peroxide intermediates
Isao Saito, Hideki Nakagawa, Yueh Hsiung Kuo, Keiichi Obata, and Teruo Matsuura
pp 5279 - 5280; DOI:
10.1021/ja00304a045
PDF
Organometallic "electron reservoirs". 23. 36-40 Electron complexes (C6R6FeCp-CpFeC6R6).+-.n (R = H, Me; n = 0-2) and the first delocalized mixed valence complexes containing iron(I)
Marie Helene Desbois, Didier Astruc, Jacques Guillin, Jean Pierre Mariot, and Francois Varret
pp 5280 - 5282; DOI:
10.1021/ja00304a046
PDF
Onium ions. 32. Intermediacy of the parent diazonium ion (protonated dinitrogen, N2+H) in the diazotization of ammonia and its derivatives with nitrosonium tetrafluoroborate (15NO+BF4-) giving 15N14N+
George A. Olah, Rainer Herges, Jeff D. Felberg, and G. K. Surya Prakash
pp 5282 - 5283; DOI:
10.1021/ja00304a047
PDF
Total synthesis of the cytochrome P-450 epoxygenase metabolites 5(R),6(S)-, 5(S),6(R)-, and 14(R),15(S)-epoxyeicosatrienoic acid (EET) and hydration products 5(R),6(R)- and 14(R),15(R)-dihydroxyeicosatrienoic acid (DHET)
Christine A. Moustakis, Jacques Viala, Jorge Capdevila, and J. R. Falck
pp 5283 - 5285; DOI:
10.1021/ja00304a048
PDF
Stabilization of the phenyl cation by hyperconjugation
Yitzhak Apeloig and Dorit Arad
pp 5285 - 5286; DOI:
10.1021/ja00304a049
PDF
A first example of generating aryl cations in the solvolysis of aryl triflates in trifluoroethanol
Yoshio Himeshima, Hiroshi Kobayashi, and Takaaki Sonoda
pp 5286 - 5288; DOI:
10.1021/ja00304a050
PDF
Toward a master equation for predicting heterolysis energies of carbon-carbon bonds in solution
Edward M. Arnett, B. Chawla, Kent Molter, Kalyani Amarnath, and Marguerite Healy
pp 5288 - 5289; DOI:
10.1021/ja00304a051
PDF
Intramolecular carbon-hydrogen insertion: synthesis of (.+-.)-pentalenolactone E methyl ester
Douglass F. Taber and Jonathan L. Schuchardt
pp 5289 - 5290; DOI:
10.1021/ja00304a052
PDF
Dynamic intermolecular tautomerism of 3,5-dimethylpyrazole in the solid state by carbon-13 CP/MAS NMR spectroscopy and x-ray crystallography
Andre Baldy, Jose Elguero, Robert Faure, Marcel Pierrot, and Emile Jean Vincent
pp 5290 - 5291; DOI:
10.1021/ja00304a053
PDF
Total synthesis of (+)-11,11'-di-O-methylelaiophylidene, an aglycon of elaiophylin
Dieter Seebach, Hak Fun Chow, Richard Jackson, Kevin Lawson, Marius Sutter, Suvit Thaisrivongs, and Juerg Zimmermann
pp 5292 - 5293; DOI:
10.1021/ja00304a054
PDF
Design of molecular assembly of diphenylcarbenes having ferromagnetic intermolecular interactions
Tadashi Sugawara, Shigeru Murata, Keisaku Kimura, Hiizu Iwamura, Yoko Sugawara, and Hitoshi Iwasaki
pp 5293 - 5294; DOI:
10.1021/ja00304a055
PDF
Detection of the static 1,2-dimethyl-2-norbornyl cation by variable temperature carbon-13 CPMAS NMR
Philip C. Myhre, Kevin L. McLaren, and Costantino S. Yannoni
pp 5294 - 5296; DOI:
10.1021/ja00304a056
PDF
Condensation of aldehydes with .mu.-alkylidyne diiron complexes: a new synthesis of .mu.-vinylcarbyne complexes
Charles P. Casey, Mark S. Konings, Robert E. Palermo, and Robert E. Colborn
pp 5296 - 5297; DOI:
10.1021/ja00304a057
PDF
Moessbauer effect study of triiron dodecacarbonyl and the reduced carbide clusters (PPN)[Fe3(CO)10CH], (PPN)2[Fe3(CO)9CCO], and (PPN)[Fe2Co(CO)9CCO]
Christopher G. Benson, Gary J. Long, J. W. Kolis, and D. F. Shriver
pp 5297 - 5298; DOI:
10.1021/ja00304a058
PDF
Isolation and structure of tunichrome B-1, a reducing blood pigment from the tunicate Ascidia nigra (Linnaeus)
Reimar C. Bruening, Eugene M. Oltz, Jun Furukawa, Koji Nakanishi, and Kenneth Kustin
pp 5298 - 5300; DOI:
10.1021/ja00304a059
PDF
Electrochemical permeability control through a redox bilayer film
Yoshio Okahata, Genichro Enna, Kazuhiro Taguchi, and Takahiro Seki
pp 5300 - 5301; DOI:
10.1021/ja00304a060
PDF
Phosphine oxides and lithium aluminum hydride-sodium borohydride-cerium(III) chloride: synthesis and reactions of phosphine-boranes
Tsuneo Imamoto, Tetsuo Kusumoto, Nobuyo Suzuki, and Kazuhiko Sato
pp 5301 - 5303; DOI:
10.1021/ja00304a061
PDF
Diastereotopic selectivity at prochiral carbon centers: functionalization of differentiated hydroxymethyl groups provides access to either stereoisomeric configuration
Stuart L. Schreiber and Zhaoyin Wang
pp 5303 - 5305; DOI:
10.1021/ja00304a062
PDF
A novel synthesis of metacyclophanes. Thermal and DDQ induced aromatization of bridgehead dienes
K. J. Shea, L. D. Burke, and Robert J. Doedens
pp 5305 - 5306; DOI:
10.1021/ja00304a063
PDF
The uncatalyzed Claisen rearrangement of chorismate to prephenate prefers a transition state of chair-like geometry
Shelley D. Copley and Jeremy R. Knowles
pp 5306 - 5308; DOI:
10.1021/ja00304a064
PDF
Construction of linear-fused tricyclopentanoids by intramolecular [6 + 2] cycloadditions of fulvenes with enamines
Tse Chong Wu and K. N. Houk
pp 5308 - 5309; DOI:
10.1021/ja00304a065
PDF
Ozonolysis of olefins adsorbed on polyethylene: a new access to ozonides by cycloadditions of carbonyl oxides to ketones
Karl Griesbaum, Willi Volpp, and Reinhard Greinert
pp 5309 - 5310; DOI:
10.1021/ja00304a066
PDF
Oxidative fragmentation of .beta.-stannyl oximes: stereospecific formation of unsaturated nitrile oxides
Hisao Nishiyama, Hiroyuki Arai, Takashi Ohki, and Kenji Itoh
pp 5310 - 5312; DOI:
10.1021/ja00304a067
PDF
Symmetry-assisted synthesis of triepoxide stereoisomers of E,Z,E,-dodeca-2,6,10-trien-1,12-diol and their cascade reactions to 2,5-linked bistetrahydrofurans
Thomas R. Hoye and Joseph C. Suhadolnik
pp 5312 - 5313; DOI:
10.1021/ja00304a068
PDF
Synthesis of 1,1-dilithio-2,2,3,3-tetramethylcyclopropane
Hajimu Kawa, Bobby C. Manley, and Richard J. Lagow
pp 5313 - 5314; DOI:
10.1021/ja00304a069
PDF
Synthesis, insertion and reductive elimination reactions of a hydrido(alkoxy)iridium complex
Linda J. Newman and Robert G. Bergman
pp 5314 - 5315; DOI:
10.1021/ja00304a070
PDF
Diastereoselection and the influence of chiraphos on metal-centered chirality in cis oxidative addition of hydrogen and triphenylsilane
Amanda J. Kunin, Ramy Farid, Curtis E. Johnson, and Richard Eisenberg
pp 5315 - 5317; DOI:
10.1021/ja00304a071
PDF
Stepwise metal-assisted conversion of carbon diselenide to diselenium and carbon dioxide. Novel bonding mode of the diselenium molecule in the double-Se2-bridged complex [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.2DMF
Claudio Bianchini, Carlo Mealli, Andrea Meli, and Michal Sabat
pp 5317 - 5318; DOI:
10.1021/ja00304a072
PDF
Additions and Corrections - A Method for the Analysis of Puckering Disorder in Five-Membered Rings: The Relative Mobilities of Furanose and Proline Rings and Their Effects on Polynucleotide and Polypeptide Backbone Flexibility
E. Westhof, and M. Sundaralingam
pp 5319 - 5319; DOI:
10.1021/ja00304a600
PDF
Additions and Corrections - Nonlinear Fluorescence Quenching and the Origin of Positive Curvature in Stern-Volmer Plots
Joel Keizer
pp 5319 - 5319; DOI:
10.1021/ja00304a601
PDF
Additions and Corrections - Cluster Synthesis. 6. The Unusual Structures, Bonding, and Reactivity of Some Sulfido-Bridged Tungsten-Osmium Carbonyl Cluster Compounds
Richard D. Adams, Istvan T. Horvath, and Pradeep Mathur
pp 5319 - 5319; DOI:
10.1021/ja00304a602
PDF
Additions and Corrections - Determination of Adsorption Conformation from Surface Resolution Analysis
D. Farin, A. Volpert, and D. Avnir
pp 5319 - 5319; DOI:
10.1021/ja00304a603
PDF
Book Reviews

pp 5320 - 5322; DOI:
10.1021/ja00304a604
PDF

Issue 19


A systematic approach to calculate molecular properties of organosulfur compounds containing the carbon-sulfur (Csp2-S) bond
James Kao, Charles Eyermann, Everett Southwick, and Diane Leister
pp 5323 - 5332; DOI:
10.1021/ja00305a001
PDF
Ab initio studies of the C3H4 surface I. SCF and CI study of structures and stabilities of isomers
N. Honjou, J. Pacansky, and M. Yoshimine
pp 5332 - 5341; DOI:
10.1021/ja00305a002
PDF
Kinetics of polyatomic free radicals produced by laser photolysis. 5. Study of the equilibrium methyl + oxygen .dblarw. CH3O2 between 421 and 538.degree.
Irene R. Slagle and David Gutman
pp 5342 - 5347; DOI:
10.1021/ja00305a003
PDF
Complexation of tert-butylammonium perchlorate by crown ethers in polar solvents studied by proton NMR spectroscopy
J. A. A. De Boer and D. N. Reinhoudt
pp 5347 - 5351; DOI:
10.1021/ja00305a004
PDF
Experimental and theoretical studies of the gas-phase protonation of aliphatic phosphine oxides and phosphoramides
J. C. Bollinger, R. Houriet, C. W. Kern, D. Perret, J. Weber, and T. Yvernault
pp 5352 - 5358; DOI:
10.1021/ja00305a005
PDF
Gas-phase reactions of free vinyl cation with benzene and free phenylium ion with ethylene. A comparative FT-ICR and nuclear decay study
Simonetta Fornarini and Maurizio Speranza
pp 5358 - 5363; DOI:
10.1021/ja00305a006
PDF
Electrochemical characterization of the iron-molybdenum cofactor from Azotobacter vinelandii nitrogenase
Franklin A. Schultz, Stephen F. Gheller, Barbara K. Burgess, Samuel Lough, and William E. Newton
pp 5364 - 5368; DOI:
10.1021/ja00305a007
PDF
Anion affinities of transition-metal carbonyls. A thermochemical correlation for iron tetracarbonyl acyl negative ions
Kelley R. Lane, Larry Sallans, and Robert R. Squires
pp 5369 - 5375; DOI:
10.1021/ja00305a008
PDF
End-to-end cyclization of hydrocarbon chains: temperature effects on an intramolecular phosphorescence quenching reaction in solution
Andrew Mar and Mitchell A. Winnik
pp 5376 - 5382; DOI:
10.1021/ja00305a009
PDF
A proton NMR study of reduced paramagnetic tris(2,2'-bipyridine) complexes of iron(II), ruthenium(II) and osmium(II)
Yasuhiko Ohsawa, M. Keith DeArmond, Kenneth W. Hanck, and Charles G. Moreland
pp 5383 - 5386; DOI:
10.1021/ja00305a010
PDF
Resistivity mechanisms in phthalocyanine-based linear-chain and polymeric conductors: variation of bandwidth with geometry
William J. Pietro, Tobin J. Marks, and Mark A. Ratner
pp 5387 - 5391; DOI:
10.1021/ja00305a011
PDF
Stereospecific formation of enolates from reaction of unsymmetrical ketenes and organolithium reagents
Lynn M. Baigrie, Hani R. Seiklay, and Thomas T. Tidwell
pp 5391 - 5396; DOI:
10.1021/ja00305a012
PDF
Regio- and diastereoselective preparation of aldols from .alpha.-branched ketone enolates generated from BHT ester enolates and organolithium reagents. In situ generation and trapping of ketenes from ester enolates
Robert Haener, Thomas Laube, and Dieter Seebach
pp 5396 - 5403; DOI:
10.1021/ja00305a013
PDF
Structures of three lithium ester enolates by x-ray diffraction: derivation of reaction path for cleavage into ketene and alcoholate
Dieter Seebach, Rene Amstutz, Thomas Laube, W. Bernd Schweizer, and J. D. Dunitz
pp 5403 - 5409; DOI:
10.1021/ja00305a014
PDF
m-Quinodimethane, parent hydrocarbon of the m-quinonoid non-Kekule series. Low-temperature isolation and solution-phase chemical reactivity
Joshua L. Goodman and Jerome A. Berson
pp 5409 - 5424; DOI:
10.1021/ja00305a015
PDF
Stereochemistry and mechanism of m-cyclophane formation in the 1,4-additions of dienes to the m-quinodimethane biradical. On the question of formal 1,2-addition via sequential 1,4-addition and rearrangement
Joshua L. Goodman and Jerome A. Berson
pp 5424 - 5428; DOI:
10.1021/ja00305a016
PDF
Kinetic isotope effect study of the borderline solvolysis of isopropyl .beta.-naphthalenesulfonate
Hiroshi Yamataka, Shinichi Tamura, Terukiyo Hanafusa, and Takashi Ando
pp 5429 - 5434; DOI:
10.1021/ja00305a017
PDF
Study of aromatic functional group conformations in solution by nuclear Overhauser enhancement and relaxation techniques: detection of .pi.-electron density and correlation with chemical reactivity
Lawrence I. Kruse, Charles W. DeBrosse, and Carolyn H. Kruse
pp 5435 - 5442; DOI:
10.1021/ja00305a018
PDF
Stereomutation in the Seyferth reaction
Joseph B. Lambert, Eric G. Larson, Richard J. Bosch, and Mollie L. E. TeVrucht
pp 5443 - 5447; DOI:
10.1021/ja00305a019
PDF
Regioselective oxidation of phenols catalyzed by polyphenol oxidase in chloroform
Rafi Z. Kazandjian and Alexander M. Klibanov
pp 5448 - 5450; DOI:
10.1021/ja00305a020
PDF
Stable simple enols. 10. 500-MHz proton NMR of trimesitylethenol and deuterated analogs: complete signal assignments and direct determination of equilibrium steric isotope effects from the NMR integrals of the isotopomeric enols
Silvio E. Biali, Zvi Rappoport, and William E. Hull
pp 5450 - 5459; DOI:
10.1021/ja00305a021
PDF
Hemiacetal formation with a phenol nucleophile: simple proton transfers as rate-limiting steps
Robert A. McClelland, David B. Devine, and Poul E. Soerensen
pp 5459 - 5463; DOI:
10.1021/ja00305a022
PDF
Kinetic study of the photochlorination of 2,3-dimethylbutane and other alkanes in solution in the presence of benzene. First measurements of the absolute rate constants for hydrogen abstraction by the "free" chlorine atom and the chlorine atom-benzene .pi.-complex. Identification of these two species as the only hydrogen abstractors in these systems
Nigel J. Bunce, Keith U. Ingold, James P. Landers, J. Lusztyk, and J. C. Scaiano
pp 5464 - 5472; DOI:
10.1021/ja00305a023
PDF
Nucleophilic addition of silyl enol ethers to aromatic nitro compounds: scope and mechanism of reaction
T. V. RajanBabu, G. S. Reddy, and Tadamichi Fukunaga
pp 5473 - 5483; DOI:
10.1021/ja00305a024
PDF
Photocyclization of o-tert-butylbenzophenone
Peter J. Wagner, B. P. Giri, J. C. Scaiano, D. L. Ward, E. Gabe, and F. L. Lee
pp 5483 - 5490; DOI:
10.1021/ja00305a025
PDF
Possible biomimetic synthesis of .beta.-lactams
Takushi Kaneko
pp 5490 - 5492; DOI:
10.1021/ja00305a026
PDF
Metabolites of the marine prosobranch mollusk Lamellaria sp
Raymond J. Andersen, D. John Faulkner, Cun Heng He, Gregory D. Van Duyne, and Jon Clardy
pp 5492 - 5495; DOI:
10.1021/ja00305a027
PDF
General method for generation of 3-siloxyallylmetallic species and their synthetic application
Jun Enda and Isao Kuwajima
pp 5495 - 5501; DOI:
10.1021/ja00305a028
PDF
Dimerization of the [8]annulene anion radical
Gerald R. Stevenson and Mark A. Nebgen
pp 5501 - 5504; DOI:
10.1021/ja00305a029
PDF
Energetics and hydration structures of a solvated gramicidin A transmembrane channel for potassium and sodium cations
Kwang S. Kim and E. Clementi
pp 5504 - 5513; DOI:
10.1021/ja00305a030
PDF
A stereochemical imperative in dehydrogenases: new data and criteria for evaluating function-based theories in bioorganic chemistry
Steven A. Benner, Krishnan P. Nambiar, and Geoffrey K. Chambers
pp 5513 - 5517; DOI:
10.1021/ja00305a031
PDF
Photophysics of ruthenium complexes bound to double helical DNA
Challa V. Kumar, Jacqueline K. Barton, and Nicholas J. Turro
pp 5518 - 5523; DOI:
10.1021/ja00305a032
PDF
Dynamic cis-trans isomerization of retinal in dark-adapted bacteriorhodopsin
Stanley Seltzer and Ron Zuckermann
pp 5523 - 5525; DOI:
10.1021/ja00305a033
PDF
Insertion of elemental sulfur into tungsten-carbon bonds
Peter Legzdins and Luis Sanchez
pp 5525 - 5526; DOI:
10.1021/ja00305a034
PDF
Synthesis and thermal rearrangement of homopentafulvalenes
Klaus Hafner and Georg F. Thiele
pp 5526 - 5528; DOI:
10.1021/ja00305a035
PDF
Sequence-specific recognition of B DNA by bis(EDTA-distamycin)fumaramide
R. Scott Youngquist and Peter B. Dervan
pp 5528 - 5529; DOI:
10.1021/ja00305a036
PDF
Formation of acrylic acid derivatives from the reaction of carbon dioxide with ethylene complexes of molybdenum and tungsten
Rafael Alvarez, Ernesto Carmona, David J. Cole-Hamilton, Agustin Galindo, Enrique Gutierrez-Puebla, Angeles Monge, Manuel L. Poveda, and Caridad Ruiz
pp 5529 - 5531; DOI:
10.1021/ja00305a037
PDF
Chemistry of exciplexes. 19. Exciplex-promoted electron transfer in 1-(phenylamino)-3-(9-anthryl)propanes
Nien Chu C. Yang, Rex Gerald, and Michael R. Wasielewski
pp 5531 - 5532; DOI:
10.1021/ja00305a038
PDF
Thermal behavior of C8H8 hydrocarbons. 2. Semibullvalene: kinetic and thermodynamic stability
H. D. Martin, T. Urbanek, and R. Walsh
pp 5532 - 5534; DOI:
10.1021/ja00305a039
PDF
Stereospecific total synthesis of (.+-.)-gephyrotoxin 223AB
Hideo Iida, Yohya Watanabe, and Chihiro Kibayashi
pp 5534 - 5535; DOI:
10.1021/ja00305a040
PDF
Internal molecular motion as forerunner of a phase change involving conformational isomerization
Qing Chuan Yang, Mary Frances Richardson, and Jack D. Dunitz
pp 5535 - 5537; DOI:
10.1021/ja00305a041
PDF
Kinetics of iron(III) porphyrin catalyzed epoxidations
Teddy G. Traylor, James C. Marsters, Taku Nakano, and Beth E. Dunlap
pp 5537 - 5539; DOI:
10.1021/ja00305a042
PDF
Oxidation of phosphazine by singlet oxygen. High-field phosphorus-31 NMR spectroscopic studies of 3-phospha-1,2-dioxa-4,5-diazine and phospha-1,2-dioxetane
Takeshi Akasaka, Rikiya Sato, and Wataru Ando
pp 5539 - 5540; DOI:
10.1021/ja00305a043
PDF
Phase transitions affecting intramolecular electron transfer in mixed-valence trinuclear iron acetate complexes
Seung M. Oh, Takeshi Kambara, David N. Hendrickson, Michio Sorai, Kazutoshi Kaji, Scott E. Woehler, and Richard J. Wittebort
pp 5540 - 5541; DOI:
10.1021/ja00305a044
PDF
Stereoselective synthesis of .gamma.,.delta.-epoxy-.beta.-methyl-.gamma.-(trimethylsilyl)alkanols. Synthesis of the C(1)-C(7) segment of 6-deoxyerythronolide B
Yuichi Kobayashi, Hiroshi Uchiyama, Hiroshi Kanbara, and Fumie Sato
pp 5541 - 5543; DOI:
10.1021/ja00305a045
PDF
Chemistry and structure of the first 10-Sb-3 species
Constantine A. Stewart, Richard L. Harlow, and Anthony J. Arduengo
pp 5543 - 5544; DOI:
10.1021/ja00305a046
PDF
Efficient triple coupling reaction to produce a self-adjusting molecular cage
David O'Krongly, Samuel R. Denmeade, Michael Y. Chiang, and Ronald Breslow
pp 5544 - 5545; DOI:
10.1021/ja00305a047
PDF
A-(modified B6)-B-[.omega.-amino(ethylamino)]-.beta.-cyclodextrin as an artificial B6 enzyme for chiral aminotransfer reaction
Iwao Tabushi, Yasuhisa Kuroda, Masahiko Yamada, Hideyuki Higashimura, and Ronald Breslow
pp 5545 - 5546; DOI:
10.1021/ja00305a048
PDF
Formation of carbon dioxide and a four-membered 1,3-dimetallacycle by deoxygenation of a ketone with [Rh(CO)2Cl]2
J. William Suggs, Michael J. Wovkulich, and Ken S. Lee
pp 5546 - 5548; DOI:
10.1021/ja00305a049
PDF
Direct observation of the aziridinium imide intermediates in the reaction of biadamantylidene with triazolinediones
Stephen F. Nelsen and Daniel L. Kapp
pp 5548 - 5549; DOI:
10.1021/ja00305a050
PDF
Alkyl migration in an iron(II) alkylidene: a new route to a stabilized bridgehead olefin
Robert S. Bly, M. Mahmun Hossain, and Lukasz Lebioda
pp 5549 - 5550; DOI:
10.1021/ja00305a051
PDF
Mercuration of the selenium-selenium bond of a chelating diselenium group with mercury (Hg0): preparation and crystal structure of [(dmpe)2Ir(.mu.-Se)2Hg]4Cl4
A. P. Ginsberg and C. R. Sprinkle
pp 5550 - 5552; DOI:
10.1021/ja00305a052
PDF
The tetrasilabicyclo[1.1.0]butane system: preparation and characterization of 1,3-di-tert-butyl-2,2,4,4-tetrakis(2,6-diethylphenyl)tetrasilabicyclo[1.1.0]butane
Satoru Masamune, Yoshio Kabe, Scott Collins, David J. Williams, and Ray Jones
pp 5552 - 5553; DOI:
10.1021/ja00305a053
PDF
Fluxional behavior in the solid state: bullvalene
B. H. Meier and William L. Earl
pp 5553 - 5555; DOI:
10.1021/ja00305a054
PDF
A synthesis of methoxatin
George Buchi, James H. Botkin, Gary C. M. Lee, and Kenichi Yakushijin
pp 5555 - 5556; DOI:
10.1021/ja00305a055
PDF
Stereospecific synthesis of rhynchosporosides, a family of fungal metabolites causing scald disease in barley and other grasses
K. C. Nicolaou, J. L. Randall, and G. T. Furst
pp 5556 - 5558; DOI:
10.1021/ja00305a056
PDF
Adsorption and decomposition of formaldehyde on the ruthenium(001) surface: the spectroscopic identification of .eta.2-formaldehyde and .eta.2-formyl
A. B. Anton, J. E. Parmeter, and W. H. Weinberg
pp 5558 - 5560; DOI:
10.1021/ja00305a057
PDF
Ab initio mechanisms for the addition of methyllithium, lithium hydride, and their dimers to formaldehyde
Elmar Kaufmann, Paul v. R. Schleyer, Kendall N. Houk, and Yun Dong Wu
pp 5560 - 5562; DOI:
10.1021/ja00305a058
PDF
High-quantum-yield long-lived charge separation in a photosynthetic reaction center model
Michael R. Wasielewski, Mark P. Niemczyk, Walter A. Svec, and E. Bradley Pewitt
pp 5562 - 5563; DOI:
10.1021/ja00305a059
PDF
Protons on a cluster surface. Reversible generation of agostic (carbon-hydrogen-metal) hydrogens from iron hydrides (iron-hydrogen-iron) on a saturated triiron cluster
J. C. Vites, G. Jacobsen, T. K. Dutta, and T. P. Fehlner
pp 5563 - 5565; DOI:
10.1021/ja00305a060
PDF
The tungsten(IV) aqua ion
Masashi Segawa and Yoichi Sasaki
pp 5565 - 5566; DOI:
10.1021/ja00305a061
PDF
Common intermediates in the flash photolysis of Vaska's compound IrCl(CO)(PPh3)2 and its dihydride adduct H2IrCl(CO)(PPh3)2. Implications with regard to reductive elimination mechanisms
David A. Wink and Peter C. Ford
pp 5566 - 5567; DOI:
10.1021/ja00305a062
PDF
Diagonal peak suppression in 2D-NOE spectra
Gerard S. Harbison, Juli Feigon, David J. Ruben, Judith Herzfeld, and Robert G. Griffin
pp 5567 - 5569; DOI:
10.1021/ja00305a063
PDF
Synthesis and deuteration of (.eta.-thiophene)Ru(.eta.-C5H5)+: a model for adsorption and deuterium exchange of thiophene on hydrodesulfurization catalysts
George H. Spies and Robert J. Angelici
pp 5569 - 5570; DOI:
10.1021/ja00305a064
PDF
Total synthesis of (-)-upial
Michael J. Taschner and Abdulsadeh Shahripour
pp 5570 - 5572; DOI:
10.1021/ja00305a065
PDF
The anionic oxy-claisen rearrangement of enolates of .alpha.-allyloxy ketones. A remarkable rate accelerating effect exhibited by the nature of the counterion
Masato Koreeda and Juan I. Luengo
pp 5572 - 5573; DOI:
10.1021/ja00305a066
PDF
Total synthesis of (.+-.)-antheridium-inducing factor (AAn) of the Fern Anemia phyllitidis. Clarification of stereochemistry
E. J. Corey and Andrew G. Myers
pp 5574 - 5576; DOI:
10.1021/ja00305a067
PDF
Actinobolin via the anomeric effect
M. Abdur Rahman and Bert Fraser-Reid
pp 5576 - 5578; DOI:
10.1021/ja00305a068
PDF
Hydrogen/deuterium exchange and addition in the reaction of (.eta.4-C4H6)Fe(CO)-.cntdot. with deuterium(D2). An anionic model for homogeneous hydrogenation
Richard N. McDonald, Philip L. Schell, and A. Kasem Chowdhury
pp 5578 - 5579; DOI:
10.1021/ja00305a069
PDF
Ultrasound-induced electrochemical synthesis of the anions selenide (Se22-, Se2-), and telluride (Te22-, and Te2-)
Bernard Gautheron, Gerard Tainturier, and Chantal Degrand
pp 5579 - 5581; DOI:
10.1021/ja00305a070
PDF
Two molecular hydrogen complexes: trans-[M(.eta.2-H2)(H)(PPh2CH2CH2PPh2)2]BF4 (M = Fe, Ru). The crystal structure determination of the iron complex
Robert H. Morris, Jeffery F. Sawyer, Mahmoud Shiralian, and Jeffrey Zubkowski
pp 5581 - 5582; DOI:
10.1021/ja00305a071
PDF
Book Reviews

pp 5583 - 5588; DOI:
10.1021/ja00305a600
PDF

Issue 20


Fractal models of protein structure, dynamics and magnetic relaxation
Gerald C. Wagner, J. Trevor Colvin, James P. Allen, and Harvey J. Stapleton
pp 5589 - 5594; DOI:
10.1021/ja00306a001
PDF
Fourier transform infrared spectra of conjugated diene and cumulene complexes with hydrogen fluoride in solid argon
Kenneth O. Patten and Lester Andrews
pp 5594 - 5600; DOI:
10.1021/ja00306a002
PDF
Interaction of frontier orbitals of Group 15 and Group 16 methides with the frontier orbitals of benzene
Judith C. Giordan, John H. Moore, John A. Tossell, and Wolfgang Kaim
pp 5600 - 5604; DOI:
10.1021/ja00306a003
PDF
Electron spin resonance of the N-methylpyrazine radical: a new spin-labeled ligand
Donald R. Eaton, Janet M. Watkins, and Richard J. Buist
pp 5604 - 5609; DOI:
10.1021/ja00306a004
PDF
Photochemical reactions in organized assemblies. 44. Surfactant and hydrophobic derivatives of trans-stilbenes as probes of vesicle and micelle solubilization sites. Studies using fluorescence and photoisomerization as probes
Brian R. Suddaby, Patti E. Brown, John C. Russell, and David G. Whitten
pp 5609 - 5617; DOI:
10.1021/ja00306a005
PDF
Dual fluorescence of 4,4'-dimethylamino- and 4,4'-diaminophenyl sulfone. Consequences of d-orbital participation in the intramolecular charge separation process
Wolfgang Rettig and Edwin A. Chandross
pp 5617 - 5624; DOI:
10.1021/ja00306a006
PDF
Spectroscopic and electrochemical studies of transition-metal tetrasulfonated phthalocyanines. 3. Raman scattering from electrochemically adsorbed tetrasulfonated phthalocyanines on silver electrodes
B. Simic-Glavaski, S. Zecevic, and E. Yeager
pp 5625 - 5635; DOI:
10.1021/ja00306a007
PDF
Role of excited atomic states in the active sites of transition metals for oxidative and reductive catalytic processes
J. Garcia-Prieto, M. E. Ruiz, and O. Novaro
pp 5635 - 5644; DOI:
10.1021/ja00306a008
PDF
Clay modified electrodes. 3. Electrochemical and electron spin resonance study of montmorillonite layers
Deniz Ege, Pushpito K. Ghosh, James R. White, Jean Francois Equey, and Allen J. Bard
pp 5644 - 5652; DOI:
10.1021/ja00306a009
PDF
Cesium desorption ionization studies of .beta.-cyclodextrin by Fourier transform mass spectrometry
M. E. Castro, L. M. Mallis, and D. H. Russell
pp 5652 - 5657; DOI:
10.1021/ja00306a010
PDF
Structural consequences of electron-transfer reactions. 11. Electrochemically induced changes in hapticity in mixed-sandwich compounds of iridium and rhodium
Walter J. Bowyer and William E. Geiger
pp 5657 - 5663; DOI:
10.1021/ja00306a011
PDF
The reactions of organic halides with (.pi.-allyl)nickel halide complexes: a mechanistic study
Louis S. Hegedus and David H. P. Thompson
pp 5663 - 5669; DOI:
10.1021/ja00306a012
PDF
A new approach to the construction of biphenylenes by the cobalt-catalyzed cocyclization of o-diethynylbenzenes with alkynes. Application to an iterative approach to [3]phenylene, the first member of a novel class of benzocyclobutadienoid hydrocarbons
Bruce C. Berris, George H. Hovakeemian, Yee Hing Lai, Helene Mestdagh, and K. Peter C. Vollhardt
pp 5670 - 5687; DOI:
10.1021/ja00306a013
PDF
Cation-anion interaction in the [Na-kryptofix-221][W(CO)5O2CH] derivative and its relevance in carbon dioxide reduction processes
Donald J. Darensbourg and Magdalena Pala
pp 5687 - 5693; DOI:
10.1021/ja00306a014
PDF
Characterization of five-coordinate mono(imidazole)(porphinato)iron(II) complexes
W. Robert Scheidt, David K. Geiger, Young Ja Lee, Christopher A. Reed, and G. Lang
pp 5693 - 5699; DOI:
10.1021/ja00306a015
PDF
Substitution of manganese pentacarbonyl is associative
Thomas R. Herrinton and Theodore L. Brown
pp 5700 - 5703; DOI:
10.1021/ja00306a016
PDF
Stabilization of clusters by interstitial atoms. Three carbon-centered zirconium iodide clusters, Zr6I12C, Zr6I14C, and MZr6I14C (M = K, Rb, or Cs)
Jerome D. Smith and John D. Corbett
pp 5704 - 5711; DOI:
10.1021/ja00306a017
PDF
Iron(II)-induced activation of hydroperoxides for the dehydrogenation and monooxygenation of organic substrates in acetonitrile
Hiroshi Sugimoto and Donald T. Sawyer
pp 5712 - 5716; DOI:
10.1021/ja00306a018
PDF
Relative reactivity of bridgehead adamantyl and homoadamantyl substrates from solvolyses with heptafluorobutyrate as a highly reactive carboxylate leaving group. Absence of SN2 character of solvolysis of tert-butyl derivatives
Dan Farcasiu, Joachim Jaehme, and Christoph Ruechardt
pp 5717 - 5722; DOI:
10.1021/ja00306a019
PDF
2-Azapyrylium salts from aluminum halide .sigma. complexes of cyclobutadienes and nitrosyl chloride. On the possible intermediacy of a heteroatom-substituted pyramidal cation
Q. B. Broxterman, H. Hogeveen, R. F. Kingma, and F. Van Bolhuis
pp 5722 - 5729; DOI:
10.1021/ja00306a020
PDF
Trajectories through an intermediate at a fourfold branch point. Implications for the stereochemistry of biradical reactions
Barry K. Carpenter
pp 5730 - 5732; DOI:
10.1021/ja00306a021
PDF
Synthetic and structural studies in the [4.4.4.5]fenestrane series
V. Bhaskar Rao, Clifford F. George, Steven Wolff, and William C. Agosta
pp 5732 - 5739; DOI:
10.1021/ja00306a022
PDF
Bicyclic, boatlike Cope rearrangements. Probe for conformational preference by the nodal carbon atoms
William Von Eggers Doering and Caroline Ann Troise
pp 5739 - 5745; DOI:
10.1021/ja00306a023
PDF
Inverse electron demand Diels-Alder reactions of heterocyclic azadienes: formal total synthesis of streptonigrin
Dale L. Boger, James S. Panek, and Steven R. Duff
pp 5745 - 5754; DOI:
10.1021/ja00306a024
PDF
Resonance Raman studies of blue copper proteins: effects of temperature and isotopic substitutions. Structural and thermodynamic implications
David F. Blair, Gary W. Campbell, W. K. Cho, Ann M. English, Herbert A. Fry, Vanessa Lum, K. A. Norton, Jon R. Schoonover, and Sunney I. Chan
pp 5755 - 5766; DOI:
10.1021/ja00306a025
PDF
Catalysis by human leukocyte elastase. Role of secondary-subsite interactions
Ross L. Stein
pp 5767 - 5775; DOI:
10.1021/ja00306a026
PDF
Kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 2. Amine oxidation and oxygen transfer to hydrocarbon substrates accompanying the reaction of p-cyano-N,N-dimethylaniline N-oxide with meso-(tetraphenylporphinato)iron(III) chloride
C. Michael Dicken, Fu Lung Lu, Michael W. Nee, and Thomas C. Bruice
pp 5776 - 5789; DOI:
10.1021/ja00306a027
PDF
Trichloro(1-methylcytosinato)gold(III). Model for gold-DNA interactions
Marko S. Holowczak, Mark D. Stancl, and Geoffrey B. Wong
pp 5789 - 5790; DOI:
10.1021/ja00306a028
PDF
Aerobic epoxidation of olefins with ruthenium porphyrin catalysts
John T. Groves and Robert Quinn
pp 5790 - 5792; DOI:
10.1021/ja00306a029
PDF
Tetrakis(1,3-dithiol-2-ylidene)cyclobutane: a novel and promising electron donor for organic metals
Toyonari Sugimoto, Hiroshi Awaji, Yohji Misaki, Zenichi Yoshida, Yasushi Kai, Hajime Nakagawa, and Nobutami Kasai
pp 5792 - 5793; DOI:
10.1021/ja00306a030
PDF
Measurement of the activation barrier for carrier transport at n-gallium arsenide semiconductor/liquid junctions
Louis G. Casagrande and Nathan S. Lewis
pp 5793 - 5794; DOI:
10.1021/ja00306a031
PDF
Calorimetric solution electron affinities
Gerald R. Stevenson and Ramli Tamby Hashim
pp 5794 - 5795; DOI:
10.1021/ja00306a032
PDF
Preparation, structure, and coordination chemistry of molybdenum(IV) tetrathiolates, Mo[S-2,4,6-C6H2(CHMe2)3]4
Eckehart Roland, Eric C. Walborsky, John C. Dewan, and Richard R. Schrock
pp 5795 - 5797; DOI:
10.1021/ja00306a033
PDF
Direct observation of a 1,3-biradical
K. Mizuno, N. Ichinose, and Y. Otsuji
pp 5797 - 5798; DOI:
10.1021/ja00306a034
PDF
Cyclization dynamics of polymers. 18. Capture radius effects in the end-to-end cyclization rate of polymers
Andrew M. Sinclair, Mitchell A. Winnik, and Gerard Beinert
pp 5798 - 5800; DOI:
10.1021/ja00306a035
PDF
Temperature dependence of the transition-state structure for the disproportionation of hydrogen atom with ethyl radical
C. Doubleday, J. McIver, and M. Page
pp 5800 - 5801; DOI:
10.1021/ja00306a036
PDF
Novel dimerization reaction of bis(alkylthio)cyclopropenethiones affording tetrakis(alkylthio)thieno[3,4-c]thiophenes
Shigeo Yoneda, Kenji Ozaki, Toshihide Inoue, Akira Sugimoto, Kazunori Yanagi, and Masao Minobe
pp 5801 - 5802; DOI:
10.1021/ja00306a037
PDF
Pressure-induced torsional isomerism in [n-Bu4N]2[RexX8] (X = bromine, iodine)
T. L. Carroll, John R. Shapley, and H. G. Drickamer
pp 5802 - 5803; DOI:
10.1021/ja00306a038
PDF
Polymerization of macrocyclic phospholipid- and surfactant-based vesicles
Steven L. Regen, N. K. P. Samuel, and Jitender M. Khurana
pp 5804 - 5805; DOI:
10.1021/ja00306a039
PDF
New semisynthetic flavoenzymes based on a tetrameric protein template, glyceraldehyde-3-phosphate dehydrogenase
Donald Hilvert and E. T. Kaiser
pp 5805 - 5806; DOI:
10.1021/ja00306a040
PDF
Sterically hindered triplet energy transfer
J. C. Scaiano, W. Leigh, M. A. Meador, and P. J. Wagner
pp 5806 - 5807; DOI:
10.1021/ja00306a041
PDF
Photodisproportionation of (4-acylpyridine)tungsten(0) pentacarbonyl complexes
Nicholas Leventis and Peter J. Wagner
pp 5807 - 5809; DOI:
10.1021/ja00306a042
PDF
Ultrahigh resolution NMR. 1. General considerations and preliminary results for carbon-13 NMR
Adam Allerhand, Robert E. Addleman, and Deon Osman
pp 5809 - 5810; DOI:
10.1021/ja00306a043
PDF
Tandem electrocyclic-sigmatropic reaction of benzocyclobutenes. An expedient route to 4,4-disubstituted isochromanones
Kozo Shishido, Eiki Shitara, Keiichiro Fukumoto, and Tetsuji Kametani
pp 5810 - 5812; DOI:
10.1021/ja00306a044
PDF
Enantioselective synthesis of anti-.alpha.-methyl-.beta.-hydroxy esters through titanium tetrachloride-mediated aldol condensation
Cesare Gennari, Anna Bernardi, Lino Colombo, and Carlo Scolastico
pp 5812 - 5813; DOI:
10.1021/ja00306a045
PDF
Synthesis of branched ribonucleotides related to the mechanism of splicing of eukaryotic messenger RNA
Mitsuo Sekine and Tsujiaki Hata
pp 5813 - 5815; DOI:
10.1021/ja00306a046
PDF
Band electronic structures of the ambient pressure organic superconductors .beta.-(ET)2X (X = I3-, IBr2-)
Myung Hwan Whangbo, Jack M. Williams, Peter C. W. Leung, Mark A. Beno, Thomas J. Emge, Hau H. Wang, K. Douglas Carlson, and G. W. Crabtree
pp 5815 - 5816; DOI:
10.1021/ja00306a047
PDF
Isomunchnone polymerization. Polyvinylenelactams from 1-(2-chloroacetyl)lactams through a mesoionic intermediate
Lon J. Mathias and D. Roger Moore
pp 5817 - 5818; DOI:
10.1021/ja00306a048
PDF
Structure and reactivity of [TiRu(CO)2(C5H5)(NMe2)3]: a direct early-late transition metal bond formed by amine elimination
William J. Sartain and John P. Selegue
pp 5818 - 5820; DOI:
10.1021/ja00306a049
PDF
Effects of molecular organization on photophysical behavior. Excimer kinetics and diffusion of 1-pyrenedecanoic acid in lipid monolayers at the nitrogen-water interface
R. Subramanian and L. K. Patterson
pp 5820 - 5821; DOI:
10.1021/ja00306a050
PDF
A new class of amino acid based sweeteners
William D. Fuller, Murray Goodman, and Michael S. Verlander
pp 5821 - 5822; DOI:
10.1021/ja00306a051
PDF
Total synthesis of khellin via a chromium carbene complex
Ayako Yamashita
pp 5823 - 5824; DOI:
10.1021/ja00306a052
PDF
Photolysis of dibenzyl ketones in the presence of pentasil zeolites. Examples of size/shape selectivity and molecular diffusional traffic control
Nicholas J. Turro, Xuegong Lei, Chen Chih Cheng, David R. Corbin, and Lloyd Abrams
pp 5824 - 5826; DOI:
10.1021/ja00306a053
PDF
Triplet energy transfer as a probe of surface diffusion rates: time-resolved diffuse reflectance transient absorption spectroscopy study
Nicholas J. Turro, Matthew B. Zimmt, Ian R. Gould, and Walter Mahler
pp 5826 - 5827; DOI:
10.1021/ja00306a054
PDF
Dioxygen-copper reactivity. Reversible oxygen and carbon monoxide binding by a new series of binuclear copper(I) complexes
Kenneth D. Karlin, Michael S. Haka, Richard W. Cruse, and Yilma Gultneh
pp 5828 - 5829; DOI:
10.1021/ja00306a055
PDF
Indirect, negative heteronuclear Overhauser effect detected in a steady-state, selective 13C{1H} NOE experiment at natural abundance
Katalin E. Kover and Gyula Batta
pp 5829 - 5830; DOI:
10.1021/ja00306a056
PDF
Streptonigrin biosynthesis. 7. Incorporation of oxygen from oxygen-18: evidence for an oxidative .beta.-carboline cleavage
W. Randal Erickson and Steven J. Gould
pp 5831 - 5832; DOI:
10.1021/ja00306a057
PDF
Additions and Corrections - Molecular Structure of 1,4,5,8-Tetramethylnaphthalene and Inplane Molecular Rotation of Some Methyl-Substituted Naphthalenes in Solids

pp 5832 - 5832; DOI:
10.1021/ja00306a302
PDF
Additions and Corrections - Total Synthesis of Elfamycins: Aurodox and Efrotomycin. 1. Strategy and Construction of Key Intermediates
R. E. Dolle, and K. C. Nicolaou
pp 5832 - 5832; DOI:
10.1021/ja00306a601
PDF
Additions and Corrections - Molecular Structure of 1,4,5,8-Tetramethylnaphthalene and Inplane Molecular Rotation of Some Methyl-Substituted Naphthalenes in Solids
Fumio Imashiro, Kiyonori Takegoshi, A. Saika, Zenei Taira, and Yutaka Asahi
pp 5832 - 5832; DOI:
10.1021/ja00306a602
PDF
Additions and Corrections - Stable Simple Enols. 11. Equilibrium Constants for the 1-Alkyl-2,2-dimesitylethenol /1-Alkyl2,2-dimesitylethanone Systems in Hexane. The Predominance of Steric Effects on Kenol Values
David A. Nugiel, and Zvi Rappoport
pp 5832 - 5832; DOI:
10.1021/ja00306a603
PDF
Additions and Corrections - Organoboron Compounds in Organic Synthesis. 1. Asymmetric Hydroboration.
S. Masamune, B. Kim, J. S. Petersen, T. Sato, S. J. Veenstra, and T. Imai
pp 5832 - 5832; DOI:
10.1021/ja00306a604
PDF
Book Reviews

pp 5833 - 5838; DOI:
10.1021/ja00306a600
PDF

Issue 21


Solvent effects on photoinduced electron transfer in rigid, bichromophoric systems
Peter Pasman, Ger F. Mes, Nico W. Koper, and Jan W. Verhoeven
pp 5839 - 5843; DOI:
10.1021/ja00307a001
PDF
Search for singlet oxygen in the decomposition of hydrogen peroxide by mineral compounds in aqueous solutions
J. M. Aubry
pp 5844 - 5849; DOI:
10.1021/ja00307a002
PDF
A theoretical study of model substituted phosphoranes, PH4X: apicophilicities, geometries, and electron densities
Robert S. McDowell and Andrew Streitwieser
pp 5849 - 5855; DOI:
10.1021/ja00307a003
PDF
Evaluation of small Gaussian basis sets and analysis of substituent effects in monosubstituted benzenes and phenols
E. L. Mehler and J. Gerhards
pp 5856 - 5863; DOI:
10.1021/ja00307a004
PDF
Structural analysis of methyltin(IV) polymers by solid-state carbon-13 NMR spectroscopy
Thomas P. Lockhart and William F. Manders
pp 5863 - 5866; DOI:
10.1021/ja00307a005
PDF
Effects of solvent and hydroxyl deuteration on the carbon-13 NMR spectrum of D-idose: spectral assignments, tautomeric compositions, and conformational equilibria
Jacques Reuben
pp 5867 - 5870; DOI:
10.1021/ja00307a006
PDF
Transition-metal-carbene chemistry. Structure, thermodynamics, and reactivity of rhodium methylidene ion (RhCH2+) in the gas phase
D. B. Jacobson and B. S. Freiser
pp 5870 - 5876; DOI:
10.1021/ja00307a007
PDF
Reactions of methyliron(1+) (MeFe+) and methylcobalt(1+) (MeCo+) with aliphatic alkenes and alkynes in the gas phase
D. B. Jacobson and B. S. Freiser
pp 5876 - 5883; DOI:
10.1021/ja00307a008
PDF
Electronic spectra of cis- and trans-azobenzenes: consequences of ortho substitution
Christine L. Forber, Eric C. Kelusky, Nigel J. Bunce, and Michael C. Zerner
pp 5884 - 5890; DOI:
10.1021/ja00307a009
PDF
Oxidation processes in the gas-phase silane-ozone system. Chemiluminescent emission and the molecular structure of H2SiO
Robert J. Glinski, James L. Gole, and David A. Dixon
pp 5891 - 5894; DOI:
10.1021/ja00307a010
PDF
Upper excited state reactivity and fluorescence of fused 8-cyanoheptafulvenes
Yoshikazu Sugihara, Shigeharu Wakabayashi, Ichiro Murata, Mamoru Jinguji, Tomoo Nakazawa, Gabriele Persy, and Jakob Wirz
pp 5894 - 5897; DOI:
10.1021/ja00307a011
PDF
Carbon-carbon bond activation: cycloheptatriene reaction on tungsten(100), tungsten(100)-(5 .times. 1)-C, and tungsten(100)-(2 .times. 1)-O
K. A. Pearlstine and C. M. Friend
pp 5898 - 5901; DOI:
10.1021/ja00307a012
PDF
Photoelectron, infrared, and theoretical study of 1-aza-5-boratricyclo[3.3.3.01,5]undecane and related compounds
Keui Jen Lee, Peter D. Livant, Michael L. McKee, and S. D. Worley
pp 5901 - 5906; DOI:
10.1021/ja00307a013
PDF
Picosecond photochemistry of iodine-arene complexes
E. F. Hilinski and P. M. Rentzepis
pp 5907 - 5910; DOI:
10.1021/ja00307a014
PDF
A comparison of gas-phase and electrochemical hydrogenation of ethylene at platinum surfaces
Andrzej Wieckowski, Stephen D. Rosasco, Ghaleb N. Salaita, Arthur Hubbard, Brian E. Bent, Francisco Zaera, and Gabor A. Somorjai
pp 5910 - 5920; DOI:
10.1021/ja00307a015
PDF
Crystal environments and geometries of leucine, isoleucine, valine and phenylalanine provide estimates of minimum nonbonded contact and preferred van der Waals interaction distances
Robert O. Gould, Alexandra M. Gray, Paul Taylor, and Malcolm D. Walkinshaw
pp 5921 - 5927; DOI:
10.1021/ja00307a016
PDF
Kinetics and mechanisms of complex formation of uranyl ion with 18-crown-6 and diaza-18-crown-6 ligands in propylene carbonate
Pierre Fux, Janine Lagrange, and Philippe Lagrange
pp 5927 - 5931; DOI:
10.1021/ja00307a017
PDF
DNA-intrastrand guanine, guanine cross-linking by cisplatin: comparison of three model compounds with head-head orientation of the nucleobases
Helmut Schoellhorn, Gabriele Raudaschl-Sieber, Gerhard Mueller, Ulf Thewalt, and Bernhard Lippert
pp 5932 - 5937; DOI:
10.1021/ja00307a018
PDF
Structure-stability relationship in ternary copper(II) complexes involving aromatic amines and tyrosine or related amino acids. Intramolecular aromatic ring stacking and its regulation through tyrosine phosphorylation
Osamu Yamauchi and Akira Odani
pp 5938 - 5945; DOI:
10.1021/ja00307a019
PDF
Polarized x-ray absorption edge spectroscopy of single-crystal copper(II) complexes
Teres A. Smith, James E. Penner-Hahn, Martha A. Berding, Sebastian Doniach, and Keith O. Hodgson
pp 5945 - 5955; DOI:
10.1021/ja00307a020
PDF
.eta.1-Benzene coordination: the synthesis and x-ray crystal structure of a novel silver salt of the weakly coordinating carborane anion B11CH12-
Kenneth Shelly, David C. Finster, Young Ja Lee, W. Robert Scheidt, and Christopher A. Reed
pp 5955 - 5959; DOI:
10.1021/ja00307a021
PDF
Structural consequences of electron-transfer reactions. Part 12. Multi electron processes involving structural changes. The two-electron reduction of hexaosmium carbonyl cluster (Os6(CO)18)
Bunchai Tulyathan and William E. Geiger
pp 5960 - 5967; DOI:
10.1021/ja00307a022
PDF
Triangular platinum and nickel clusters: the "tinker-toy" construction of chains with high nuclearity
Dennis J. Underwood, Roald Hoffmann, Kazuyuki Tatsumi, Akira Nakamura, and Yasuhiro Yamamoto
pp 5968 - 5980; DOI:
10.1021/ja00307a023
PDF
Synthetic and mechanistic aspects of intramolecular aliphatic carbon-hydrogen bond activation by titanium(IV) and zirconium(IV) metal centers
Stanley L. Latesky, Anne K. McMullen, Ian P. Rothwell, and John C. Huffman
pp 5981 - 5987; DOI:
10.1021/ja00307a024
PDF
Multiple metal-carbon bonds. 38. Preparation of trialkoxymolybdenum(VI) alkylidyne complexes, their reactions with acetylenes, and the x-ray structure of Mo[C3(CMe3)2][OCH(CF3)2](C5H5N)2
Laughlin G. McCullough, Richard R. Schrock, John C. Dewan, and John C. Murdzek
pp 5987 - 5998; DOI:
10.1021/ja00307a025
PDF
Multiple metal-carbon bonds. 40. Reaction of Mo(CCMe3)[OCH(CF3)2]3(dimethoxyethane) with tert-butylacetylene, an aborted acetylene polymerization
H. Strutz, J. C. Dewan, and R. R. Schrock
pp 5999 - 6005; DOI:
10.1021/ja00307a026
PDF
Exocyclic cleavage in the alkaline hydrolysis of methyl ethylene phosphate. Evidence against the significance of stereoelectronic acceleration in reactions of cyclic phosphates
Ronald Kluger and Gregory R. J. Thatcher
pp 6006 - 6011; DOI:
10.1021/ja00307a027
PDF
Structure of trichorzianine A IIIc, an antifungal peptide from Trichoderma harzianum
Bernard Bodo, Sylvie Rebuffat, Mohamed El Hajji, and Daniel Davoust
pp 6011 - 6017; DOI:
10.1021/ja00307a028
PDF
Stable carbocations. 261. Deuterium isotope effects on the carbon-13 NMR spectra of 1-methylcyclobutyl and trishomocyclopropenyl cations
G. K. Surya Prakash, Massoud Arvanaghi, and George A. Olah
pp 6017 - 6019; DOI:
10.1021/ja00307a029
PDF
Enthalpies of hydration of alkenes. 3. Cycloalkenes
Kenneth B. Wiberg, David J. Wasserman, Eric J. Martin, and Mark A. Murcko
pp 6019 - 6022; DOI:
10.1021/ja00307a030
PDF
Thermolysis of bis[2-[(trimethylsilyl)oxy]propyl]furoxan (TOP-furoxan). The first practical method for intermolecular cycloaddition of an in situ generated nitrile oxide with 1,2-di- and trisubstituted olefins
Dennis P. Curran and Christopher J. Fenk
pp 6023 - 6028; DOI:
10.1021/ja00307a031
PDF
.alpha.-Deuterium and carbon-13 kinetic isotope effects associated with the SN2 displacement of iodide and tosylate by lithium organocuprates
Cong Yuan Guo, Marilyn L. Brownawell, and Joseph San Filippo
pp 6028 - 6030; DOI:
10.1021/ja00307a032
PDF
Kinetics of neutral hydrolysis of two 1-acyl-1,2,4-triazoles in binary aqueous mixtures: a critique of the Evans and Polanyi proposals concerning isochoric activation parameters
Jan R. Haak, Jan B. F. N. Engberts, and Michael J. Blandamer
pp 6031 - 6035; DOI:
10.1021/ja00307a033
PDF
Rate-controlling step of oxazolinone formation. Secondary and solvent kinetic isotope effects
Michael S. Matta and Mark E. Andracki
pp 6036 - 6039; DOI:
10.1021/ja00307a034
PDF
Transition-state properties for the association of .alpha.-1-protease inhibitor with porcine pancreatic elastase
Ross L. Stein
pp 6039 - 6042; DOI:
10.1021/ja00307a035
PDF
Binding of calcium to amino acids: the crystal structure of pentaaquobis(hydroxy-(L)-prolinato)calcium, Ca(C5H8O3N)2.5H2O
Eunice E. Kim, Andrew Sicignano, and Klaas Eriks
pp 6042 - 6046; DOI:
10.1021/ja00307a036
PDF
Stereochemical course of an enzyme-catalyzed allene-acetylene isomerization
John M. Schwab and Daniel C. T. Lin
pp 6046 - 6052; DOI:
10.1021/ja00307a037
PDF
Calixarenes. 13. The conformational properties of calix[4]arenes, calix[6]arenes, calix[8]arenes, and oxacalixarenes
C. David Gutsche and Lorenz J. Bauer
pp 6052 - 6059; DOI:
10.1021/ja00307a038
PDF
Calixarenes. 14. The conformational properties of the ethers and esters of the calix[6]arenes and the calix[8]arenes
C. David Gutsche and Lorenz J. Bauer
pp 6059 - 6063; DOI:
10.1021/ja00307a039
PDF
Calixarenes. 15. The formation of complexes of calixarenes with neutral organic molecules in solution
Lorenz J. Bauer and C. David Gutsche
pp 6063 - 6069; DOI:
10.1021/ja00307a040
PDF
Proposed structure of heme d, a prosthetic group of bacterial terminal oxidases
Russell Timkovich, Margaret S. Cork, Robert B. Gennis, and Peter Y. Johnson
pp 6069 - 6075; DOI:
10.1021/ja00307a041
PDF
Two-step covalent modification of proteins. Selective labeling of Schiff base-forming sites and selective blockade of the sense of smell in vivo
J. Russell Mason, Fah Che Leong, Kevin W. Plaxco, and Thomas Hellman Morton
pp 6075 - 6084; DOI:
10.1021/ja00307a042
PDF
Biomimetic models for cysteine proteases. 1. Intramolecular imidazole catalysis of thiol ester solvolysis: a model for the deacylation step
J. P. Street and R. S. Brown
pp 6084 - 6089; DOI:
10.1021/ja00307a043
PDF
Halomethylenes: effects of halogen substitution on absolute heats of formation
Sharon G. Lias, Zeev Karpas, and Joel F. Liebman
pp 6089 - 6096; DOI:
10.1021/ja00307a044
PDF
Dissociative electron transfer. Autocatalysis and kinetic characteristics of the electrochemical reductive cleavage of the carbon halogen bond in alkyl halides giving rise to stable radicals and carbanions
Claude P. Andrieux, Andreas Merz, and Jean Michel Saveant
pp 6097 - 6103; DOI:
10.1021/ja00307a045
PDF
Configuration entropy of the alanine dipeptide in vacuum and in solution: a molecular dynamics study
John Brady and Martin Karplus
pp 6103 - 6105; DOI:
10.1021/ja00307a046
PDF
Intramolecular reductive elimination of methane from a dinuclear palladium complex containing methyl and hydride on adjacent palladium centers
B. Kellenberger, S. J. Young, and John K. Stille
pp 6105 - 6107; DOI:
10.1021/ja00307a047
PDF
A new type of carbene catalyst. Direct evidence for the involvement of coordinated carbenes in a cluster-catalyzed transalkylation reaction between tertiary amines
Richard D. Adams, Hoon Sik Kim, and Suning Wang
pp 6107 - 6108; DOI:
10.1021/ja00307a048
PDF
Synthesis of biscopper(I) [3]-catenates: multiring interlocked coordinating systems
Jean Pierre Sauvage and Jean Weiss
pp 6108 - 6110; DOI:
10.1021/ja00307a049
PDF
Reactivity of zero-valent metalloporphyrin dianions toward organic electrophiles
James P. Collman, P. J. Brothers, L. McElwee-White, and E. Rose
pp 6110 - 6111; DOI:
10.1021/ja00307a050
PDF
Mechanism of the azulene to naphthalene rearrangement
Michael J. S. Dewar and Kenneth M. Merz
pp 6111 - 6112; DOI:
10.1021/ja00307a051
PDF
Intramolecular photochemical electron transfer. 3. Solvent dependence of fluorescence quenching and electron transfer rates in a porphyrin-amide-quinone molecule
John A. Schmidt, Aleksander Siemiarczuk, Alan C. Weedon, and James R. Bolton
pp 6112 - 6114; DOI:
10.1021/ja00307a052
PDF
Organic reactions in liquid-crystalline solvents. 3. Substituted .beta.-phenylpropiophenones as photochemical probes of solute-solvent interactions in liquid crystals
William J. Leigh
pp 6114 - 6116; DOI:
10.1021/ja00307a053
PDF
Photoactivated oxidation by alcohols by oxygen
Randy E. Cameron and Andrew B. Bocarsly
pp 6116 - 6117; DOI:
10.1021/ja00307a054
PDF
A chiral pyrene excimer in .gamma.-cyclodextrin cavity
Koji Kano, Hitoshi Matsumoto, Shizunobu Hashimoto, Masahiko Sisido, and Yukio Imanishi
pp 6117 - 6118; DOI:
10.1021/ja00307a055
PDF
Use of differential second-derivative UV and FTIR spectroscopy in structural studies of multichromophoric compounds
Gregory L. Verdine and Koji Nakanishi
pp 6118 - 6120; DOI:
10.1021/ja00307a056
PDF
Nature of the destruction of deoxyguanosine residues by mitomycin C
Maria Tomasz, Roselyn Lipman, Gregory Verdine, and Koji Nakanishi
pp 6120 - 6121; DOI:
10.1021/ja00307a057
PDF
Multidentate Lewis acids. Reduction of thioketones in the presence of organomercury trifluoroacetates
James D. Wuest and Boulos Zacharie
pp 6121 - 6123; DOI:
10.1021/ja00307a058
PDF
Palladium-mediated vicinal cleavage of allyl epoxides with retention of stereochemistry: a cis hydroxylation equivalent
Barry M. Trost and Steven R. Angle
pp 6123 - 6124; DOI:
10.1021/ja00307a059
PDF
Isolation of oxo-centered cobalt(III) clusters and their role in the cobalt bromide catalyzed autoxidation of aromatic hydrocarbons
Charles E. Sumner and Guy R. Steinmetz
pp 6124 - 6126; DOI:
10.1021/ja00307a060
PDF
The quest for free metaphosphate in solution: racemization at phosphorus in the transfer of the phospho group from phenyl phosphate to tert-butyl alcohol in acetonitrile
Jonathan M. Friedman and Jeremy R. Knowles
pp 6126 - 6127; DOI:
10.1021/ja00307a061
PDF
Synthesis and properties of doped .mu.-oxo(tetrabenzoporphyrinato)germanium(IV)
Michael Hanack and Tilman Zipplies
pp 6127 - 6129; DOI:
10.1021/ja00307a062
PDF
First observation by potassium-39 NMR of K- in solution and in crystalline potassides
Mary L. Tinkham and James L. Dye
pp 6129 - 6130; DOI:
10.1021/ja00307a063
PDF
Gas-phase electron transfer: direct observation of kinetic barriers in metallocene self-exchange reactions
John R. Eyler and David E. Richardson
pp 6130 - 6131; DOI:
10.1021/ja00307a064
PDF
Direct measurements of rate differences among nuclear spin sublevels in reactions of biradicals.
G. L. Closs and O. D. Redwine
pp 6131 - 6133; DOI:
10.1021/ja00307a065
PDF
Improved energy storage in a two-polyelectrolyte system
Richard E. Sassoon
pp 6133 - 6134; DOI:
10.1021/ja00307a066
PDF
Interactions of atomic and molecular iron with methane in argon matrix
Zakya H. Kafafi, Robert H. Hauge, and John L. Margrave
pp 6134 - 6135; DOI:
10.1021/ja00307a067
PDF
Electron transfer in the heme pocket of hemoglobin
Michael P. Doyle, Surendra N. Mahapatro, Craig M. VanZyl, and Mathew R. Hester
pp 6136 - 6137; DOI:
10.1021/ja00307a068
PDF
Synthesis via vinyl sulfones. 13. Stereoselective, chemodirected formal SN2' addition of organometallic reagents to .beta.'-amino cyclopentenyl sulfone derivatives
D. K. Hutchinson and P. L. Fuchs
pp 6137 - 6138; DOI:
10.1021/ja00307a069
PDF
Homogeneous catalysis of hydrogen reduction of sulfur dioxide to sulfur and water using [(.eta.5-MenCp)Mo(S)(SH)]2
Gregory J. Kubas and R. R. Ryan
pp 6138 - 6140; DOI:
10.1021/ja00307a070
PDF
Computer Software Reviews

pp 6140 - 6142; DOI:
10.1021/ja00307a600
PDF
Book Reviews

pp 6143 - 6152; DOI:
10.1021/ja00307a601
PDF

Issue 22


Electron hydration dynamics using the 2-anilinonaphthalene precursor
J. Lee and G. W. Robinson
pp 6153 - 6156; DOI:
10.1021/ja00308a001
PDF
A theoretical study of olefin insertions into titanium-carbon and titanium-hydrogen bonds. An analysis by paired interacting orbitals
Hiroshi Fujimoto, Terumasa Yamasaki, Hirotaka Mizutani, and Nobuaki Koga
pp 6157 - 6161; DOI:
10.1021/ja00308a002
PDF
Line shape of the intervalence transfer band in bridged mixed-valence dimers: the delocalized case
Jaeju Ko and Mary Jo Ondrechen
pp 6161 - 6167; DOI:
10.1021/ja00308a003
PDF
NMR and infrared studies of the complexation reaction of 18-crown-6 with some organic solvents
Pamela A. Mosier-Boss and Alexander I. Popov
pp 6168 - 6174; DOI:
10.1021/ja00308a004
PDF
Development and use of quantum molecular models. Part 77. MNDO calculations for the dehydrocyclooctatetraenes
Michael J. S. Dewar and Kenneth M. Merz
pp 6175 - 6179; DOI:
10.1021/ja00308a005
PDF
Evidence for triplet state sublevel selective photochemistry in phthalazine
D. A. Leinwand, S. M. Lefkowitz, and H. C. Brenner
pp 6179 - 6183; DOI:
10.1021/ja00308a006
PDF
Novel structural modulation in the ambient-pressure sulfur-based organic superconductor .beta.-(BEDT-TTF)2I3: origin and effects on its electrical conductivity
Peter C. W. Leung, Thomas J. Emge, Mark A. Beno, Hau H. Wang, Jack M. Williams, Vaclav Petricek, and Philip Coppens
pp 6184 - 6191; DOI:
10.1021/ja00308a007
PDF
Secondary ion mass spectrometry of monomolecular layers of fatty acids prepared by Langmuir-Blodgett techniques
Joseph H. Wandass and Joseph A. Gardella
pp 6192 - 6195; DOI:
10.1021/ja00308a008
PDF
Chemical ionization/fast-atom bombardment mass spectrometry: ion/molecule reactions
Royal B. Freas, Mark M. Ross, and Joseph E. Campana
pp 6195 - 6201; DOI:
10.1021/ja00308a009
PDF
Reactions of sputtered copper cluster ions
Royal B. Freas and Joseph E. Campana
pp 6202 - 6204; DOI:
10.1021/ja00308a010
PDF
Vibrational circular dichroism in bis(acetylacetonato)(L-alaninato)cobalt(III). Isolated occurrences of the coupled oscillator and ring current intensity mechanisms
Daryl A. Yung, Elmer D. Lipp, and Laurence A. Nafie
pp 6205 - 6213; DOI:
10.1021/ja00308a011
PDF
Enhanced vibrational circular dichroism via vibrationally generated electronic ring currents
Teresa B. Freedman, Gregory A. Balukjian, and Laurence A. Nafie
pp 6213 - 6222; DOI:
10.1021/ja00308a012
PDF
Heteronuclear transition-metal cluster ions in the gas phase. Photodissociation and reactivity of vanadium-iron cluster ion (VFe+)
R. L. Hettich and B. S. Freiser
pp 6222 - 6226; DOI:
10.1021/ja00308a013
PDF
.pi.-Bond anisotropy and C-D.cntdot..cntdot..cntdot.O hydrogen bonding in the crystal structure of deuterionitromethane
G. A. Jeffrey, J. R. Ruble, L. M. Wingert, J. H. Yates, and R. K. McMullan
pp 6227 - 6230; DOI:
10.1021/ja00308a014
PDF
Metal ion promoted hydration of pendant alkenes and its possible relationship to aconitase
Lawrence R. Gahan, Jack M. Harrowfield, Anthony J. Herlt, Leonard F. Lindoy, Peter O. Whimp, and Alan W. Sargeson
pp 6231 - 6242; DOI:
10.1021/ja00308a015
PDF
X-ray studies on metal ion interactions with vitamins. 1. Crystal and molecular structure of the tetrakis(.mu.-acetato)bis(thiamin monophosphate)dirhodium(II) sesquihydrate complex: thiamin base-metal bonding
Katsuyuki Aoki and Hiroshi Yamazaki
pp 6242 - 6249; DOI:
10.1021/ja00308a016
PDF
Phosphorus-31 magic angle spinning NMR study of the cation distribution in Zn3-xMgx(PO4)2
R. J. B. Jakeman, A. K. Cheetham, N. J. Clayden, and C. M. Dobson
pp 6249 - 6252; DOI:
10.1021/ja00308a017
PDF
Dimerization and stacking in transition-metal bisdithiolenes and tetrathiolates
Santiago Alvarez, Ramon Vicente, and Roald Hoffmann
pp 6253 - 6277; DOI:
10.1021/ja00308a018
PDF
Stepwise reduction of carbon dioxide to formaldehyde and methanol: reactions of carbon dioxide and carbon dioxide like molecules with hydridochlorobis(cyclopentadienyl)zirconium(IV)
Sandro Gambarotta, Sauro Strologo, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 6278 - 6282; DOI:
10.1021/ja00308a019
PDF
Axial ligand anation and aquation reactions in diplatinum(III) complexes. Comparison of aquation rates between hexachloroplatinate(IV) anion and diplatinum(III) chloro complexes having .mu.-phosphato or .mu.-pyrophosphito ligands
Ramadan El-Mehdawi, Samuel A. Bryan, and D. Max Roundhill
pp 6282 - 6286; DOI:
10.1021/ja00308a020
PDF
Coenzyme models. 41. On the unusual reactivities of N(5)-hydrogen-bonded flavin. An approach to regiospecific flavin activation through hydrogen bonding
Seiji Shinkai, Noriaki Honda, Yuichi Ishikawa, and Osamu Manabe
pp 6286 - 6292; DOI:
10.1021/ja00308a021
PDF
Synthesis, structure, and electronic properties of (.eta.-C5Me5)2V(.mu.-OC)V(CO)5. A complex with a linear vanadium-oxygen-carbon-vanadium bond
Joseph H. Osborne, Arnold L. Rheingold, and William C. Trogler
pp 6292 - 6297; DOI:
10.1021/ja00308a022
PDF
Tellurium-centered radical cations. 1. The 1,3-ditellurole radical cation by chemical, electrochemical, and photochemical oxidation
Michael R. Detty, Neil F. Haley, Raymond S. Eachus, James W. Hassett, Henry R. Luss, M. Gary Mason, John M. McKelvey, and Alex A. Wernberg
pp 6298 - 6304; DOI:
10.1021/ja00308a023
PDF
Crystal structure, magnetic properties, and single-crystal EPR spectra of a copper-nickel [CuNi]2 bis heterobinuclear compound: complementarity of the magnetic and EPR techniques
Yves Journaux, Olivier Kahn, Irene Morgenstern-Badarau, Jean Galy, Joel Jaud, Alessandro Bencini, and Dante Gatteschi
pp 6305 - 6312; DOI:
10.1021/ja00308a024
PDF
Combinational O-aryl carbamate and benzamide directed ortho metalation reactions. Synthesis of ochratoxin A and ochratoxin B
Mukund P. Sibi, S. Chattopadhyay, John W. Dankwardt, and V. Snieckus
pp 6312 - 6315; DOI:
10.1021/ja00308a025
PDF
Cycloalkylmethyl radicals. 2. Axial and equatorial cyclohexylmethyl and (4-alkylcyclohexy)methyl radicals. First determination of the conformational free energy difference of the CH2.cntdot. group
K. U. Ingold and J. C. Walton
pp 6315 - 6317; DOI:
10.1021/ja00308a026
PDF
Reactivities of rotameric ap- and sp-3,5-dimethyl-2-(9-fluorenyl)phenylnitrenes
Shigeru Murata, Tadashi Sugawara, and Hiizu Iwamura
pp 6317 - 6329; DOI:
10.1021/ja00308a027
PDF
Methyl-substituted poly(vinylnaphthalene) as a reversible singlet oxygen carrier
Isao Saito, Ryu Nagata, and Teruo Matsuura
pp 6329 - 6334; DOI:
10.1021/ja00308a028
PDF
Bonding in phosphoryl (-PO32-) and sulfuryl (-SO3-) group transfer between nitrogen nucleophiles as determined from rate constants for identity reactions
Andrew Williams
pp 6335 - 6339; DOI:
10.1021/ja00308a029
PDF
Pseudorotational mechanism for the inversion of 10-Si-5 siliconates: ligand structure and reactivity
William H. Stevenson, Scott Wilson, J. C. Martin, and William B. Farnham
pp 6340 - 6352; DOI:
10.1021/ja00308a030
PDF
Silane inversion catalyzed by weak nucleophiles: pseudorotation of 10-Si-5 intermediates
William H. Stevenson and J. C. Martin
pp 6352 - 6358; DOI:
10.1021/ja00308a031
PDF
The structure and stability of the 10-F-2 trifluoride ion, a compound of a hypervalent first row element
Paul A. Cahill, Clifford E. Dykstra, and J. C. Martin
pp 6359 - 6362; DOI:
10.1021/ja00308a032
PDF
Mechanism of hydration of simple olefins in aqueous solution. cis- and trans-Cyclooctene
Y. Chiang and A. J. Kresge
pp 6363 - 6367; DOI:
10.1021/ja00308a033
PDF
Generation, spectroscopy, and reactivity of excited 1-naphthylmethyl radicals
Linda J. Johnston and J. C. Scaiano
pp 6368 - 6372; DOI:
10.1021/ja00308a034
PDF
Synthesis of thromboxane A2
Shripad S. Bhagwat, Philip R. Hamann, and W. Clark Still
pp 6372 - 6376; DOI:
10.1021/ja00308a035
PDF
Mechanism of the reaction between cis-[PtCl2(NH3)2] and DNA in vitro
N. P. Johnson, A. M. Mazard, J. Escalier, and J. P. Macquet
pp 6376 - 6380; DOI:
10.1021/ja00308a036
PDF
Biosynthesis of riboflavin. Incorporation of multiply 13C-labeled precursors into the xylene ring
Adelbert Bacher, Quang Le Van, Paul J. Keller, and Heinz G. Floss
pp 6380 - 6385; DOI:
10.1021/ja00308a037
PDF
Gold carbonyl, Au(CO): matrix isolation ESR study
Paul H. Kasai and Paul M. Jones
pp 6385 - 6389; DOI:
10.1021/ja00308a038
PDF
Hexakis(2,4,6-triisopropylphenyl)cyclotristannane (R2Sn)3 and tetrakis(2,4,6-triisopropylphenyl)distannene (R2Sn)2, their unprecedented thermal interconversion, and the first solution spectral characterization of a distannene
Satoru Masamune and Lawrence R. Sita
pp 6390 - 6391; DOI:
10.1021/ja00308a039
PDF
NMR spectra of (C5(CH3)5)IrH2SiMe3Li(pmdeta) and (C5(CH3)5)IrH3Li(pmdeta): the first direct observation of resolved lithium-7-proton coupling
Thomas M. Gilbert and Robert G. Bergman
pp 6391 - 6393; DOI:
10.1021/ja00308a040
PDF
Do anomeric effects involving the second-row substituents, chlorine, mercapto, and phosphino exist? Stabilization energies and structural preferences
Paul v. R. Schleyer, Eluvathingal D. Jemmis, and Guenther W. Spitznagel
pp 6393 - 6394; DOI:
10.1021/ja00308a041
PDF
Two-dimensional correlation of connected NMR transitions
C. Griesinger, O. W. Soerensen, and R. R. Ernst
pp 6394 - 6396; DOI:
10.1021/ja00308a042
PDF
Palladium-promoted Diels-Alder cycloadditions to 1-phenyl-3,4-dimethylphosphole. Facile synthesis of a new class of rigid chiral bidentate phosphines: 5-phosphino-7-phosphabicyclo[2.2.1]hept-2-enes
Mark S. Holt, John H. Nelson, Phillipe Savignac, and Nathaniel W. Alcock
pp 6396 - 6397; DOI:
10.1021/ja00308a043
PDF
Silver-assisted 1,2-cleavage of penicillins. A three-step synthesis of optically active penems
Marco Alpegiani, Angelo Bedeschi, Franco Giudici, Ettore Perrone, and Giovanni Franceschi
pp 6398 - 6399; DOI:
10.1021/ja00308a044
PDF
Effects of molten salts on reactions. Nucleophilic aromatic substitution by halide ions in molten dodecyltributylphosphonium salts
Slaton E. Fry and Norbert J. Pienta
pp 6399 - 6400; DOI:
10.1021/ja00308a045
PDF
Organolithium reagent-promoted conversion of a functionalized 7-oxanorbornane to annulated fulvenes. An expedient route to 1,7-cyclohexenonorbornadienes
Tina M. Kravetz and Leo A. Paquette
pp 6400 - 6402; DOI:
10.1021/ja00308a046
PDF
The biosynthesis of aristeromycin. Elucidation of the origin of the adenine and cyclopentane rings
Ronald J. Parry and Volker Bornemann
pp 6402 - 6403; DOI:
10.1021/ja00308a047
PDF
Formation of HCr(CO)3- from the remarkable reaction of hydride ion with benzenechromium tricarbonyl. Gas-phase reactions of a novel 14-electron metal anion complex
Kelley R. Lane and Robert R. Squires
pp 6403 - 6404; DOI:
10.1021/ja00308a048
PDF
Enantioselective lactonization of sodium 4-hydroxypimelate under abiological conditions
Kaoru Fuji, Manabu Node, Shunji Terada, Makoto Murata, Hideko Nagasawa, Tooru Taga, and Katsunosuke Machida
pp 6404 - 6406; DOI:
10.1021/ja00308a049
PDF
Resonance Raman scattering from horseradish peroxidase compound I
W. Anthony Oertling and Gerald T. Babcock
pp 6406 - 6407; DOI:
10.1021/ja00308a050
PDF
Evidence on covalency and monomeric structure of phenyl silyl lithiums in ethereal solutions from scalar 29Si-6(7)Li couplings
Ulf Edlund, Tore Lejon, T. Krishnan Venkatachalam, and Erwin Buncel
pp 6408 - 6409; DOI:
10.1021/ja00308a051
PDF
Ether cleavage following insertion of carbon monoxide into the tantalum-silicon bond of (.eta.5-C5Me5)Ta(SiMe3)Cl3
John Arnold and T. Don Tilley
pp 6409 - 6410; DOI:
10.1021/ja00308a052
PDF
Tetracyclo[5.1.0.01,6.02,7]octane, a [1.1.1]propellane derivative, and a new route to the parent hydrocarbon
Klaus Semmler, Guenter Szeimies, and Johannes Belzner
pp 6410 - 6411; DOI:
10.1021/ja00308a053
PDF
Organometallic-crown reagents. Anti-Cram selectivity via R2CuLi.cntdot.crown and enhanced Cram selectivity via RLi.cntdot.crown and RMgX.cntdot.crown
Yoshinori Yamamoto and Kazuhiro Maruyama
pp 6411 - 6413; DOI:
10.1021/ja00308a054
PDF
Cadmium-113 chemical shifts of cadmium-iodide complexes in supercooled aqueous solution
Marilyn J. B. Ackerman and Joseph J. H. Ackerman
pp 6413 - 6414; DOI:
10.1021/ja00308a055
PDF
Photochemical expoxidation of olefins with molecular oxygen activated by niobium porphyrin: a functional model of cytochrome P-450
Yoshihisa Matsuda, Shuji Sakamoto, Hiroaki Koshima, and Yukito Murakami
pp 6415 - 6416; DOI:
10.1021/ja00308a056
PDF
Disilylation of acetylenes with silicon-manganese reagent
Junichi Hibino, Shigeki Nakatsukasa, Keigo Fugami, Seijiro Matsubara, Koichiro Oshima, and Hitosi Nozaki
pp 6416 - 6417; DOI:
10.1021/ja00308a057
PDF
Palladium-catalyzed annelation onto N,N-dialkylanilines by tetrahydrofuran. Stereospecific formation of heterotricyclic compounds via cation-radical intermediates
Tsutomu Sakakibara, Shoko Karasumaru, and Iwazo Kawano
pp 6417 - 6419; DOI:
10.1021/ja00308a058
PDF
Thiolate additions to bicyclomycin and analogues: a structurally novel latent Michael-acceptor system
Robert M. Williams, Kotaro Tomizawa, Robert W. Armstrong, and Jen Sen Dung
pp 6419 - 6421; DOI:
10.1021/ja00308a059
PDF
Reaction of o-phthalaldehyde with alanine and thiols: kinetics and mechanism
Osborne S. Wong, Larry A. Sternson, and Richard L. Schowen
pp 6421 - 6422; DOI:
10.1021/ja00308a060
PDF
Design of DNA-binding peptides: stabilization of .alpha.-helical structure by DNA
Lee Walters and Emil Thomas Kaiser
pp 6422 - 6424; DOI:
10.1021/ja00308a061
PDF
Reactions of coordinated ligands: coupling of two diphosphenes (P:P) at a metal center to give a coordinated phosphometallocyclopentane. Synthesis and x-ray structure of cyclic (tert-BuPP-tert-Bu)Ni(tert-BuP-tert-BuP-tert-BuP-tert-BuP): a square-planar nickel(II) geometry imparted by sterically demanding ligands
Richard A. Jones, Mark H. Seeberger, and Bruce R. Whittlesey
pp 6424 - 6426; DOI:
10.1021/ja00308a062
PDF
On the mechanism of thermal rearrangement of (bicyclo[6.1.0]nona-2,4,6-triene)tricarbonylmolybdenum
Frank J. Liotta and Barry K. Carpenter
pp 6426 - 6427; DOI:
10.1021/ja00308a063
PDF
Functionalized nitrogen atom transfer catalyzed by cytochrome P-450
Edmund W. Svastits, John H. Dawson, Ronald Breslow, and Samuel H. Gellman
pp 6427 - 6428; DOI:
10.1021/ja00308a064
PDF
Additions and Corrections - Synthesis and Characterization of a New Fe/Mo/S Cluster Containing the [Fe6Mo2S6]3+ Core. A Precursor to a Possible Structural Analouge for the Fe/Mo Site in Nitrogenase.
D. Coucouvanis, and M. G. Kanatzidis
pp 6428 - 6428; DOI:
10.1021/ja00308a600
PDF
Book Reviews

pp 6429 - 6434; DOI:
10.1021/ja00308a601
PDF

Issue 23


Nuclear magnetic resonance studies of the solution chemistry of metal complexes. 21. The complexation of zinc by glycylhistidine and alanylhistidine peptides
Dallas L. Rabenstein, Susan A. Daignault, Anvarhusein A. Isab, Alan P. Arnold, and Mohamed M. Shoukry
pp 6435 - 6439; DOI:
10.1021/ja00309a001
PDF
Exchange of two-spin order in nuclear magnetic resonance: separation of exchange and cross-relaxation processes
Gerhard Wagner, Geoffrey Bodenhausen, Norbert Mueller, Mark Rance, Ole W. Soerensen, Richard R. Ernst, and Kurt Wuethrich
pp 6440 - 6446; DOI:
10.1021/ja00309a002
PDF
Interfacial electron transfer in titanium dioxide colloids
Graham T. Brown, James R. Darwent, and Paul D. I. Fletcher
pp 6446 - 6451; DOI:
10.1021/ja00309a003
PDF
Picosecond dynamics of proton transfers
Lewis E. Manring and Kevin S. Peters
pp 6452 - 6458; DOI:
10.1021/ja00309a004
PDF
Picosecond decay dynamics of the trans-stilbene-olefin contact ion pair: electron-transfer vs. ion-pair separation
Joshua L. Goodman and Kevin S. Peters
pp 6459 - 6463; DOI:
10.1021/ja00309a005
PDF
Electron-donating ability of aliphatic and aromatic rings
G. S. Nolan, Leif J. Saethre, M. R. Siggel, T. D. Thomas, and L. Ungier
pp 6463 - 6467; DOI:
10.1021/ja00309a006
PDF
Electron spin resonance and electron spin echo modulation studies of N,N,N',N'-tetramethylbenzidine photoionization in frozen micellar solutions: structural effect of 1-butanol addition to sodium and tetramethylammonium dodecylsulfate and dodecyltrimethylammonium chloride micelles
Ewa Szajdzinska-Pietek, Rene Maldonado, Larry Kevan, and Richard R. M. Jones
pp 6467 - 6470; DOI:
10.1021/ja00309a007
PDF
Electron spin resonance of Re2(.mu.-H)2(CO)8-.cntdot. and Re2(.mu.-H)2(CO)6(.mu.-ddpm)-.cntdot. (dppm = (Ph2P)2CH2). An indication of large 5d-6p mixing in the odd-electron orbital
Takayoshi Sowa, Takashi Kawamura, Tokio Yamabe, and Teijiro Yonezawa
pp 6471 - 6475; DOI:
10.1021/ja00309a008
PDF
Reaction mixture analysis by fast atom bombardment mass spectrometry: palladium-mediated reactions of organomercurials with glycals
Henry T. Kalinoski, Uli Hacksell, Douglas F. Barofsky, Elisabeth Barofsky, and G. Doyle Daves
pp 6476 - 6482; DOI:
10.1021/ja00309a009
PDF
Theoretical studies of lithium fluoride, lithium hydroxide, and lithium amide tetramers
Anne Marie Sapse, Krishnan Raghavachari, Paul von Rague Schleyer, and Elmar Kaufmann
pp 6483 - 6486; DOI:
10.1021/ja00309a010
PDF
Theoretical prediction of vibrational spectra. 2. Force field, spectroscopically refined geometry, and reassignment of the vibrational spectrum of naphthalene
Harrell Sellers, Peter Pulay, and James E. Boggs
pp 6487 - 6494; DOI:
10.1021/ja00309a011
PDF
Phosphorus-nitrogen multiple bonds. A theoretical investigation of structure and bonding in (NH)2PNH2, (NH2)2PN, and the (cyclic) dimer P2N6H8
Reinhart Ahlrichs and Heinz Schiffer
pp 6494 - 6498; DOI:
10.1021/ja00309a012
PDF
Multielement NMR and ESR study of solutions of the alkali metals sodium to cesium in N,N-diethylacetamide, N,N-dipropylacetamide, N,N-dimethylpropanamide, and tetramethylurea
Dolores M. Holton, Peter P. Edwards, David C. Johnson, Catherine J. Page, William McFarlane, and Brian Wood
pp 6499 - 6504; DOI:
10.1021/ja00309a013
PDF
Structural differentiation of carbon monoxide and oxygen binding to iron porphyrins: polar pocket effects
T. G. Traylor, Noboru Koga, and Larrie A. Deardurff
pp 6504 - 6510; DOI:
10.1021/ja00309a014
PDF
A complex containing a nickel-oxygen unit at the center of a porphyrin. The x-ray crystal and molecular structure of the nickel(II) complex of octaethylporphyrin N-oxide dianion
Alan L. Balch, Yee Wai Chan, and Marilyn M. Olmstead
pp 6510 - 6514; DOI:
10.1021/ja00309a015
PDF
Isolation and characterization of acetyl hypofluorite
Evan H. Appelman, Marshall H. Mendelsohn, and Hyunyong Kim
pp 6515 - 6518; DOI:
10.1021/ja00309a016
PDF
Effect of thiolate vs. nitrogen-base ligands on oxygen stretching frequencies of (oxytetraphenylporphyrinato)cobalt
Kazuo Nakamoto and Hiroki Oshio
pp 6518 - 6521; DOI:
10.1021/ja00309a017
PDF
Conformation-reactivity relationships for the organotransition metal complexes (.eta.5-C5H5)Fe(CO)(PPh3)R and (.eta.5-C5H5)Re(NO)(PPh3)R (R = alkyl and aryl)
Jeffrey I. Seeman and Stephen G. Davies
pp 6522 - 6531; DOI:
10.1021/ja00309a018
PDF
Stereoselective oxidative addition of silanes and hydrogen halides to the iridium(I) cis phosphine complexes IrX(CO)(dppe) (X = Br, CN; dppe = 1,2-bis(diphenylphosphino)ethane)
Curtis E. Johnson and Richard Eisenberg
pp 6531 - 6540; DOI:
10.1021/ja00309a019
PDF
Ferric ion sequestering agents. 14. 1-Hydroxy-2(1H)-pyridinone complexes: properties and structure of a novel iron-iron dimer
Robert C. Scarrow, David L. White, and Kenneth N. Raymond
pp 6540 - 6546; DOI:
10.1021/ja00309a020
PDF
Cyclynes. Part 4. Pericyclynes of the order [5], [6], [7], and [8]. Simple convergent syntheses and chemical reactions of the first homoconjugated cyclic polyacetylenes
Lawrence T. Scott, Gary J. DeCicco, James L. Hyun, and Gerd Reinhardt
pp 6546 - 6555; DOI:
10.1021/ja00309a021
PDF
Cyclynes. Part 5. Pericyclynes: "exploded cycloalkanes" with unusual orbital interactions and conformational properties. MM2 and STO-3G calculations, x-ray crystal structures, photoelectron spectra, and electron transmission spectra
K. N. Houk, Lawrence T. Scott, Nelson G. Rondan, David C. Spellmeyer, Gerd Reinhardt, James L. Hyun, Gary J. DeCicco, Robert Weiss, Marie H. M. Chen, and et al.
pp 6556 - 6562; DOI:
10.1021/ja00309a022
PDF
Nucleophilic addition to olefins. 14. Kinetics of hydrolysis of benzylidene-1,3-indandione
Claude F. Bernasconi, Alan Laibelman, and Janie L. Zitomer
pp 6563 - 6570; DOI:
10.1021/ja00309a023
PDF
Nucleophilic addition to olefins. 15. Kinetics of the reaction of 1,3-indandione anion with benzylidene-1,3-indandione
Claude F. Bernasconi, Alan Laibelman, and Janie L. Zitomer
pp 6570 - 6575; DOI:
10.1021/ja00309a024
PDF
Occam's razor revisited. Chain carriers in the N-bromosuccinimide bromination of neopentane-methylene chloride
Dennis D. Tanner, Darwin W. Reed, Seet L. Tan, Christian P. Meintzer, Cheves Walling, and Alan Sopchik
pp 6576 - 6584; DOI:
10.1021/ja00309a025
PDF
Reexamination of the reaction of a "graded set" of radicals with N-bromosuccinimide: a kinetic argument concerning the .pi., and .omega. states of succinimidyl
Dennis D. Tanner and Christian P. Meintzer
pp 6584 - 6589; DOI:
10.1021/ja00309a026
PDF
The electronic structure of selenoformaldehyde
Scott Collins, Thomas G. Back, and Arvi Rauk
pp 6589 - 6592; DOI:
10.1021/ja00309a027
PDF
Electronic control of stereoselectivity. 30. X-ray analysis of the effect of apical substitution on the three-dimensional features of isodicyclopentafulvenes. Experimental demonstration of minimal bridgehead C-H angle deformation accompanying substantial hybridization change at the apical center
Judith C. Gallucci, Tina M. Kravetz, Kenneth E. Green, and Leo A. Paquette
pp 6592 - 6598; DOI:
10.1021/ja00309a028
PDF
Electronic control of stereoselectivity. 31. .pi.-Facial course of Diels-Alder cycloadditions to 10-isopropylideneisodicyclopentadiene
Leo A. Paquette, Tina M. Kravetz, and Leh Yeh Hsu
pp 6598 - 6603; DOI:
10.1021/ja00309a029
PDF
Photocyclization of 2-vinylbiphenyls and related compounds under triplet sensitization: an adiabatic reaction on the triplet surface
S. Lazare, R. Lapouyade, and R. Bonneau
pp 6604 - 6609; DOI:
10.1021/ja00309a030
PDF
Photochemistry of polyenes. 23. Application of the H.T.-n mechanism of photoisomerization to the photocycles of bacteriorhodopsin. A model study
Robert S. H. Liu, Dennis Mead, and Alfred E. Asato
pp 6609 - 6614; DOI:
10.1021/ja00309a031
PDF
Photogeneration of triphenyl C3 radical cations: deprotonation and nucleophilic addition as competitive pathways
Michael Klett and Richard P. Johnson
pp 6615 - 6620; DOI:
10.1021/ja00309a032
PDF
Cyclophane series. Part 24. [2.2](1,4)Phenanthrenoparacyclophane: synthesis and two-dimensional proton and carbon-13 NMR study
Henning Hopf, Cornelia Mlynek, Sayed El-Tamany, and Ludger Ernst
pp 6620 - 6627; DOI:
10.1021/ja00309a033
PDF
Permanganate ion oxidations. 15. Additional evidence for formation of soluble (colloidal) manganese dioxide during the permanganate ion oxidation of carbon-carbon double bonds in phosphate-buffered solutions
Fillmore Freeman and John C. Kappos
pp 6628 - 6633; DOI:
10.1021/ja00309a034
PDF
Dynamics of the cleavage of Ellman's reagent in surfactant vesicles
Robert A. Moss and Ronald P. Schreck
pp 6634 - 6639; DOI:
10.1021/ja00309a035
PDF
Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes
Eiichi Negishi, David E. Van Horn, and Tadao Yoshida
pp 6639 - 6647; DOI:
10.1021/ja00309a036
PDF
A new approach to polypropionates: routes to subunits of monensin and tirandamycin
Samuel Danishefsky and Daniel F. Harvey
pp 6647 - 6652; DOI:
10.1021/ja00309a037
PDF
The role of the chlorine substituents in the antibiotic vancomycin: preparation and characterization of mono- and didechlorovancomycin
Constance M. Harris, Rajamoorthi Kannan, Hana Kopecka, and Thomas M. Harris
pp 6652 - 6658; DOI:
10.1021/ja00309a038
PDF
12-, 15-, and 18-Membered-ring nitrogen-pivot lariat ethers: syntheses, properties, and sodium and ammonium cation binding properties
Rose Ann Schultz, Banita D. White, Dennis M. Dishong, Kristin A. Arnold, and George W. Gokel
pp 6659 - 6668; DOI:
10.1021/ja00309a039
PDF
Methyl transfers. 10. The Marcus equation application to soft nucleophiles
Edward S. Lewis, Mark L. McLaughlin, and Thomas A. Douglas
pp 6668 - 6673; DOI:
10.1021/ja00309a040
PDF
Heavy-atom kinetic isotope effects in the acid-catalyzed rearrangement of N-2-naphthyl-N'-phenylhydrazine. Rearrangement is shown to be a concerted process
Henry J. Shine, Lidia Kupczyk-Subotkowska, and Witold Subotkowski
pp 6674 - 6678; DOI:
10.1021/ja00309a041
PDF
Synthesis and diatropicity of a phenanthrene annelated trans-dimethyldihydropyrene: a novel molecule to indicate the high .pi.-bond order of the 9,10 bond of phenanthrene
Yee Hing Lai
pp 6678 - 6683; DOI:
10.1021/ja00309a042
PDF
Ultrahigh resolution NMR. 2. Measurements of secondary isotope effects on chemical shifts, long-range carbon-carbon scalar coupling constants, and carbon-13 spin-spin relaxation times directly from line widths
Adam Allerhand and Michael Dohrenwend
pp 6684 - 6688; DOI:
10.1021/ja00309a043
PDF
Theoretical studies on pteridines. 3. Geometries, tautomer and ionization energies, and rearrangement and reduction mechanisms of the quinonoid dihydropterin substrates of dihydropteridine reductase
Jill E. Gready
pp 6689 - 6695; DOI:
10.1021/ja00309a044
PDF
Cartesian correlation times for NMR AX2 spin systems
Michael M. Fuson, Mark S. Brown, David M. Grant, and Glenn T. Evans
pp 6695 - 6698; DOI:
10.1021/ja00309a045
PDF
Rotational dynamics of flexible alkanes. An NMR coupled relaxation and a Brownian dynamics study
Mark S. Brown, David M. Grant, W. J. Horton, Charles L. Mayne, and Glenn T. Evans
pp 6698 - 6707; DOI:
10.1021/ja00309a046
PDF
Spontaneous fragmentation of cationic polystyrene chains
A. Grey Craig and Peter J. Derrick
pp 6707 - 6708; DOI:
10.1021/ja00309a047
PDF
Photoinduced .alpha.-hydrogen elimination of an iridium(III) dialkyl: formation of an isolable iridium methylidene
Michael D. Fryzuk, Patricia A. MacNeil, and Steven J. Rettig
pp 6708 - 6710; DOI:
10.1021/ja00309a048
PDF
Photoalkylation of dicyanoarenes with alkyltriphenylborate salts
J. Y. Lan and Gary B. Schuster
pp 6710 - 6711; DOI:
10.1021/ja00309a049
PDF
Adsorption and reactivity of acetylene on a copper(110) surface
Neil R. Avery
pp 6711 - 6712; DOI:
10.1021/ja00309a050
PDF
Change in rate-limiting step in proton removal from an intramolecularly hydrogen-bonded acid and the rate of opening and closing of a hydrogen bond
N. E. Briffett, Frank Hibbert, and R. J. Sellens
pp 6712 - 6714; DOI:
10.1021/ja00309a051
PDF
Functionalized heteropolytungstate anions possessing a modified Dawson structure: small, individually distinguishable labels for conventional transmission electron microscopy
John F. W. Keana, Marc D. Ogan, Yixin Lu, Michael Beer, and J. Varkey
pp 6714 - 6715; DOI:
10.1021/ja00309a052
PDF
Synthesis, structure, and reactions of a .eta.5-CpCo(.eta.4-bisketene) complex
Charles F. Jewell, Lanny S. Liebeskind, and Michael Williamson
pp 6715 - 6716; DOI:
10.1021/ja00309a053
PDF
Resonance Raman spectroscopy of metalloproteins under extreme conditions: cryogenic diamond-cell study of azurin
Stephen F. Agnew, Jon R. Schoonover, Basil I. Swanson, and William H. Woodruff
pp 6716 - 6718; DOI:
10.1021/ja00309a054
PDF
Long-lived reactive excited states of zero-valent phosphine, phosphite, and arsine complexes of nickel, palladium and platinum
Jonathan V. Caspar
pp 6718 - 6719; DOI:
10.1021/ja00309a055
PDF
Synthesis and characterization of the first transition metal complex of 1,2:5,6:9,10-tribenzocyclododeca-1,5,9-triene-3,7,11-triyne
Joseph D. Ferrara, Claire Tessier-Youngs, and Wiley J. Youngs
pp 6719 - 6721; DOI:
10.1021/ja00309a056
PDF
The stereochemical course of phosphoryl transfer reactions of P1,P1-disubstituted pyrophosphosphates in aprotic solvents - a model for the enzyme catalyzed dissociative phosphoryl transfer
Paul M. Cullis and Andrew Rous
pp 6721 - 6723; DOI:
10.1021/ja00309a057
PDF
Direct observation of a photochemically produced dienol. Evidence for a noncatalyzed reketonization pathway unavailable to simple enols
Randy M. Duhaime and Alan C. Weedon
pp 6723 - 6724; DOI:
10.1021/ja00309a058
PDF
Nanosecond flash photolysis studies of intersystem crossing rate constants in biradicals: structural effects brought about by spin-orbit coupling
Matthew B. Zimmt, Charles Doubleday, Ian R. Gould, and Nicholas J. Turro
pp 6724 - 6726; DOI:
10.1021/ja00309a059
PDF
Magnetic field effect on the intersystem crossing rate constants of biradicals measured by nanosecond transient UV absorption
Matthew B. Zimmt, Charles Dougleday, and Nicholas J. Turro
pp 6726 - 6727; DOI:
10.1021/ja00309a060
PDF
Structures of binuclear and tetranuclear iron(III) complexes as models for ferritin core formation
Bruce P. Murch, Paul D. Boyle, and Lawrence Que
pp 6728 - 6729; DOI:
10.1021/ja00309a061
PDF
[[(2-Tetrahydrofuranyl)- and (2-tetrahydropyranyl)thio]methyl]lithium: methanethiol carbanion equivalents
Eric Block and Mohammad Aslam
pp 6729 - 6731; DOI:
10.1021/ja00309a062
PDF
Chemistry of sulfines. 12. Unusually facile thio-Claisen rearrangement of 1-alkenyl 2-alkenyl sulfoxides: a new sulfine synthesis
Eric Block and Saleem Ahmad
pp 6731 - 6732; DOI:
10.1021/ja00309a063
PDF
Dicopper(I) tropocoronands: synthesis, x-ray crystal structure, and spectral properties of neutral binuclear copper(I) complexes bridged by symmetrically substituted alkynes
Gilberto M. Villacorte, Dan Gibson, Ian D. Williams, and Stephen J. Lippard
pp 6732 - 6734; DOI:
10.1021/ja00309a064
PDF
The Mo3S44+ aquo ion
F. Albert Cotton, Zvi Dori, Rosa Llusar, and Willi Schwotzer
pp 6734 - 6735; DOI:
10.1021/ja00309a065
PDF
The cuboidal Mo4S46+ aquo ion and its derivatives
F. Albert Cotton, Michael P. Diebold, Zvi Dori, Rosa Llusar, and Willi Schwotzer
pp 6735 - 6736; DOI:
10.1021/ja00309a066
PDF
Synthetic receptors: size and shape recognition within a molecular cleft
Julius Rebek, Ben Askew, Nafisa Islam, Mary Killoran, David Nemeth, and Raymond Wolak
pp 6736 - 6738; DOI:
10.1021/ja00309a067
PDF
Molecular recognition: three-point binding leads to a selective receptor for aromatic amino acids
Julius Rebek and David Nemeth
pp 6738 - 6739; DOI:
10.1021/ja00309a068
PDF
Photoassisted polymerization of terminal alkynes by W(CO)6 involving catalyst generation by an alkyne to vinylidene ligand rearrangement
Shayne J. Landon, Peter M. Shulman, and Gregory L. Geoffroy
pp 6739 - 6740; DOI:
10.1021/ja00309a069
PDF
Anti-Michael carbolithiation of silicon and phenyl-substituted .alpha.,.beta.-unsaturated secondary amides
G. W. Klumpp, A. J. C. Mierop, J. J. Vrielink, A. Brugman, and M. Schakel
pp 6740 - 6742; DOI:
10.1021/ja00309a070
PDF
Cyclization of 2-(3-butenyl)bromobenzene via the aryllithium derivative
Gerald A. Ross, Miles D. Koppang, Duane E. Bartak, and Neil F. Woolsey
pp 6742 - 6743; DOI:
10.1021/ja00309a071
PDF
Mass spectrometry of microscale chemical reaction products produced at the surface of organic solids
B. T. Chait and F. H. Field
pp 6743 - 6744; DOI:
10.1021/ja00309a072
PDF
Additions and Corrections - Bare Tetranuclear Transition-Metal Cluster Ions in the Gas Phase. Reactivity of Sc4+ with Small Molecules
M. B. Wise, D. B. Jacobson, and B. S. Freiser
pp 6744 - 6744; DOI:
10.1021/ja00309a600
PDF
Additions and Corrections - Synthesis and Structures of (C5H5)2Mo2FexTe2(CO)7(x=1,2). Cluster Assembly Mechanisms and the Role of the Tellurium
Leonard E. Bogan, Jr., Thomas B. Rauchfuss, and Arnold L. Rheingold
pp 6744 - 6744; DOI:
10.1021/ja00309a601
PDF
Additions and Corrections - Reactions of Cyclic Cation Radicals with Nucleophiles: A New Route to Distonic Ions.
Thomas M. Sack, Ronald L. Cerny, and Michael L. Gross
pp 6744 - 6744; DOI:
10.1021/ja00309a602
PDF
Book Reviews

pp 6745 - 6748; DOI:
10.1021/ja00309a603
PDF

Issue 24


Low-temperature carbon-13 magnetic resonance in solids. 5. Chemical shielding anisotropy of the 13CH2 group
Julio C. Facelli, Anita M. Orendt, Alvin J. Beeler, Mark S. Solum, Gisbert Depke, Klaus D. Malsch, John W. Downing, Parvathi S. Murthy, David M. Grant, and Josef Michl
pp 6749 - 6754; DOI:
10.1021/ja00310a001
PDF
Paramagnetic carbon-13 and phosphorus-31 NMR relaxation studies of the stability, structure, and dynamics of complexes in the glycine/manganese(II)/adenosine 5'-triphosphate system
Jens J. Led
pp 6755 - 6765; DOI:
10.1021/ja00310a002
PDF
Tandem mass spectrometry methodology for the sequence determination of cyclic peptides
Klaus Eckart, Helmut Schwarz, Kenneth B. Tomer, and Michael L. Gross
pp 6765 - 6769; DOI:
10.1021/ja00310a003
PDF
Prediction of silicon-29 nuclear magnetic resonance chemical shifts using a group electronegativity approach: applications to silicate and aluminosilicate structures
Nathan Janes and Eric Oldfield
pp 6769 - 6775; DOI:
10.1021/ja00310a004
PDF
Resonance Raman spectra of oxyen adducts of cobalt porphyrins. Enhancement of solvent and solute bands via resonance vibrational coupling
James R. Kincaid, Leonard M. Proniewicz, Krzysztof Bajdor, Alan Bruha, and Kazuo Nakamoto
pp 6775 - 6781; DOI:
10.1021/ja00310a005
PDF
Cycloreversion induced by charge-transfer excitation of electron donor-acceptor complexes. Wavelength-dependent photochemistry of dianthracene
J. M. Masnovi and J. K. Kochi
pp 6781 - 6788; DOI:
10.1021/ja00310a006
PDF
Toward a theory of chemical reactivity based on the charge density
Richard F. W. Bader and Preston J MacDougall
pp 6788 - 6795; DOI:
10.1021/ja00310a007
PDF
The ring opening of gas-phase cyclopropane radical cations
Thomas M. Sack, David L. Miller, and Michael L. Gross
pp 6795 - 6800; DOI:
10.1021/ja00310a008
PDF
Absolute electronegativity and absolute hardness of Lewis acids and bases
Ralph G. Pearson
pp 6801 - 6806; DOI:
10.1021/ja00310a009
PDF
.beta.-Diketonate cobalt(3+) chelates. Stereoisomerism and electrochemical studies of complexes with two different ligands
Jacob Saar, Donald E. Smith, and Michael Cais
pp 6807 - 6811; DOI:
10.1021/ja00310a010
PDF
On the concept of local hardness in chemistry
Max Berkowitz, Swapan K. Ghosh, and Robert G. Parr
pp 6811 - 6814; DOI:
10.1021/ja00310a011
PDF
Radical cations of fulvenes: planar or twisted?
Christopher J. Abelt and Heinz D. Roth
pp 6814 - 6818; DOI:
10.1021/ja00310a012
PDF
Reaction of 6-yl radicals of uracil, thymine, and cytosine and their nucleosides and nucleotides with nitrobenzenes via addition to give nitroxide radicals. Hydroxide ion-catalyzed nitroxide heterolysis
S. Steenken and V. Jagannadham
pp 6818 - 6826; DOI:
10.1021/ja00310a013
PDF
Conformation of mono- and dicarboxylic acids adsorbed on silver surfaces
M. Moskovits and J. S. Suh
pp 6826 - 6829; DOI:
10.1021/ja00310a014
PDF
Haptotropic rearrangements in polyene-MLn complexes. 3. Polyene-ML2 systems
Jerome Silvestre and Thomas A. Albright
pp 6829 - 6841; DOI:
10.1021/ja00310a015
PDF
The geometries of the high-energy conformers of some acyclic 1,3-dienes
Michael E. Squillacote, Thomas C. Semple, and Philip W. Mui
pp 6842 - 6846; DOI:
10.1021/ja00310a016
PDF
Polypeptide-metal cluster connectivities in metallothionein 2 by novel proton-cadmium-113 heteronuclear two-dimensional NMR experiments
Michael H. Frey, Gerhard Wagner, Milan Vasak, Ole W. Soerensen, David Neuhaus, Erich Woergoetter, Jeremias H. R. Kaegi, Richard R. Ernst, and Kurt Wuethrich
pp 6847 - 6851; DOI:
10.1021/ja00310a017
PDF
Superdegenerate electronic energy levels in extended structures
Timothy Hughbanks
pp 6851 - 6859; DOI:
10.1021/ja00310a018
PDF
Gas-phase isotope fractionation factor for proton-bound dimers of methoxide anions
David A. Weil and David A. Dixon
pp 6859 - 6865; DOI:
10.1021/ja00310a019
PDF
Reversible formation and disruption of micelles by control of the redox state of the head group
T. Saji, K. Hoshino, and S. Aoyagui
pp 6865 - 6868; DOI:
10.1021/ja00310a020
PDF
Dependence of deuterium spin-lattice relaxation rates of multilamellar phospholipid dispersions on orientational order
Gerald D. Williams, James M. Beach, Steven W. Dodd, and Michael F. Brown
pp 6868 - 6873; DOI:
10.1021/ja00310a021
PDF
Electronic structure and thermal stability of thiepins. Photoelectron spectroscopic investigations
Rolf Gleiter, Gerhard Krennrich, Dieter Cremer, Kagetoshi Yamamoto, and Ichiro Murata
pp 6874 - 6879; DOI:
10.1021/ja00310a022
PDF
Rare examples of structurally characterized five-coordinate organocobalt complexes. Novel dynamic NMR evidence for synergistic enhancement of cis and trans effects in B12 models
Luigi G. Marzilli, Michael F. Summers, Nevenka Bresciani-Pahor, Ennio Zangrando, Jean Pierre Charland, and Lucio Randaccio
pp 6880 - 6888; DOI:
10.1021/ja00310a023
PDF
Control of the photochemical reactivity of coordination compounds by formation of supramolecular structures: the case of the hexacyanocobaltate(III) anion associated with polyammonium macrocyclic receptors
M. F. Manfrin, L. Moggi, V. Castelvetro, Vincenzo Balzani, M. W. Hosseini, and J. M. Lehn
pp 6888 - 6892; DOI:
10.1021/ja00310a024
PDF
Dual stereoselectivity in the nucleophilic attack on (.pi.-allyl)palladium complexes
Jan E. Baeckvall, Ruth E. Nordberg, and Didier Wilhelm
pp 6892 - 6898; DOI:
10.1021/ja00310a025
PDF
Stereochemistry at iron during carbonyl insertion reactions of FeMeI(CO)2(PMe3)2
Steven C. Wright and Michael C. Baird
pp 6899 - 6902; DOI:
10.1021/ja00310a026
PDF
Binucleating tetrapyrrole macrocycles
Francis V. Acholla, Fusao Takusagawa, and Kristin Bowman Mertes
pp 6902 - 6908; DOI:
10.1021/ja00310a027
PDF
Experimental and theoretical studies of dinuclear gold(I) and gold(II) phosphorus ylide complexes. Oxidative addition, halide exchange, and structural properties including the crystal and molecular structures of [Au(CH2)2PPh2]2 and [Au(CH2)2PPh2]2(CH3)Br
John D. Basil, H. H. Murray, John P. Fackler, J. Tocher, A. M. Mazany, B. Trzcinska-Bancroft, H. Knachel, D. Dudis, T. J. Delord, and D. Marler
pp 6908 - 6915; DOI:
10.1021/ja00310a028
PDF
Metal-spine conductivity in a partially oxidized metallomacrocycle: (phthalocyaninato)cobalt iodide
Jens Martinsen, Judith L. Stanton, Richard L. Greene, Jiro Tanaka, Brian M. Hoffman, and James A. Ibers
pp 6915 - 6920; DOI:
10.1021/ja00310a029
PDF
Coordination chemistry of microbial iron transport compounds. 34. The pH-dependent reduction of ferric enterobactin probed by electrochemical methods and its implications for microbial iron transport
Chi Woo Lee, David J. Ecker, and Kenneth N. Raymond
pp 6920 - 6923; DOI:
10.1021/ja00310a030
PDF
Preparation and conformations of the medium-ring dimethylphosphazenes (NPMe2)9-12: Crystal and molecular structures of octadecamethylcyclononaphosphazene, eicosamethylcyclodecaphosphazene, docosamethylcycloundecaphosphazene, and tetracosamethylcyclododecaphosphazene
Richard T. Oakley, Steven J. Rettig, Norman L. Paddock, and James Trotter
pp 6923 - 6936; DOI:
10.1021/ja00310a031
PDF
Complexation of tin(II) chloride by a novel macrocycle containing rhodium and nitrogen binding sites. The preparation and x-ray crystal structure of Rh2Sn2(CO)2Cl6[.mu.-2,6-bis(diphenylphosphino)pyridine]2
Alan L. Balch, Hakon Hope, and Fred E. Wood
pp 6936 - 6941; DOI:
10.1021/ja00310a032
PDF
Mechanistic polyoxoanion chemistry: intramolecular rearrangements of the .alpha.-Mo8O264-, C6H5AsMo7O254-, and (C6H5As)2Mo6O244- anions
W. G. Klemperer, C. Schwartz, and D. A. Wright
pp 6941 - 6950; DOI:
10.1021/ja00310a033
PDF
X-ray crystal structure and conformational analysis of tetradecamethylcycloheptasilane, (Me2Si)7
Fathieh Shafiee, James R. Damewood, Kenneth J. Haller, and Robert West
pp 6950 - 6956; DOI:
10.1021/ja00310a034
PDF
Mixed olefin-alkyne complexes of molybdenum(II) and tungsten (II) dithiocarbamates
J. R. Morrow, T. L. Tonker, J. L. Templeton, and W. R. Kenan
pp 6956 - 6963; DOI:
10.1021/ja00310a035
PDF
Internal molecular motion of triphenylphosphine oxide: analysis of atomic displacement parameters for orthorhombic and monoclinic crystal modifications at 100 and 150 K
Carolyn P. Brock and W. Bernd Schweizer
pp 6964 - 6970; DOI:
10.1021/ja00310a036
PDF
Carbon acidity. 66. Equilibrium ion pair acidities of substituted diphenylmethanes in cyclohexylamine
Andrew Streitwieser, Erich A. Vorpagel, and Chia Chung Chen
pp 6970 - 6975; DOI:
10.1021/ja00310a037
PDF
Carbon acidity. 67. The indicator scale of cesium ion pairs in tetrahydrofuran
Daniel A. Bors, Michael J. Kaufman, and Andrew Streitwieser
pp 6975 - 6982; DOI:
10.1021/ja00310a038
PDF
Carbon acidity. 68. Hydrogen isotope exchange kinetics of 1,3-diphenylindene, cyclopentadiene, 1,4-diphenylcyclopentadiene, and 2,7-di-tert-butylfluorene
Andrew Streitwieser, Michael J. Kaufman, Daniel A. Bors, Joseph R. Murdoch, Craig A. MacArthur, James T. Murphy, and Celia C. Shen
pp 6983 - 6986; DOI:
10.1021/ja00310a039
PDF
Kinetics of oxidation of 3-[2-(1,4-dihydroxyphenyl)thio]-1,4,5-trimethyl-1,2,4-triazolium by 1,4-benzoquinones: evidence for a hydride-transfer pathway
M. P. Youngblood
pp 6987 - 6992; DOI:
10.1021/ja00310a040
PDF
Analytical optical resolution of bromochlorofluoromethane by enantioselective inclusion into a tailor-made cryptophane and determination of its maximum rotation
Josette Canceill, Liliane Lacombe, and Andre Collet
pp 6993 - 6996; DOI:
10.1021/ja00310a041
PDF
On the optical activity of bromochlorofluoromethane
Samuel H. Wilen, Kathryn A. Bunding, Concetta M. Kasheres, and Milton J. Wieder
pp 6997 - 6998; DOI:
10.1021/ja00310a042
PDF
Enzyme-catalyzed organic synthesis: a comparison of strategies for in situ regeneration of NAD from NADH
Linda G. Lee and George M. Whitesides
pp 6999 - 7008; DOI:
10.1021/ja00310a043
PDF
Glycerol kinase: substrate specificity
Debbie C. Crans and George M. Whitesides
pp 7008 - 7018; DOI:
10.1021/ja00310a044
PDF
Glycerol kinase: synthesis of dihydroxyacetone phosphate, sn-glycerol-3-phosphate, and chiral analogs
Debbie C. Crans and George M. Whitesides
pp 7019 - 7027; DOI:
10.1021/ja00310a045
PDF
Proton NMR analyses, shielding mechanisms, coupling constants, and conformations in steroids bearing halogen, hydroxy, and oxo groups and double bonds
H. J. Schneider, U. Buchheit, N. Becker, G. Schmidt, and U. Siehl
pp 7027 - 7039; DOI:
10.1021/ja00310a046
PDF
Molecular organization in starches: a carbon 13 CP/MAS NMR study
Michael J. Gidley and Stephen M. Bociek
pp 7040 - 7044; DOI:
10.1021/ja00310a047
PDF
Photochemistry of ketones in solution. Part 75. Photodecarbonylation of cis- and trans-2,7-dimethyl-3,5-cycloheptadienones: applicability of orbital symmetry theory to photochemical cheletropic fragmentations
David I. Schuster, Li Wang, and James M. Van der Veen
pp 7045 - 7053; DOI:
10.1021/ja00310a048
PDF
Autoxidation of biological molecules. 4. Maximizing the antioxidant activity of phenols
G. W. Burton, T. Doba, E. Gabe, L. Hughes, F. L. Lee, L. Prasad, and Keith U. Ingold
pp 7053 - 7065; DOI:
10.1021/ja00310a049
PDF
The formation of an enantiomerically pure product of free radical coupling. The chemistry of diphenylcarbene in polycrystalline S-(+)-2-butanol
Jose Zayas and Matthew S. Platz
pp 7065 - 7069; DOI:
10.1021/ja00310a050
PDF
On the application of the steady state to kinetic isotope effects
Piotr Paneth
pp 7070 - 7071; DOI:
10.1021/ja00310a051
PDF
Resolution of racemic mixtures via lipase catalysis in organic solvents
Gerald Kirchner, Mark P. Scollar, and Alexander M. Klibanov
pp 7072 - 7076; DOI:
10.1021/ja00310a052
PDF
Photosensitized isomerization of norbornadiene to quadricyclane with (arylphosphine)copper(I) halides
Dennis J. Fife, William M. Moore, and Karen W. Morse
pp 7077 - 7083; DOI:
10.1021/ja00310a053
PDF
New hypervalent phosphorus compounds: neutral and cationic 10-P-5 species from O:P(OCH2CH2)3N and Lewis acids
L. E. Carpenter and J. G. Verkade
pp 7084 - 7087; DOI:
10.1021/ja00310a054
PDF
The use of polymer-bound oximes for the synthesis of large peptides usable in segment condensation: synthesis of a 44 amino acid amphiphilic peptide model of apolipoprotein A-1
Satoe H. Nakagawa, Herman S. H. Lau, F. J. Kezdy, and E. T. Kaiser
pp 7087 - 7092; DOI:
10.1021/ja00310a055
PDF
Substituent effects on hydrogen abstraction by phenyl ketone triplets
Peter J. Wagner, Royal J. Truman, and J. C. Scaiano
pp 7093 - 7097; DOI:
10.1021/ja00310a056
PDF
Electrophilic reactions at single bonds. 20. Selective monohalogenation of methane over supported acidic or platinum metal catalysts and hydrolysis of methyl halides over .gamma.-alumina-supported metal oxide/hydroxide catalysts. A feasible path for the oxidative conversion of methane into methyl alcohol/dimethyl ether
George A. Olah, Balaram Gupta, Jeff D. Felberg, Wai M. Ip, Altaf Husain, Richard Karpeles, Koop Lammertsma, Ashok K. Melhotra, Nirupam J. Trivedi, and et al.
pp 7097 - 7105; DOI:
10.1021/ja00310a057
PDF
Conversion of serine to stereochemically pure .beta.-substituted .alpha.-amino acids via .beta.-lactones
Lee D. Arnold, Thomas H. Kalantar, and John C. Vederas
pp 7105 - 7109; DOI:
10.1021/ja00310a058
PDF
Role of agostic interaction in .beta.-elimination of palladium and nickel complexes. An ab initio MO study
Nobuaki Koga, Shigeru Obara, Kazuo Kitaura, and Keiji Morokuma
pp 7109 - 7116; DOI:
10.1021/ja00310a059
PDF
Is hydrocyanic acid a normal acid? Proton transfer from hydrocyanic acid to bases and small inhibition of proton exchange by acid
Rodney A. Bednar and William P. Jencks
pp 7117 - 7126; DOI:
10.1021/ja00310a060
PDF
Direct proton transfer between hydrocyanic acid and nitrogen and oxygen bases
Rodney A. Bednar and William P. Jencks
pp 7126 - 7134; DOI:
10.1021/ja00310a061
PDF
Intramolecular proton transfer through water in diamine monocations
Rodney A. Bednar and William P. Jencks
pp 7135 - 7138; DOI:
10.1021/ja00310a062
PDF
Nuclear magnetic response and conformational energy characterization of repeat peptides of elastin: the cyclohexadecapeptide, cyclo-(L-Val1-L-Pro2-Gly3-Gly4)4
M. A. Khaled, K. U. Prasad, C. M. Venkatachalam, and D. W. Urry
pp 7139 - 7145; DOI:
10.1021/ja00310a063
PDF
Influence of acetate buffers and metal ions on ketonization rates of enolpyruvate: a further test of the Marcus function
Barbara A. Miller and Daniel L. Leussing
pp 7146 - 7153; DOI:
10.1021/ja00310a064
PDF
Conformation and dimerization of actinomycin-related peptide lactones in solution and in the solid state
Anthony B. Mauger, Oswald A. Stuart, James A. Ferretti, and James V. Silverton
pp 7154 - 7163; DOI:
10.1021/ja00310a065
PDF
Intramolecular kinetic deuterium isotope effects on microsomal hydroxylation and chemical chlorination of toluene-.alpha.-d1 and toluene-.alpha.,.alpha.-d2
Robert P. Hanzlik, Kerstin Hogberg, Joseph B. Moon, and Charles M. Judson
pp 7164 - 7167; DOI:
10.1021/ja00310a066
PDF
Synthesis and crystal structure of an optically active, internally coordinated alkylchloroborane. The boron-centered anomeric effect
Christopher S. Shiner, Charles M. Garner, and R. Curtis Haltiwanger
pp 7167 - 7172; DOI:
10.1021/ja00310a067
PDF
The PE spectrum of [1.1.1]propellane: evidence for a non-bonding MO?
Evi Honegger, Hanspeter Huber, Edgar Heilbronner, William P. Dailey, and Kenneth B. Wiberg
pp 7172 - 7174; DOI:
10.1021/ja00310a068
PDF
Rotational spectra and structures of small clusters: Ar3-HF and Ar3-DF
H. S. Gutowsky, T. D. Klots, Carl Chuang, John D. Keen, C. A. Schmuttenmaer, and Tryggvi Emilsson
pp 7174 - 7175; DOI:
10.1021/ja00310a069
PDF
Studies in the cycloproparene series. The synthesis, trapping, and spectral characterization of 1H-cyclopropa[l]phenanthrene
Brian Halton, Barry R. Dent, Stefan Bohm, David L. Officer, Hans Schmickler, Fritz Schophoff, and Emanuel Vogel
pp 7175 - 7176; DOI:
10.1021/ja00310a070
PDF
Dewar furan. Its generation and trapping with isobenzofuran
Ian G. Pitt, Richard A. Russell, and Ronald N. Warrener
pp 7176 - 7178; DOI:
10.1021/ja00310a071
PDF
Phenyliodonium bis(phenylsulfonyl)methylide, a new hypervalent iodonium ylide
Lazaros Hadjiarapoglou, Spyros Spyroudis, and Anastasios Varvoglis
pp 7178 - 7179; DOI:
10.1021/ja00310a072
PDF
Oxidative nucleophilic addition of organovanadium reagents to aldehydes with formation of ketones
Toshikazu Hirao, Daisuke Misu, and Toshio Agawa
pp 7179 - 7181; DOI:
10.1021/ja00310a073
PDF
Competitive carbon-hydrogen activation and C.tplbond.C coordination in the reactions of acetylenes with a binuclear rhodium complex
Donald H. Berry and Richard Eisenberg
pp 7181 - 7183; DOI:
10.1021/ja00310a074
PDF
Stereochemistry of cycloadditions of fluoroallene
William R. Dolbier, Conrad R. Burkholder, Gene E. Wicks, Gus J. Palenik, and Marian Gawron
pp 7183 - 7184; DOI:
10.1021/ja00310a075
PDF
Stereoselective total synthesis of (.+-.)-8-deoxyanisatin
Andrew S. Kende and Jen Chen
pp 7184 - 7186; DOI:
10.1021/ja00310a076
PDF
NMR isotope shifts as a probe of electronic structure
Kenneth L. Servis and Robert L. Domenick
pp 7186 - 7187; DOI:
10.1021/ja00310a077
PDF
Selenium-77 nuclear magnetic resonance investigation of a protein-selenoligand complex: interaction of .alpha.-chymotrypsin with (phenylselenyl)acetate
Gregory P. Mullen, R. Bruce Dunlap, and Jerome D. Odom
pp 7187 - 7189; DOI:
10.1021/ja00310a078
PDF
Measurement of hydrazine-hydrazine radical cation self-exchange electron-transfer rates by proton NMR
Stephen F. Nelsen and Silas C. Blackstock
pp 7189 - 7190; DOI:
10.1021/ja00310a079
PDF
Probing polymer effects on chemical reactivity: ligand substitution kinetics of Ru(NH3)5(H2O)2+ in Nafion films
Charles M. Lieber and Nathan S. Lewis
pp 7190 - 7191; DOI:
10.1021/ja00310a080
PDF
Tetraaryldiphosphine cation radicals. Electrochemical generation and ESR study
Marcel Culcasi, Gerard Gronchi, and Paul Tordo
pp 7191 - 7193; DOI:
10.1021/ja00310a081
PDF
High-resolution NMR with a surface coil
M. Gochin and Alex Pines
pp 7193 - 7194; DOI:
10.1021/ja00310a082
PDF
Structures and Raman spectra of two crystalline modifications of dithiodiglycolic acid
Charles P. Nash, M. M. Olmstead, B. Weiss-Lopez, W. K. Musker, N. Ramasubbu, and R. Parthasarathy
pp 7194 - 7195; DOI:
10.1021/ja00310a083
PDF
Synthesis and characterization of dirhodium complexes with four N,N'-diphenylbenzamidine bridging ligands. Electrochemical generation and ESR properties of [Rh2(N2R2CR)4]n where R = Phenyl and n = 1 and -1
J. C. Le, M. Y. Chavan, L. K. Chau, J. L. Bear, and K. M. Kadish
pp 7195 - 7197; DOI:
10.1021/ja00310a084
PDF
Simplification of proton NMR spectra by selective excitation of experimental subspectra
Donald G. Davis and Ad Bax
pp 7197 - 7198; DOI:
10.1021/ja00310a085
PDF
Synthesis of 9-decarboxymethoxatin. Metal complexation of methoxatin as a possible requirement for its biological activity
J. Barry Noar, Evelyn J. Rodriguez, and Thomas C. Bruice
pp 7198 - 7199; DOI:
10.1021/ja00310a086
PDF
Valence .sigma. ionization in systems with multiple metal-metal bonds
Edward M. Kober and Dennis L. Lichtenberger
pp 7199 - 7201; DOI:
10.1021/ja00310a087
PDF
Aqueous electrochemistry of trans-(py)4ReV(O)2+. Electrocatalytic reductions based on rhenium(II)
David W. Pipes and Thomas J. Meyer
pp 7201 - 7202; DOI:
10.1021/ja00310a088
PDF
Time-resolved resonance Raman studies of the .delta..delta.* excited state of octachlorodirhenate dianion (Re2Cl82-)
Richard F. Dallinger
pp 7202 - 7204; DOI:
10.1021/ja00310a089
PDF
Photochemistry of the carbonyl ylide produced by reaction of fluorenylidene with acetone. A comparison of carbonyl and nitrile ylides
J. C. Scaiano, W. G. McGimpsey, and H. L. Casal
pp 7204 - 7206; DOI:
10.1021/ja00310a090
PDF
Importance of entropy terms in triplet energy transfer equilibria
F. Gessner and J. C. Scaiano
pp 7206 - 7207; DOI:
10.1021/ja00310a091
PDF
Monomeric tungsten(IV) phenoxide and thiolate complexes
Mark L. Listemann, John C. Dewan, and Richard R. Schrock
pp 7207 - 7208; DOI:
10.1021/ja00310a092
PDF
Synthesis and structural characterization of the complex [NiMo(CO)2{.mu.-.eta.2,.eta.2-C(Me)C(Me)C(O)}(.eta.-C5H5)(.eta.-C5H4Me)]
Michael C. Azar, Michael J. Chetcuti, Charles Eigenbrot, and Kelly A. Green
pp 7209 - 7210; DOI:
10.1021/ja00310a093
PDF
On the stability of cubic phosphorus, P8
Georges Trinquier, Jean Pierre Daudey, and Najia Komiha
pp 7210 - 7212; DOI:
10.1021/ja00310a094
PDF
X-ray and neutron diffraction study of H5Ir[P(iso-Pr)3]2
Luigi Garlaschelli, Saeed I. Khan, Robert Bau, Giuliano Longoni, and Thomas F. Koetzle
pp 7212 - 7213; DOI:
10.1021/ja00310a095
PDF
An alternant hydrocarbon .pi. system with nonalternant character. Evidence from UV-VIS spectroscopy for cyclic homoconjugation in homoazulene
Lawrence T. Scott, Mitsunori Oda, and Ihsan Erden
pp 7213 - 7214; DOI:
10.1021/ja00310a096
PDF
Application of spin trapping to probe the radical-pair model in magnetic-field-dependent photoreduction of naphthoquinone in SDS micellar solution
Masaharu Okazaki, Shigeru Sakata, Ryusei Konaka, and Takeshi Shiga
pp 7214 - 7216; DOI:
10.1021/ja00310a097
PDF
Selective hydroformylation of ethylene on rhodium-zinc-silica. An apparent example of site isolation of rhodium and Lewis acid-promoted carbonyl insertion
M. Ichikawa, A. J. Lang, D. F. Shriver, and W. M. H. Sachtler
pp 7216 - 7218; DOI:
10.1021/ja00310a098
PDF
Comparisons of the heterobimetallic and heterotrimetallic anions HFeW(CO)9- and Ph3PAuFeW(CO)9-
Larry W. Arndt, Marcetta Y. Darensbourg, John P. Fackler, Richard J. Lusk, David O. Marler, and Kay A. Youngdahl
pp 7218 - 7219; DOI:
10.1021/ja00310a099
PDF
Organometallic compounds of Group III. Part 41. Direct observation of the initial insertion of an unsaturated hydrocarbon into the titanium-carbon bond of the soluble Ziegler polymerization catalyst Cp2TiCl2-MeAlCl2
John J. Eisch, Andrzej M. Piotrowski, Sydney K. Brownstein, Eric J. Gabe, and Florence L. Lee
pp 7219 - 7221; DOI:
10.1021/ja00310a100
PDF
Thermal extrusion of dimethylsilanone from (hydridosilyt)ketenes. A retro-Wolff rearrangement
Thomas J. Barton and Brian L. Groh
pp 7221 - 7222; DOI:
10.1021/ja00310a101
PDF
Layer cross-linking in pillared clays
Thomas J. Pinnavaia, Steven D. Landau, Ming Shin Tzou, Ivy D. Johnson, and Max Lipsicas
pp 7222 - 7224; DOI:
10.1021/ja00310a102
PDF
Highly conductive metallomacrocyclic assemblies. Synthesis via electrocrystallization and single-crystal properties of a phthalocyanine molecular metal without halogen counterions
Tamotsu Inabe, Shuhei Nakamura, Wen Bin Liang, Tobin J. Marks, Robert L. Burton, Carl R. Kannewurf, and Kenichi Imaeda
pp 7224 - 7226; DOI:
10.1021/ja00310a103
PDF
Organometallic clusters containing oxygen atoms. Preparation, structure, and properties of (.eta.-C5H5)11V13O18(NMe3)2 and (.eta.-C5H5)14V16O24, dimeric derivatives of (.eta.-C5H5)6V6O8
Frank Bottomley, Daniel E. Paez, and Peter S. White
pp 7226 - 7227; DOI:
10.1021/ja00310a104
PDF
Stereospecificity of 1,3-dipolar cycloadditions of p-nitrobenzonitrile oxide to cis- and trans-dideuterioethylene
K. N. Houk, Raymond A. Firestone, Linda L. Munchausen, Paul H. Mueller, Byron H. Arison, and Lynn A. Garcia
pp 7227 - 7228; DOI:
10.1021/ja00310a105
PDF
Ionic multimers from heterocyclic compounds. Clusters or polymers?
Robert J. Doyle and Joseph E. Campana
pp 7228 - 7230; DOI:
10.1021/ja00310a106
PDF
Alkyl migration or carbonyl migration? Ab initio MO study of reaction mechanism for carbonyl insertion of palladium complex
Nobuaki Koga and Keiji Morokuma
pp 7230 - 7231; DOI:
10.1021/ja00310a107
PDF
Exciton delocalization of the excited singlet state of chlorophyll a monohydrate dimer and fluorescence lifetimes of translationally equivalent aggregates
F. K. Fong, M. S. Showell, and A. J. Alfano
pp 7231 - 7233; DOI:
10.1021/ja00310a108
PDF
Application of allenylsilanes in [3+2] annulation approaches to oxygen and nitrogen heterocycles
Rick L. Danheiser, Carrie A. Kwasigroch, and Yeun Min Tsai
pp 7233 - 7235; DOI:
10.1021/ja00310a109
PDF
Book Reviews

pp 7235 - 7238; DOI:
10.1021/ja00310a600
PDF

Issue 25


Geometrical structures of four conformers of the phosphocenium ion, P(C5H5)2+. A phosphorus sandwich?
Timothy J. Lee, Henry F. Schaefer, and Eric A. Magnusson
pp 7239 - 7243; DOI:
10.1021/ja00311a001
PDF
Does fluoroformic acid exist?
Zdenek Havlas, Tomas Kovar, and Rudolf Zahradnik
pp 7243 - 7246; DOI:
10.1021/ja00311a002
PDF
Vibrational spectrum, structure, and energy of [1.1.1]propellane
Kenneth B. Wiberg, William P. Dailey, Frederick H. Walker, Sherman T. Waddell, Louis S. Crocker, and Marshall Newton
pp 7247 - 7257; DOI:
10.1021/ja00311a003
PDF
The molecular structure of gaseous [1.1.1]propellane: an electron-diffraction investigation
Lise Hedberg and Kenneth Hedberg
pp 7257 - 7260; DOI:
10.1021/ja00311a004
PDF
Theoretical study of the stability of molecular P2, P4 (T.alpha.), and P8 (Oh)
Reinhart Ahlrichs, Stefan Brode, and Claus Ehrhardt
pp 7260 - 7264; DOI:
10.1021/ja00311a005
PDF
A theoretical study on the reactivity of nucleophiles coordinated to palladium
Jan E. Baeckvall, Eva E. Bjoerkman, Lars Pettersson, and Per Siegbahn
pp 7265 - 7267; DOI:
10.1021/ja00311a006
PDF
Cation binding effect on hydrogen bonding
Harold Basch, M. Krauss, and W. J. Stevens
pp 7267 - 7271; DOI:
10.1021/ja00311a007
PDF
Calculation of group electronegativity
John Mullay
pp 7271 - 7275; DOI:
10.1021/ja00311a008
PDF
SINDO1 study of photochemical reaction mechanisms of diazirines
Peter L. Mueller-Remmers and Karl Jug
pp 7275 - 7284; DOI:
10.1021/ja00311a009
PDF
MNDO and ab initio study of the reduction of formaldehyde by lithium methylamide
Michael L. McKee
pp 7284 - 7290; DOI:
10.1021/ja00311a010
PDF
An ESR study of the reaction of aluminum atoms with 1,3-butadiene: cheleotropic cycloaddition and substituted allyl formation
J. H. B. Chenier, J. A. Howard, J. S. Tse, and B. Mile
pp 7290 - 7294; DOI:
10.1021/ja00311a011
PDF
Angle-selected ENDOR spectroscopy. 1. Theoretical interpretation of ENDOR shifts from randomly orientated transition-metal complexes
G. G. Hurst, T. A. Henderson, and R. W. Kreilick
pp 7294 - 7299; DOI:
10.1021/ja00311a012
PDF
Angle-selected ENDOR spectroscopy. 2. Determination of proton coordinates from a polycrystalline sample of bis(2,4-pentanedionato)copper(II)
T. A. Henderson, G. C. Hurst, and R. W. Kreilick
pp 7299 - 7303; DOI:
10.1021/ja00311a013
PDF
Carbon-13 chemical shift anisotropies of pyridine and diazines
Pejman Parhami and B. M. Fung
pp 7304 - 7306; DOI:
10.1021/ja00311a014
PDF
Intrinsic deuterium/proton NMR isotope effects on carbon-13 chemical shifts: dependence on carbon hybridization and substitution
Joachim R. Wesener, Detlef Moskau, and Harald Guenther
pp 7307 - 7311; DOI:
10.1021/ja00311a015
PDF
Dynamics of phenylalanine in the solid state by NMR
M. H. Frey, J. A. DiVerdi, and S. J. Opella
pp 7311 - 7315; DOI:
10.1021/ja00311a016
PDF
A comparison of the ion-molecule reactions of Group 11 metal ions with alcohols
D. A. Weil and Charles L. Wilkins
pp 7316 - 7320; DOI:
10.1021/ja00311a017
PDF
Through-bond interactions in nonconjugated dienes and diones
V. Balaji, Kenneth D. Jordan, Rolf Gleiter, Gerhard Jaehne, and Georg Mueller
pp 7321 - 7323; DOI:
10.1021/ja00311a018
PDF
Vibrational spectra and force constants for the perfluorocyclopropenyl cation
Norman C. Craig, Gini F. Fleming, and Julianto Pranata
pp 7324 - 7329; DOI:
10.1021/ja00311a019
PDF
Measurement of the dissociation energies of gas-phase neutral dimers by a photoionization technique: values for trans-2-butene/sulfur dioxide, (trans-2-butene)2, and benzene/sulfur dioxide
J. R. Grover, E. A. Walters, J. K. Newman, and M. G. White
pp 7329 - 7339; DOI:
10.1021/ja00311a020
PDF
Photodissociation of the dimanganese ion: Mn2+: a route to the energetics of metal clusters
Martin F. Jarrold, Andreas J. Illies, and Michael T. Bowers
pp 7339 - 7344; DOI:
10.1021/ja00311a021
PDF
The electronic spectrum of cytosine
Frantisek Zaloudek, Joel S. Novros, and Leigh B. Clark
pp 7344 - 7351; DOI:
10.1021/ja00311a022
PDF
General approach to annulated 4-cyclooctenones by aliphatic Claisen rearrangement. Stereospecific total synthesis of (.+-.)-precapnelladiene
William A. Kinney, Michael J. Coghlan, and Leo A. Paquette
pp 7352 - 7360; DOI:
10.1021/ja00311a023
PDF
Transition-state structures for ester aminolysis with and without rate-limiting proton transfer
Ildiko M. Kovach, Michael Belz, Mark Larson, Steven Rousy, and Richard L. Schowen
pp 7360 - 7365; DOI:
10.1021/ja00311a024
PDF
Spectroscopy and photochemistry of thiouracils: implications for the mechanism of photocrosslinking in tRNA
Steven J. Milder and David S. Kliger
pp 7365 - 7373; DOI:
10.1021/ja00311a025
PDF
A microelectrochemical diode with submicron contact spacing based on the connection of two microelectrodes using dissimilar redox polymers
Gregg P. Kittlesen, Henry S. White, and Mark S. Wrighton
pp 7373 - 7380; DOI:
10.1021/ja00311a026
PDF
Mechanism of the spontaneous dehydration of bicarbonate ion
Piotr Paneth and Marion H. O'Leary
pp 7381 - 7384; DOI:
10.1021/ja00311a027
PDF
Gas-phase hydrogen-deuterium exchange reactions of anions: kinetics and detailed mechanism
Joseph J. Grabowski, Charles H. DePuy, and Veronica M. Bierbaum
pp 7384 - 7389; DOI:
10.1021/ja00311a028
PDF
Mechanism of cytochrome c oxidase-catalyzed dioxygen reduction at low temperatures. Evidence for two intermediates at the three-electron level and entropic promotion of the bond-breaking step
David F. Blair, Stephan N. Witt, and Sunney I. Chan
pp 7389 - 7399; DOI:
10.1021/ja00311a029
PDF
Reactions of CoCp+ (Cp = cyclopentadienyl) with hydrocarbons in the gas phase. Observation of novel skeletal isomerizations/dehydrocyclizations resulting in cobaltocenium formation
D. B. Jacobson and B. S. Freiser
pp 7399 - 7407; DOI:
10.1021/ja00311a030
PDF
A theoretical study of the cyclopropane ring opening by palladium
Jan E. Baeckvall, Eva E. Bjoerkman, Lars Pettersson, Per Siegbahn, and Alain Strich
pp 7408 - 7412; DOI:
10.1021/ja00311a031
PDF
Temperature and electrolyte effects on the electron-transfer reactions of cytochrome c
Kent B. Koller and Fred M. Hawkridge
pp 7412 - 7417; DOI:
10.1021/ja00311a032
PDF
Investigation of the trimetallic compounds [(.eta.5-C5H5)2TiX]2ZnX2 (X = Cl, Br) by ESR and ENDOR spectroscopies
Didier Gourier, Daniel Vivien, and Edmond Samuel
pp 7418 - 7423; DOI:
10.1021/ja00311a033
PDF
A new type of transition-metal dimer based on a hexaphosphine ligand system: Co2(CO)4(eHTP)2+ (eHTP = (Et2PCH2CH2)2PCH2P(CH2CH2PEt2)2)
Fredric R. Askham, George G. Stanley, and Edward C. Marques
pp 7423 - 7431; DOI:
10.1021/ja00311a034
PDF
Electron transfer across polypeptides. 5. Rapid rates of electron transfer between osmium(II) and cobalt(III) in complexes with bridging oligoprolines and other polypeptides
Stephan S. Isied, Asbed Vassilian, Roy H. Magnuson, and Harold A. Schwarz
pp 7432 - 7438; DOI:
10.1021/ja00311a035
PDF
Edge-sharing bioctahedral dimolybdenum(III) molecules with .mu.-RS groups. Direct experimental evidence for spin-state equilibria
F. Albert Cotton, Michael P. Diebold, Charles . O'Connor, and Gregory L. Powell
pp 7438 - 7445; DOI:
10.1021/ja00311a036
PDF
Transition-metal-promoted reactions of boron hydrides. 7. Platinum(II) bromide catalyzed cage growth and dehydrocoupling reactions of diborane with small polyhedral carboranes and boranes: synthesis of a new arachno carborane, 5,6-C2B6H12, and the diborane-coupled compounds 2:1',2'-[1,6-C2B4H5][B2H5] and 2:1',2'-[B5H8][B2H5]
Edward W. Corcoran and Larry G. Sneddon
pp 7446 - 7450; DOI:
10.1021/ja00311a037
PDF
Solid-state carbon-13 NMR determination of methyltin(IV) structure. Crystal and molecular structure of dimethyltin(IV) bis(1-pyrrolidinecarbodithioate)
Thomas P. Lockhart, William F. Manders, and E. O. Schlemper
pp 7451 - 7453; DOI:
10.1021/ja00311a038
PDF
Synthesis, reactions, and electronic structure of low-valent rhenium-oxo compounds. Crystal and molecular structure of Re(O)I(MeC.tplbond.CMe)2
James M. Mayer, David L. Thorn, and T. H. Tulip
pp 7454 - 7462; DOI:
10.1021/ja00311a039
PDF
A kinetic investigation of carbon dioxide insertion processes involving anionic tungsten-alkyl and -aryl derivatives: effects of carbon dioxide pressure, counterions, and ancillary ligands. Comparisons with migratory carbon monoxide insertion processes
Donald J. Darensbourg, Rebecca Kudaroski Hanckel, Christopher G. Bauch, Magdalena Pala, Debra Simmons, and J. Nicole White
pp 7463 - 7473; DOI:
10.1021/ja00311a040
PDF
Stereochemical studies of the carbon dioxide insertion reactions into the tungsten-alkyl bond
Donald J. Darensbourg and Georg Grotsch
pp 7473 - 7476; DOI:
10.1021/ja00311a041
PDF
Convergent functional groups: synthetic and structural studies
Julius Rebek, Luann Marshall, Raymond Wolak, Kevin Parris, Mary Killoran, Ben Askew, David Nemeth, and N. Islam
pp 7476 - 7481; DOI:
10.1021/ja00311a042
PDF
Allosteric effects in organic chemistry: binding cooperativity in a model for subunit interactions
Julius Rebek, Timothy Costello, Luann Marshall, Ruth Wattley, Robert C. Gadwood, and Kay Onan
pp 7481 - 7487; DOI:
10.1021/ja00311a043
PDF
Binding forces and catalysis. The use of bipyridyl-metal chelation to enhance reaction rates
Julius Rebek, Timothy Costello, and Ruth Wattley
pp 7487 - 7493; DOI:
10.1021/ja00311a044
PDF
Stepwise base-promoted elimination of hydrochloric acid via hydrogen-bonded carbanions studied by reaction branching and extreme deuterium isotope effects. Parallel carbocationic and carbanionic reactions
Maria Oelwegaard, Ian McEwen, Alf Thibblin, and Per Ahlberg
pp 7494 - 7499; DOI:
10.1021/ja00311a045
PDF
The octant rule. 16. Front octant effects: synthesis and circular dichroism of syn-(1'R)-spiro[cyclobutan-2-one-1,2'-(4'(a)-methyladamantane)] and syn-(1'S)-spiro[cyclobutan-2-one-1,7'-(2'-exo-methylnorbornane)]
David A. Lightner, Tsung C. Chang, Daniel T. Hefelfinger, Dennis E. Jackman, W. M. Donald Wijekoon, and John W. Givens
pp 7499 - 7508; DOI:
10.1021/ja00311a046
PDF
[3.3]Metacyclophane: a novel synthesis and a study of the structure through x-ray diffraction, molecular mechanics, and solution NMR analysis
M. F. Semmelhack, J. J. Harrison, D. C. Young, A. Gutierrez, Shahin Rafii, and Jon Clardy
pp 7508 - 7514; DOI:
10.1021/ja00311a047
PDF
Stereocontrolled total synthesis of lipoxins A
K. C. Nicolaou, C. A. Veale, S. E. Webber, and H. Katerinopoulos
pp 7515 - 7518; DOI:
10.1021/ja00311a048
PDF
Experiments in pursuit of pentagonal dodecahedrane: model synthesis of convex polyquinanes
Goverdhan Mehta and Mangalam S. Nair
pp 7519 - 7524; DOI:
10.1021/ja00311a049
PDF
Model compounds for the study of spectroscopic properties of visual pigments and bacteriorhodopsin
Timor Baasov and Mordechai Sheves
pp 7524 - 7533; DOI:
10.1021/ja00311a050
PDF
Acid-catalyzed .alpha.-halogenation of amidines by tetrahalomethanes. Kinetic- and isotope-effect evidence for the intermediacy of the ketene aminal tautomer
Stefan Loefaas and Per Ahlberg
pp 7534 - 7541; DOI:
10.1021/ja00311a051
PDF
Electrophilic reaction at single bonds. 21. Superacid-catalyzed alkylation of adamantane
George A. Olah, Omar Farooq, V. V. Krishnamurthy, G. K. Surya Prakash, and Khosrow Laali
pp 7541 - 7545; DOI:
10.1021/ja00311a052
PDF
Oxygen participation induced by increased electron demand
Joseph B. Lambert and Eric G. Larson
pp 7546 - 7550; DOI:
10.1021/ja00311a053
PDF
Photochemistry of iron atoms and dimers with ethylene in cryogenic matrixes. The FT-IR spectrum of ethenyliron hydride
Zakya H. Kafafi, Robert H. Hauge, and John L. Margrave
pp 7550 - 7559; DOI:
10.1021/ja00311a054
PDF
Matrix-isolation studies of the reactions of iron atoms and iron dimers with acetylene in an argon matrix. The FT-IR spectrum of ethynyliron hydride
Ellen S. Kline, Zakya H. Kafafi, Robert H. Hauge, and John L. Margrave
pp 7559 - 7562; DOI:
10.1021/ja00311a055
PDF
Catalytic epoxidation of 1-octene with diluted hydrogen peroxide. On the basic role of hydroxo complexes of platinum(II) and related species
Giorgio Strukul and Rino A. Michelin
pp 7563 - 7569; DOI:
10.1021/ja00311a056
PDF
Theoretical study of the tautomeric equilibrium of 4(1H)-pyridinone in solution
J. A. Sordo, M. Klobukowski, and Serafin Fraga
pp 7569 - 7572; DOI:
10.1021/ja00311a057
PDF
Iodide reduction of sulfilimines. Evidence for the partitioning of sulfurane intermediates
Paul R. Young and Patrick E. McMahon
pp 7572 - 7577; DOI:
10.1021/ja00311a058
PDF
Evidence for concerted general acid catalysis in an SN2-like transition state for the reduction of sulfilimines by thiols
Paul R. Young, Arvydas P. Zygas, and I Wen Evelyn Lee
pp 7578 - 7581; DOI:
10.1021/ja00311a059
PDF
Experimental search for the silanone-to-silylene rearrangement
Thomas J. Barton and Gregory P. Hussmann
pp 7581 - 7584; DOI:
10.1021/ja00311a060
PDF
Phenalene-phosphazene complexes: injection of electron spin density into the cyclotriphosphazene ring system
R. C. Haddon, S. L. Mayo, S. V. Chichester, and J. H. Marshall
pp 7585 - 7591; DOI:
10.1021/ja00311a061
PDF
Solvation effects on the alkaline hydrolysis of some p-nitrophenyl esters
Michael S. Matta and Anthony A. Toenjes
pp 7591 - 7596; DOI:
10.1021/ja00311a062
PDF
Mechanistic studies on the Wolff rearrangement: the chemistry and spectroscopy of some .alpha.-keto carbenes
Robert J. McMahon, Orville L. Chapman, Richard A. Hayes, Thomas C. Hess, and Hans Peter Krimmer
pp 7597 - 7606; DOI:
10.1021/ja00311a063
PDF
Mechanism of the chromium-catalyzed epoxidation of olefins. Role of oxochromium(V) cations
E. G. Samsel, K. Srinivasan, and Jay K. Kochi
pp 7606 - 7617; DOI:
10.1021/ja00311a064
PDF
Mechanism and products of autoxidation of 5,7-dihydroxytryptamine
Achintya K. Sinhababu and Ronald T. Borchardt
pp 7618 - 7627; DOI:
10.1021/ja00311a065
PDF
Mechanism of action of S-adenosyl-L-homocysteine hydrolase. Measurement of kinetic isotope effects using adenosine-3'-d and S-adenosyl-L-homocysteine-3'-d as substrates
Achintya K. Sinhababu, Ronnda L. Bartel, Nancy Pochopin, and Ronald T. Borchardt
pp 7628 - 7632; DOI:
10.1021/ja00311a066
PDF
EPR evidence for hydrogen bond donation to the terminal oxygen of cobalt-oxygen model compounds and cobalt oxymyoglobin
F. Ann Walker and James Bowen
pp 7632 - 7635; DOI:
10.1021/ja00311a067
PDF
X-ray and proton NMR analyses of the structure and conformation of 2-azacoformycin, a potent inhibitor of adenosine deaminase
George I. Birnbaum, Jean Robert Brisson, Steven H. Krawczyk, and Leroy B. Townsend
pp 7635 - 7640; DOI:
10.1021/ja00311a068
PDF
.beta.I and .beta.II-turn conformations in model dipeptides with the Pro-Xaa sequences
A. Aubry, M. T. Cung, and M. Marraud
pp 7640 - 7647; DOI:
10.1021/ja00311a069
PDF
Conformational characterization of glycine residues incorporated into some homopolypeptides by solid-state carbon-13 NMR spectroscopy
Shinji Ando, Takeshi Yamanobe, Isao Ando, Akira Shoji, Takuo Ozaki, Ryoko Tabeta, and Hazime Saito
pp 7648 - 7652; DOI:
10.1021/ja00311a070
PDF
Lone-pair directionality in hydrogen-bond potential functions for molecular mechanics calculations: the inhibition of human carbonic anhydrase II by sulfonamides
Angelo Vedani and Jack D. Dunitz
pp 7653 - 7658; DOI:
10.1021/ja00311a071
PDF
Exchange characteristics of the amide protons of d-biotin and derivatives: implications for the mechanism of biotin enzymes and the role of sulfur in biotin
D. C. Fry, T. L. Fox, M. D. Lane, and A. S. Mildvan
pp 7659 - 7665; DOI:
10.1021/ja00311a072
PDF
Cobalt(II) nitrosyl cation radicals of porphyrins, chlorins, and isobacteriochlorins. Models for nitrite and sulfite reductases and implications for A1u heme radicals
Etsuko Fujita, C. K. Chang, and Jack Fajer
pp 7665 - 7669; DOI:
10.1021/ja00311a073
PDF
Biomimetic models for cysteine proteases. 3. Acylation of imidazolium-thiolate zwitterions by p-nitrophenylacetate as a model for the acylation step and demonstration of intramolecular general-base-catalyzed delivery of water by imidazole to thiol esters as a model for the deacylation step
J. P. Street, K. I. Skorey, R. S. Brown, and R. G. Ball
pp 7669 - 7679; DOI:
10.1021/ja00311a074
PDF
Effect of hydrophobic-lipophilic interactions on chemical reactivity. 6. The first example of correlation of hydrophobic-lipophilic substituent constants with chemical reactivity for a simple substrate-solvent system
Wei Qiang Fan and Xi Kui Jiang
pp 7680 - 7684; DOI:
10.1021/ja00311a075
PDF
Induction of peptide conformation at apolar water interfaces. 1. A study with model peptides of defined hydrophobic periodicity
W. F. DeGrado and J. D. Lear
pp 7684 - 7689; DOI:
10.1021/ja00311a076
PDF
Analysis of the principles governing proton-transfer reactions. Comparison of the imine and amine groups
Eric A. Hillenbrand and Steve Scheiner
pp 7690 - 7696; DOI:
10.1021/ja00311a077
PDF
Dynamic Jahn-Teller effect in methane radical cation. Location of the transition structures for hydrogen scrambling and inversion
M. N. Paddon-Row, D. J. Fox, J. A. Pople, K. N. Houk, and David W. Pratt
pp 7696 - 7700; DOI:
10.1021/ja00311a078
PDF
Interconversion of .mu.-alkylidyne and .mu.-alkenyl diiron complexes
Charles P. Casey, Seth R. Marder, and Bruce R. Adams
pp 7700 - 7705; DOI:
10.1021/ja00311a079
PDF
Silicon-carbon unsaturated compounds. 20. Formation and reactions of disilacyclopropanes and molecular structure of 3-(hydroxydimesitylsilyl)-1,1-dimesityl-2,2-bis(trimethylsilyl)-1-silacyclopropane
Mitsuo Ishikawa, Shigeji Matsuzawa, Hiroshi Sugisawa, Fujio Yano, Shigehiro Kamitori, and Taiichi Higuchi
pp 7706 - 7710; DOI:
10.1021/ja00311a080
PDF
Preparation and interconversion of dithiatriazine derivatives: crystal, molecular, and electronic structure of bis(5-phenyl-1,3,2,4,6-dithiatriazine) (PhCN3S2)2
Rene T. Boere, Catherine L. French, Richard T. Oakley, A. Wallace Cordes, J. Ann James Privett, Scott L. Craig, and James B. Graham
pp 7710 - 7717; DOI:
10.1021/ja00311a081
PDF
Theoretical probes of activated-complex structure and properties: substituent effects in carbonyl addition
Ian H. Williams, Dale Spangler, Gerald M. Maggiora, and Richard L. Schowen
pp 7717 - 7723; DOI:
10.1021/ja00311a082
PDF
Photochemistry of a biphenylyl-substituted cyclohexenone. Mechanistic and exploratory organic photochemistry
H. E. Zimmerman, Jianhua Xu, R. K. King, and C. E. Caufield
pp 7724 - 7732; DOI:
10.1021/ja00311a083
PDF
Photochemical rearrangements of naphthyl-substituted enones. Mechanistic and exploratory organic photochemistry
Howard E. Zimmerman, Craig E. Caufield, and Russell K. King
pp 7732 - 7744; DOI:
10.1021/ja00311a084
PDF
Rapidly rearranging excited states of bichromophoric molecules. Mechanistic and exploratory organic photochemistry
Howard E. Zimmerman and Doreen C. Lynch
pp 7745 - 7756; DOI:
10.1021/ja00311a085
PDF
Nature of the active sites for alkane-selective oxidation on vanadium-phosphorus oxides
Guido Busca, Gabriele Centi, and Ferruccio Trifiro
pp 7757 - 7758; DOI:
10.1021/ja00311a086
PDF
Formation of a novel .eta.3:.eta.4-1,2,3-trimethyl-4,5-dimethylenecyclopentenyl ligand by hydrogen abstraction from a permethylcyclopentadienyl group in permethyltitanocene carbyl and related systems
Johannes W. Pattiasina, Catharina E. Hissink, Jan L. De Boer, Auke Meetsma, Jan H. Teuben, and Anthony L. Spek
pp 7758 - 7759; DOI:
10.1021/ja00311a087
PDF
Synthesis of 6-methylpretetramid, the fully aromatic precursor of tetracycline
S. Mahalingam, Peter C. Kuzma, John Y. C. Lee, and Thomas M. Harris
pp 7760 - 7761; DOI:
10.1021/ja00311a088
PDF
A fully synthetic route to tunicaminyluracil
Samuel Danishefsky and Michael Barbachyn
pp 7761 - 7762; DOI:
10.1021/ja00311a089
PDF
A fully synthetic route to hikosamine
Samuel Danishefsky and Clarence Maring
pp 7762 - 7764; DOI:
10.1021/ja00311a090
PDF
Oxidation and reduction potentials of transient free radicals
Danial D. M. Wayner and David Griller
pp 7764 - 7765; DOI:
10.1021/ja00311a091
PDF
An efficient, site-specific DNA target for bleomycin
Hiroshi Sugiyama, Robert E. Kilkuskie, Sidney M. Hecht, Gijs A. Van der Marel, and Jacques H. Van Boom
pp 7765 - 7767; DOI:
10.1021/ja00311a092
PDF
Photochemistry of acyloxymethyl(benzyl)silanes. Evidence for the primary formation of a benzyl-silyl radical pair and mechanism of free-radical 1,2-(carbon .fwdarw. silicon)-acyloxy migration
Mitsuo Kira, Hitoaki Yoshida, and Hideki Sakurai
pp 7767 - 7768; DOI:
10.1021/ja00311a093
PDF
Catalysis by human leukocyte elastase. 5. Structural features of the virtual transition state for acylation
Ross L. Stein
pp 7768 - 7769; DOI:
10.1021/ja00311a094
PDF
Rhodopsin in polymerized bilayer membranes
P. N. Tyminski, L. H. Latimer, and D. F. O'Brien
pp 7769 - 7770; DOI:
10.1021/ja00311a095
PDF
Macroexpansion methodology. 3. Eight-step synthesis of (-)-(3Z)-cembrene A
Paul A. Wender and Dennis A. Holt
pp 7771 - 7772; DOI:
10.1021/ja00311a096
PDF
Metalloketene formation by insertion of carbon suboxide into tungsten and rhenium metal-hydride bonds
Gregory L. Hillhouse
pp 7772 - 7773; DOI:
10.1021/ja00311a097
PDF
Copper polyhydrides
Timothy H. Lemmen, Kirsten Folting, John C. Huffman, and Kenneth G. Caulton
pp 7774 - 7775; DOI:
10.1021/ja00311a098
PDF
Formation of stable tungsten(alkene)carbyne complexes by carbonyl substitution reactions
Andreas Mayr, Alison M. Dorries, Gregory A. McDermott, Steven J. Geib, and Arnold L. Rheingold
pp 7775 - 7776; DOI:
10.1021/ja00311a099
PDF
An efficient asymmetric synthesis of (+)-mesembrine and related chiral 4,4-disubstituted cyclohexenones
A. I. Meyers, Reinhard Hanreich, and Klaus T. Wanner
pp 7776 - 7778; DOI:
10.1021/ja00311a100
PDF
Time reversal of the evolution under scalar spin-spin interactions in NMR. Application for .omega.1 decoupling in two-dimensional NOE spectroscopy
O. W. Soerensen, C. Griesinger, and R. R. Ernst
pp 7778 - 7779; DOI:
10.1021/ja00311a101
PDF
Lanthanum complexes of spheroidal carbon shells
J. R. Heath, S. C. O'Brien, Q. Zhang, Y. Liu, R. F. Curl, F. K. Tittel, and R. E. Smalley
pp 7779 - 7780; DOI:
10.1021/ja00311a102
PDF
Separation of oxygen isotopic compounds by reversed-phase liquid chromatography on the basis of oxygen isotope effects on the dissociation of carboxylic acids
Nobuo Tanaka and Mikio Araki
pp 7780 - 7781; DOI:
10.1021/ja00311a103
PDF
Separation of nitrogen isotopic compounds by reversed-phase liquid chromatography on the basis of nitrogen isotope effects on the dissociation of amines
Nobuo Tanaka, Atsumi Yamaguchi, Mikio Araki, and Kazuhiro Kimata
pp 7781 - 7782; DOI:
10.1021/ja00311a104
PDF
Properties of porphyrin dimers, formed by pairing cationic and anionic porphyrins
Emmanuel Ojadi, Russell Selzer, and Henry Linschitz
pp 7783 - 7784; DOI:
10.1021/ja00311a105
PDF
Triplet ESR study of dimerization of cationic and anionic water-soluble porphyrins
Hans Van Willigen, Utpal Das, Emmanuel Ojadi, and Henry Linschitz
pp 7784 - 7785; DOI:
10.1021/ja00311a106
PDF
Models for the triply bridging site in chemisorption: the first complex containing the Pt3(.mu.3-H) group and evidence for inversion of the Pt3(.mu.3-H) unit and for reversible coordination of carbon monoxide
Brian R. Lloyd and Richard J. Puddephatt
pp 7785 - 7786; DOI:
10.1021/ja00311a107
PDF
Photoelectron spectra and bonding in cerocene, bis(.pi.-[8]annulene)cerium(IV)
Andrew Streitwieser, Steven A. Kinsley, John T. Rigsbee, Ignazio L. Fragala, and Enrico Ciliberto
pp 7786 - 7788; DOI:
10.1021/ja00311a108
PDF
An organotransition metal based approach to the synthesis of C-glycosides
Philip DeShong, Greg A. Slough, Varadaraj Elango, and George L. Trainor
pp 7788 - 7790; DOI:
10.1021/ja00311a109
PDF
Total synthesis of (+)-actinobolin
Ravi S. Garigipati, David M. Tschaen, and Steven M. Weinreb
pp 7790 - 7792; DOI:
10.1021/ja00311a110
PDF
An inhibitor of chorismate mutase resembling the transition-state conformation
Paul A. Bartlett and Charles R. Johnson
pp 7792 - 7793; DOI:
10.1021/ja00311a111
PDF
Hydration of chloride and bromide anions: determination of relative free energy by computer simulation
Terry P. Lybrand, Indira Ghosh, and J. Andrew McCammon
pp 7793 - 7794; DOI:
10.1021/ja00311a112
PDF
Book Reviews

pp 7795 - 7804; DOI:
10.1021/ja00311a600
PDF

Issue 26


Quantization effects in the photocurrent spectroscopy of superlattice electrodes
A. J. Nozik, B. R. Thacker, J. A. Turner, and J. M. Olson
pp 7805 - 7810; DOI:
10.1021/ja00312a001
PDF
The dependence of biological electron transfer rates on exothermicity. The cytochrome c/cytochrome b5 couple
George McLendon and John R. Miller
pp 7811 - 7816; DOI:
10.1021/ja00312a002
PDF
Laser flash photolysis study of the hydrogen atom transfer reaction from triplet 1-naphthol to ground benzophenone
Haruo Shizuka, Hiroyuki Hagiwara, and Masaru Fukushima
pp 7816 - 7823; DOI:
10.1021/ja00312a003
PDF
Stereodynamics of a series of di-tert-butylphosphines [(tert-C4H9)2PR; R = H, Me, Et, CH2Ph, iso-C3H7, tert-C4H9, and Ph]. Carbon-13, proton, and phosphorus-31 NMR studies. Molecular mechanics calculations
Christopher D. Rithner and C. Hackett Bushweller
pp 7823 - 7836; DOI:
10.1021/ja00312a004
PDF
Structure and conformations of 4-chloro-1-butanol: electron-diffraction evidence for internal hydrogen bonding
Otto Bastiansen, Liv Fernholt, Kenneth Hedberg, and Ragnhild Seip
pp 7836 - 7841; DOI:
10.1021/ja00312a005
PDF
Selectivity of proton abstraction from propyne on the silver(110) surface
J. M. Vohs, B. A. Carney, and M. A. Barteau
pp 7841 - 7848; DOI:
10.1021/ja00312a006
PDF
Simultaneous determination of photoreaction dynamics and energetics using pulsed, time-resolved photoacoustic calorimetry
Jeanne E. Rudzki, Joshua L. Goodman, and Kevin S. Peters
pp 7849 - 7854; DOI:
10.1021/ja00312a007
PDF
Factors determining carbon monoxide adsorption sites on palladium and platinum (100) and (111) surfaces: theoretical study
Alfred B. Anderson and M. K. Awad
pp 7854 - 7857; DOI:
10.1021/ja00312a008
PDF
Theoretical interpretation of the cyclohexane .fwdarw. benzene reaction on the platinum(III) surface
Dae Bok Kang and Alfred B. Anderson
pp 7858 - 7861; DOI:
10.1021/ja00312a009
PDF
Inclusion of spin-orbit and low-symmetry effects in a vibronic coupling (PKS) model for mixed-valence dimers: application to the Creutz-Taube ion
K. Neuenschwander, S. B. Piepho, and Paul N. Schatz
pp 7862 - 7869; DOI:
10.1021/ja00312a010
PDF
Theoretical studies of the system H3O+(H2O)n for n = 1, 9
E. Kochanski
pp 7869 - 7873; DOI:
10.1021/ja00312a011
PDF
Monte Carlo study of the conformation-dependent hydration of the 18-crown-6 macrocycle
G. Ranghino, S. Romans, J. M. Lehn, and Georges Wipff
pp 7873 - 7877; DOI:
10.1021/ja00312a012
PDF
The infrared spectrum and force field of tricarbon monoxide
Ronald D. Brown, David E. Pullin, Edward H. N. Rice, and Martin Rodler
pp 7877 - 7880; DOI:
10.1021/ja00312a013
PDF
Direct observation of ion-pair dynamics
J. M. Masnovi and J. K. Kochi
pp 7880 - 7893; DOI:
10.1021/ja00312a014
PDF
Tailored excitation for Fourier transform ion cyclotron mass spectrometry
Alan G. Marshall, Tao Chin Lin Wang, and Tom L. Ricca
pp 7893 - 7897; DOI:
10.1021/ja00312a015
PDF
g-Tensor in a low-spin heme system using molecular orbital theory - ferricytochrome c and nitrosylhemoglobin
K. C. Mishra, Santosh K. Mishra, J. N. Roy, S. Ahmad, and T. P. Das
pp 7898 - 7904; DOI:
10.1021/ja00312a016
PDF
Structural dependence of the singlet-triplet energy gap of the tetramethylene biradical
C. Doubleday, J. McIver, and M. Page
pp 7904 - 7909; DOI:
10.1021/ja00312a017
PDF
Oxidation of 2,6-di-tert-butylphenol by molecular oxygen. 2. Catalysis by cobaltous polyamine chelates through their (.mu.-peroxo)- and (.mu.-peroxo)(.mu.-hydroxo)dicobalt(III) complexes
Stephen A. Bedell and Arthur E. Martell
pp 7909 - 7913; DOI:
10.1021/ja00312a018
PDF
Mixed copper/iron clusters. The preparation and structures of [(Ph3P)2Cu]2Fe(CO)4 and [(diphos)2Cu]2Cu6Fe4(CO)16
G. Doyle, K. A. Eriksen, and D. Van Engen
pp 7914 - 7920; DOI:
10.1021/ja00312a019
PDF
Influence of solvent properties on the kinetics of complexation of the sodium ion with 18-crown-6
Bruce O. Strasser and Alexander I. Popov
pp 7921 - 7924; DOI:
10.1021/ja00312a020
PDF
Properties of metal-metal single bonds. Vibrational and electronic spectra of binuclear rhodium(II) and iridium(II) isocyanide complexes with comparisons to decacarbonyldimanganese [Mn2(CO)10]
Vincent M. Miskowski, Terrance P. Smith, Thomas M. Loehr, and Harry B. Gray
pp 7925 - 7934; DOI:
10.1021/ja00312a021
PDF
Structural insights from the molybdenum K-edge x-ray absorption near edge structure of the iron-molybdenum protein of nitrogenase and its iron-molybdenum cofactor by comparison with synthetic iron-molybdenum-sulfur clusters
S. D. Conradson, B. K. Burgess, W. E. Newton, J. W. McDonald, J. F. Rubinson, S. F. Gheller, L. E. Mortenson, M. W. W. Adams, P. K. Mascharak, and et al.
pp 7935 - 7940; DOI:
10.1021/ja00312a022
PDF
Formation and thermal reactions of rhodium-carbon bonds derived from the reactions of octaethylporphyrin-rhodium(III) dimer with alkyl carbon-hydrogen bonds in alkyl aromatics
Kenneth J. Del Rossi and Bradford B. Wayland
pp 7941 - 7944; DOI:
10.1021/ja00312a023
PDF
Synthetic, structural, spectroscopic, and theoretical studies of decamethylvanadocene arylnitrenes
Joseph H. Osborne, Arnold L. Rheingold, and William C. Trogler
pp 7945 - 7952; DOI:
10.1021/ja00312a024
PDF
Nucleophilic attack on .eta.2-acetyl ligands. Structure of a bridging .eta.2-acetone complex
Bruce D. Martin, Stephen A. Matchett, Jack R. Norton, and Oren P. Anderson
pp 7952 - 7959; DOI:
10.1021/ja00312a025
PDF
Association phenomena. 6. NMR studies of the mixed chelates of triethylenetetramine, phosphate, and metal ions
George C. Mei and C. David Gutsche
pp 7959 - 7963; DOI:
10.1021/ja00312a026
PDF
Association phenomena. 7. Mixed chelate and comicellar catalysis of acetyl phosphate olysis reactions
C. David Gutsche and George C. Mei
pp 7964 - 7967; DOI:
10.1021/ja00312a027
PDF
Total synthesis of a novel antiulcer agent via a modification of the intramolecular Wadsworth-Emmons-Wittig reaction
Paul A. Aristoff, Paul D. Johnson, and Allen W. Harrison
pp 7967 - 7974; DOI:
10.1021/ja00312a028
PDF
Asymmetric synthesis of 2-alkyl pyrrolidines and piperidines. Synthesis of (+)-metazocine
Albert I. Meyers, Daniel A. Dickman, and Thomas R. Bailey
pp 7974 - 7978; DOI:
10.1021/ja00312a029
PDF
Factors influencing conformational preferences in cyclohexenes
Joseph B. Lambert and Dale E. Marko
pp 7978 - 7982; DOI:
10.1021/ja00312a030
PDF
Metmyoglobin and methemoglobin as efficient traps for nitrosyl hydride (nitroxyl) in neutral aqueous solution
Dennis A. Bazylinski and Thomas C. Hollocher
pp 7982 - 7986; DOI:
10.1021/ja00312a031
PDF
On the reaction of trioxodinitrate(II) with hemoglobin and myoglobin
Dennis A. Bazylinski, Joanne Goretski, and Thomas C. Hollocher
pp 7986 - 7989; DOI:
10.1021/ja00312a032
PDF
Stereoelectronic aspects of the intercalative binding properties of 7,12-dimethylbenz[a]anthracene metabolites with DNA
Irene S. Zegar, Arungundrum S. Prakash, Ronald G. Harvey, and Pierre R. LeBreton
pp 7990 - 7995; DOI:
10.1021/ja00312a033
PDF
Mixed-valence dialkylbiferrocenium salts: an explanation for the observed temperature dependence of electron-transfer rates
Teng Yuan Dong, David N. Hendrickson, Kumiko Iwai, Michelle J. Cohn, Steven J. Geib, Arnold L. Rheingold, Hirotoshi Sano, Izumi Motoyama, and Satoru Nakashima
pp 7996 - 8008; DOI:
10.1021/ja00312a034
PDF
Valence-detrapping modes for electron transfer in the solid state of mixed-valence, oxo-centered, trinuclear iron acetate complexes: x-ray structure and physical data for [Fe3O(O2CCH3)6(4-Et-py)3](4-Et-py)
Seung M. Oh, David N. Henderickson, Karen L. Hassett, and Raymond E. Davis
pp 8009 - 8018; DOI:
10.1021/ja00312a035
PDF
Cystine peptides. The antiparallel .beta.-sheet conformation of two synthetic cyclic bis(cystine peptides)
R. Kishore, A. Kumar, and P. Balaram
pp 8019 - 8023; DOI:
10.1021/ja00312a036
PDF
Structure elucidation of nitrosocimetidine, a mutagenic charge-transfer system
Scott Rice, Dana Ichinotsubo, Howard Mower, and Morton Mandel
pp 8023 - 8029; DOI:
10.1021/ja00312a037
PDF
A theoretical study of the phosphinonitrene (H2P:N)-iminophosphane (HP:NH) rearrangement
Minh Tho Nguyen, Michael A. McGinn, and Anthony F. Hegarty
pp 8029 - 8033; DOI:
10.1021/ja00312a038
PDF
Ab initio calculations on the lowest .pi. state of difluorocarbene radical cation
David A. Hrovat and Weston Thatcher Borden
pp 8034 - 8035; DOI:
10.1021/ja00312a039
PDF
Infrared multiphoton dissociation of some oxygen-containing hydrocarbon ions. Differentiation of isomeric ion structures in the gas phase
G. Baykut, C. H. Watson, R. R. Weller, and J. R. Eyler
pp 8036 - 8042; DOI:
10.1021/ja00312a040
PDF
Electronic structure of three-membered rings containing phosphorus atoms. PE spectroscopic investigations and model calculations
Rolf Gleiter, Wolfgang Schaefer, and Marianne Baudler
pp 8043 - 8049; DOI:
10.1021/ja00312a041
PDF
Kinetic isotope effect associated with the dissociative addition of dihydrogen to trans-Ir(CO)Cl(Ph3P)2
Peng Zhou, Arturo A. Vitale, Joseph San Filippo, and William H. Saunders
pp 8049 - 8054; DOI:
10.1021/ja00312a042
PDF
Charge carrier trapping and recombination dynamics in small semiconductor particles
Guido Rothenberger, Jacques Moser, Michael Graetzel, Nick Serpone, and Devendra K. Sharma
pp 8054 - 8059; DOI:
10.1021/ja00312a043
PDF
Distonic oxonium and ammonium radical cations. A neutralization-reionization and collisional activation study
Chrysostomos Wesdemiotis, Paul O. Danis, Rong Feng, Jacqueline Tso, and Fred W. McLafferty
pp 8059 - 8066; DOI:
10.1021/ja00312a044
PDF
Efficient total synthesis of (.+-.)-anatoxin a
Rick L. Danheiser, John M. Morin, and Edward J. Salaski
pp 8066 - 8073; DOI:
10.1021/ja00312a045
PDF
"Ordered" structure in dilute suspensions of highly charged polymer lattices as studied by microscopy. 2. The influence of ionic strength, dielectric constant, temperature, and viscosity
Norio Ise, Kensaku Ito, Tsuneo Okubo, Shin Dosho, and Ikuo Sogami
pp 8074 - 8077; DOI:
10.1021/ja00312a046
PDF
Variations in reactivity of lone-pair electrons due to intramolecular hydrogen bonding as observed by Penning ionization electron spectroscopy
Koichi Ohno, Keitaro Imai, and Yoshiya Harada
pp 8078 - 8082; DOI:
10.1021/ja00312a047
PDF
Study of stereochemical properties of molecular orbitals by Penning ionization electron spectroscopy. Effects of through-space/through-bond interactions on electron distributions
Koichi Ohno, Toshimasa Ishida, Yukito Naitoh, and Yasuo Izumi
pp 8082 - 8086; DOI:
10.1021/ja00312a048
PDF
Metallocalixarenes: syntheses and x-ray crystal structures of titanium(IV), iron(III), and cobalt(II) complexes of p-tert-butylcalix[4]arene
Marilyn M. Olmstead, Gary Sigel, Hakon Hope, Xiaojie Xu, and Philip P. Power
pp 8087 - 8091; DOI:
10.1021/ja00312a049
PDF
Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes
Gerald Jeske, Harald Lauke, Heiko Mauermann, Paul N. Swepston, Herbert Schumann, and Tobin J. Marks
pp 8091 - 8103; DOI:
10.1021/ja00312a050
PDF
Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) ligands
Gerald Jeske, Laurel E. Schock, Paul N. Swepston, Herbert Schumann, and Tobin J. Marks
pp 8103 - 8110; DOI:
10.1021/ja00312a051
PDF
Highly reactive organolanthanides. A mechanistic study of catalytic olefin hydrogenation by bis(pentamethylcyclopentadienyl) and related 4f complexes
Gerald Jeske, Harald Lauke, Heiko Mauermann, Herbert Schumann, and Tobin J. Marks
pp 8111 - 8118; DOI:
10.1021/ja00312a052
PDF
Synthesis and structure of a new ternary chalcogenide Nb3Pd0.72Se7; interrelationships in the packing of prisms and planes
Douglas A. Keszler and James A. Ibers
pp 8119 - 8127; DOI:
10.1021/ja00312a053
PDF
Crystal and molecular structure of and magnetic coupling in two complexes containing gadolinium(III) and copper(II) ions
A. Bencini, C. Benelli, A. Caneschi, Richard L. Carlin, A. Dei, and D. Gatteschi
pp 8128 - 8136; DOI:
10.1021/ja00312a054
PDF
Systematics of the formation of .PI.-carbonyl ligands in four-iron clusters. Synthesis and structures of [K(18-crown-6)][Fe4(AuPEt3)(CO)13].CH2Cl2, Fe4(AuPEt3)(CO)12(COCH3), [PPN][Fe4(CuPPh3)(CO)13], and [PPN][Fe4(HgCH3)(CO)13]
Colin P. Horwitz, Elizabeth M. Holt, Carolyn P. Brock, and Duward F. Shriver
pp 8136 - 8146; DOI:
10.1021/ja00312a055
PDF
Solution equilibria between carbon-bonded carbonyl and .PI.-carbonyl ligands in four-iron clusters and cleavage of the .PI.-carbonyl ligand
Colin P. Horwitz and Duward F. Shriver
pp 8147 - 8153; DOI:
10.1021/ja00312a056
PDF
Study of intramolecular sensitization and other excited-state pathways in orthometalated azobenzene complexes of palladium(II)
Yasuo Wakatsuki, Hiroshi Yamazaki, Paul A. Grutsch, Mahalingam Santhanam, and Charles Kutal
pp 8153 - 8159; DOI:
10.1021/ja00312a057
PDF
The mechanism of Lewis acid catalyzed ene reactions
Barry B. Snider and Eyal Ron
pp 8160 - 8164; DOI:
10.1021/ja00312a058
PDF
Arsenite-inhibited xanthine oxidase - determination of the molybdenum-sulfur-arsenic geometry by EXAFS
S. P. Cramer and R. Hille
pp 8164 - 8169; DOI:
10.1021/ja00312a059
PDF
Activation of methane by photoexcited copper atoms and the photochemistry of methylcopper hydride in solid methane matrixes
J. Mark Parnis, Steven A. Mitchell, Jaimie Garcia-Prieto, and Geoffrey A. Ozin
pp 8169 - 8178; DOI:
10.1021/ja00312a060
PDF
Molecular complexes of nucleosides and nucleotides with a monomeric cationic porphyrin and some of its metal derivatives
R. F. Pasternack, E. J. Gibbs, A. Antebi, S. Bassner, L. De Poy, D. H. Turner, A. Williams, F. Laplace, M. H. Lansard, and et al.
pp 8179 - 8186; DOI:
10.1021/ja00312a061
PDF
Diastereo- and enantioselective aldehyde addition reactions of 2-allyl-1,3,2-dioxaborolane-4,5-dicarboxylic esters, a useful class of tartrate ester modified allylboronates
William R. Roush, Alan E. Walts, and Lee K. Hoong
pp 8186 - 8190; DOI:
10.1021/ja00312a062
PDF
Cadmium-113 shielding tensors in cadmium-substituted metalloproteins
Paul S. Marchetti, Paul D. Ellis, and Robert G. Bryant
pp 8191 - 8196; DOI:
10.1021/ja00312a063
PDF
On the singlet and triplet excited states of nitrosamines
Yuan L. Chow, Zheng Zhi Wu, Ming Pui Lau, and Rodrick W. Yip
pp 8196 - 8201; DOI:
10.1021/ja00312a064
PDF
Multinuclear NMR study of the disproportionation and syn/anti isomerism in solutions of amino-substituted methylmercury derivatives of adenine and 9-methyladenine
Jean Pierre Charland, Viet Minh Tan Phan, Maurice St-Jacques, and Andre L. Beauchamp
pp 8202 - 8211; DOI:
10.1021/ja00312a065
PDF
Synthesis and structures of distibene (RSb:SbR) and bridging stibinidene (RSb) iron complexes
A. H. Cowley, N. C. Norman, M. Pakulski, D. Bricker, and D. R. Russell
pp 8211 - 8218; DOI:
10.1021/ja00312a066
PDF
Base-catalyzed reactions of triarylmethyl carbocations with water
Joseph R. Gandler
pp 8218 - 8223; DOI:
10.1021/ja00312a067
PDF
On the incidence of internal ion pair return during solvolysis of sec-alkyl benzenesulfonates
Cristina Paradisi and Joseph F. Bunnett
pp 8223 - 8233; DOI:
10.1021/ja00312a068
PDF
Calcium and magnesium binding to .gamma.-carboxyglutamate and .beta.-carboxyaspartate residues: structures of calcium and magnesium complexes of methylmalonic acid
Maria E. Curry, Drake S. Eggleston, and Derek J. Hodgson
pp 8234 - 8238; DOI:
10.1021/ja00312a069
PDF
Toward an ab initio derivation of crystal morphology
Ziva Berkovitch-Yellin
pp 8239 - 8253; DOI:
10.1021/ja00312a070
PDF
Specific rate enhancement by olefin coordination in reductive elimination of .eta.3-allylpalladium complexes
Hideo Kurosawa, Mitsuhiro Emoto, Akira Urabe, Kunio Miki, and Nobutami Kasai
pp 8253 - 8254; DOI:
10.1021/ja00312a071
PDF
An asymmetric Simmons-Smith reaction
Isao Arai, Atsunori Mori, and Hisashi Yamamoto
pp 8254 - 8256; DOI:
10.1021/ja00312a072
PDF
Homochiral ketals in organic synthesis. Diastereoselective cyclopropanation
Eugene A. Mash and Keith A. Nelson
pp 8256 - 8258; DOI:
10.1021/ja00312a073
PDF
Pyrazolyl-bridged iridium dimers. 10. Sequential addition at the metal centers in a diiridium configuration. Oxidatively induced relocation of a bent, terminal nitrosyl group to occupy a bridging site
D. O. Kimberley Fjeldsted, Stephen R. Stobart, and Michael J. Zaworotko
pp 8258 - 8259; DOI:
10.1021/ja00312a074
PDF
New mode of ligation for 1,3-butadiene to two metal centers. Synthesis and structure of [{(iso-Pr)2PCH2CH2CH2P(iso-Pr)2}Rh]2(.mu.-.eta.3-.eta.3-C4H6): a partial butadiene sandwich
Michael D. Fryzuk, Warren E. Piers, and Steven J. Rettig
pp 8259 - 8261; DOI:
10.1021/ja00312a075
PDF
Synthesis, structure, and reactivity of the {[(.eta.5-C5H5)2U]2(.mu.-TiW5O19-.kappa.2O)2}4- anion
V. W. Day, C. W. Earley, W. G. Klemperer, and D. J. Maltbie
pp 8261 - 8262; DOI:
10.1021/ja00312a076
PDF
Molecular building blocks for the synthesis of ceramic materials: [Si8O12](OCH3)8
V. W. Day, Walter G. Klemperer, V. V. Mainz, and D. M. Millar
pp 8262 - 8264; DOI:
10.1021/ja00312a077
PDF
Interaction of a hydrogen molecule with palladium
H. Nakatsuji and M. Hada
pp 8264 - 8266; DOI:
10.1021/ja00312a078
PDF
Sequence-specific cleavage of double-helical DNA. N-Bromoacetyldistamycin
Brenda F. Baker and Peter B. Dervan
pp 8266 - 8268; DOI:
10.1021/ja00312a079
PDF
NMR evidence for a horseradish peroxidase state with a deprotonated proximal histidine
Jeffrey S. De Ropp, V. Thanabal, and Gerd N. La Mar
pp 8268 - 8270; DOI:
10.1021/ja00312a080
PDF
Metal-metal bonds involving actinides. Synthesis and characterization of a complex having an unsupported actinide to transition metal bond
Richard S. Sternal, Carolyn P. Brock, and Tobin J. Marks
pp 8270 - 8272; DOI:
10.1021/ja00312a081
PDF
Spectral and electrochemical identification of iron(IV)-oxo porphyrin and iron(IV)-oxo porphyrin .pi.-cation species
Thomas S. Calderwood and Thomas C. Bruice
pp 8272 - 8273; DOI:
10.1021/ja00312a082
PDF
Photocatalysis of oxygen transfer from p-cyano-N,N-dimethylaniline N-oxide to meso-(tetraphenylporphinato)chromium(III) chloride
Lung Chi Yuan, Thomas S. Calderwood, and Thomas C. Bruice
pp 8273 - 8274; DOI:
10.1021/ja00312a083
PDF
A vinyltrimethylenemethane intermediate in the 1,3-sigmatropic rearrangement of the 6-methylenebicyclo[3.1.0]hex-2-enyl system
Steven Pikulin and Jerome A. Berson
pp 8274 - 8276; DOI:
10.1021/ja00312a084
PDF
Kinetics and mechanism of nitrate reduction by a dimeric aquamolybdenum(III) complex in aqueous solution. Direct evidence for an oxo-group transfer
Karl Weighardt, Maria Woeste, Partha S. Roy, and Phalguni Chaudhuri
pp 8276 - 8277; DOI:
10.1021/ja00312a085
PDF
On the nucleophilic nature of a TMM-PdL2 intermediate: a direct palladium catalyzed addition of trimethylenemethane to heteroatom unsaturation
Barry M. Trost and Peter J. Bonk
pp 8277 - 8279; DOI:
10.1021/ja00312a086
PDF
First examples of polynuclear, sulfur-containing, zirconium compounds. Synthesis and structural characterization of the trinuclear Zr3S3(S-tert-Bu)2(BH4)4(THF)2 and the hexanuclear Zr6S6(S-tert-Bu)4(BH4)8(THF)2 clusters
D. Coucouvanis, R. K. Lester, M. G. Kanatzidis, and D. Kessisoglou
pp 8279 - 8280; DOI:
10.1021/ja00312a087
PDF
A compound with a tin-phosphorus double bond: the first stable stannaphosphene
Claude Couret, Jean Escudie, Jacques Satge, Annie Raharinirina, and Jean Dominique Andriamizaka
pp 8280 - 8281; DOI:
10.1021/ja00312a088
PDF
Novel structure of the complex between carboxypeptidase A and a ketonic substrate analog
David W. Christianson, Lawrence C. Kuo, and William N. Lipscomb
pp 8281 - 8283; DOI:
10.1021/ja00312a089
PDF
A quantitative theory of mass spectral fragmentation patterns
J. Silberstein and R. D. Levine
pp 8283 - 8284; DOI:
10.1021/ja00312a090
PDF
Preparation and structures of novel di- and trinuclear clusters of iridium(II) without carbonyl ligands
F. Albert Cotton, Pascual Lahuerta, . Mercedes Sanau, and Willi Schwotzer
pp 8284 - 8285; DOI:
10.1021/ja00312a091
PDF
Transient circular dichroism of the luminescent state of Ru(bpy)32+
J. S. Gold, S. J. Milder, J. W. Lewis, and D. S. Kliger
pp 8285 - 8286; DOI:
10.1021/ja00312a092
PDF
Electron transfer through aromatic spacers in bridged electron-donor-acceptor molecules
H. Heitele and M. E. Michel-Beyerle
pp 8286 - 8288; DOI:
10.1021/ja00312a093
PDF
Pyrophosphate formation via a phosphoramidate intermediate in polyammonium macrocycle:metal ion-catalyzed hydrolysis of ATP
P. G. Yohannes, Mathias P. Mertes, and Kristin Bowman Mertes
pp 8288 - 8289; DOI:
10.1021/ja00312a094
PDF
Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivatives
James M. Tour and Eiichi Negishi
pp 8289 - 8291; DOI:
10.1021/ja00312a095
PDF
Nature of the migrating group in 1,5-sigmatropic hydrogen shifts
S. D. Kahn, W. J. Hehre, N. G. Rondan, and K. N. Houk
pp 8291 - 8292; DOI:
10.1021/ja00312a096
PDF
X-ray crystal structure and hydrocarbon solution dynamics of tetrameric 1-(dimethylamino)-3-lithiopropane
Gerhard W. Klumpp, Marcel Vos, Franciscus J. J. De Kanter, Cees Slob, Hendrik Krabbendam, and Anthony L. Spek
pp 8292 - 8294; DOI:
10.1021/ja00312a097
PDF
Highly stereoselective reduction of .alpha.-substituted .beta.-keto amides by means of hydrosilane-fluoride ion and hydrosilane-acid reagent. A practical approach to aldols of both threo and erythro configurations
Makoto Fujita and Tamejiro Hiyama
pp 8294 - 8296; DOI:
10.1021/ja00312a098
PDF
New carbon-carbon bond-forming reaction of carbon monoxide: remarkable trialkylation of a carbonyl ligand in a molybdenum pentadienyl complex
Michael S. Kralik, John P. Hutchinson, and Richard D. Ernst
pp 8296 - 8297; DOI:
10.1021/ja00312a099
PDF
Silapyran and silacyclobutene formation in the gas-phase pyrolysis of 2-(dimethylsilyl)furan
Thomas J. Barton and Brian L. Groh
pp 8297 - 8299; DOI:
10.1021/ja00312a100
PDF
Gas-phase generation of singlet oxygen by reaction of ozone with organic substances
W. C. Eisenberg, K. Taylor, and R. W. Murray
pp 8299 - 8300; DOI:
10.1021/ja00312a101
PDF
Biosynthesis of 7,8-didemethyl-8-hydroxy-5-deazariboflavin, the chromophoric moiety of coenzyme F420
Quang Le Van, Bruno Schwarzkopf, Adelbert Bacher, Paul J. Keller, Sungsook Lee, and Heinz G. Floss
pp 8300 - 8301; DOI:
10.1021/ja00312a102
PDF
Chiral complexes polymerize methacrylate esters to give helical polymers that mutarotate by uncoiling
Donald J. Cram and Dotsevi Y. Sogah
pp 8301 - 8302; DOI:
10.1021/ja00312a103
PDF
Electronic conductivity of poly[tris(5,5'-bis[(3-acrylyl-1-propoxy)carbonyl]-2,2'-bipyridine)ruthenium(0)]
C. Michael Elliott, J. G. Redepenning, and Ethan M. Balk
pp 8302 - 8304; DOI:
10.1021/ja00312a104
PDF
N-Carboxybiotin formation by pyruvate carboxylase: the stereochemical consequence at phosphorus
David E. Hansen and Jeremy R. Knowles
pp 8304 - 8305; DOI:
10.1021/ja00312a105
PDF
Crystal and band electronic structures of an organic salt with the first three-dimensional radical-cation donor network, (BEDT-TTF)Ag4(CN)5
Urs Geiser, Hau H. Wang, Larry E. Gerdom, Millicent A. Firestone, Lauren M. Sowa, and Jack M. Williams
pp 8305 - 8307; DOI:
10.1021/ja00312a106
PDF
Isopentenyl diphosphate:dimethylallyl diphosphate isomerase. Irreversible inhibition of the enzyme by active-site-directed covalent attachment
Manfred Muehlbacher and C. Dale Poulter
pp 8307 - 8308; DOI:
10.1021/ja00312a107
PDF
Synthesis of aromatic Schiff base oligomers at the air/water interface
Alan K. Engel, Tomoko Yoden, Kohei Sanui, and Naoya Ogata
pp 8308 - 8310; DOI:
10.1021/ja00312a108
PDF
Correction. Anomerization of Furanose Sugars and Sugar Phosphates
John Pierce, Anthony S. Serianni, and Robert Barker
pp 8310 - 8310; DOI:
10.1021/ja00312a600
PDF
Correction. Hartree-Fock MO Theoretical Approach to Aromaticity. Interpretation of Hückel Resonance Energy in Terms of Kinetic Energy of π Electrons
Hiroshi Ichikawa, and Yukiko Ebisawa
pp 8310 - 8310; DOI:
10.1021/ja00312a601
PDF
Correction. Bimetallic Solvated Metal Atom Dispersed Catalysts. New Materials with Low-Temperature Catalytic Properties
Kenneth J. Klabunde, and Yuzo Imizu
pp 8310 - 8310; DOI:
10.1021/ja00312a602
PDF
Book Reviews

pp 8311 - 8315; DOI:
10.1021/ja00312a603
PDF